scholarly journals Hydrolytic dehydrogenation of NH3BH3 catalyzed by ruthenium nanoparticles supported on magnesium–aluminum layered double-hydroxides

RSC Advances ◽  
2020 ◽  
Vol 10 (17) ◽  
pp. 9996-10005
Author(s):  
Xueying Qiu ◽  
Jiaxi Liu ◽  
Pengru Huang ◽  
Shujun Qiu ◽  
Chaoming Weng ◽  
...  

Ru/MgAl-LDHs catalyst was successfully prepared, which exhibited higher catalytic activity and lower activation energy toward the hydrolysis of ammonia borane for hydrogen production.

2017 ◽  
Vol 1 (10) ◽  
pp. 2128-2133 ◽  
Author(s):  
Wanyue Ye ◽  
Yuzhen Ge ◽  
Zhanming Gao ◽  
Rongwen Lu ◽  
Shufen Zhang

Enhanced hydrogen production activity of Pt nanoparticles from hydrolysis of ammonia–borane by facile surface coating of nanosized graphene oxide.


Small ◽  
2014 ◽  
Vol 10 (15) ◽  
pp. 3145-3152 ◽  
Author(s):  
Enass K. Abo-Hamed ◽  
Timothy Pennycook ◽  
Yana Vaynzof ◽  
Chris Toprakcioglu ◽  
Alexandros Koutsioubas ◽  
...  

2018 ◽  
Vol 2 (1) ◽  

In this study, a microwave treatment was chosen as an alternative method to synthesize Co-B-P catalyst for hydrogen production from hydrolysis of sodium borohydride (NaBH4 ) for the first time. The effect of gas, treatment time, and microwave power, amount of catalyst and temperature on the catalytic activity of Co-B-P catalyst was investigated under microwave treatment. The synthesized Co-B-P catalyst was characterized by XRD, SEM, EDX, BET and FTIR measurements. In the presence of Co-B-P catalyst, hydrolysis of NaBH4 under microwave treatment was completed in 9 minutes whereas it was completed in 16 minutes under normal condition. It was found that the value of activation energy is 16.211 kJ*mol-1.


2015 ◽  
Vol 51 (69) ◽  
pp. 13412-13415 ◽  
Author(s):  
V. K. Puthiyapura ◽  
D. J. L. Brett ◽  
A. E. Russell ◽  
W. F. Lin ◽  
C. Hardacre

PtSn showed a higher activity and lower activation energy towards butanol electrooxidation compared to pure Pt.


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