scholarly journals Facile fabrication, characterization and catalytic activity of a NiMo/Al2O3 nanocatalyst via a solution combustion method used in a low temperature hydrodesulfurization process: the effect of fuel to oxidant ratio

RSC Advances ◽  
2020 ◽  
Vol 10 (21) ◽  
pp. 12439-12450
Author(s):  
Roya Hamidi ◽  
Reza Khoshbin ◽  
Ramin Karimzadeh

Novel bimetallic NiMo/Al2O3 nanocatalysts were fabricated via a solution combustion method to evaluate the role of fuel to oxidant molar ratios on their structural properties and hydrodesulfurization activity.

2020 ◽  
Vol 59 (1) ◽  
pp. 131-143 ◽  
Author(s):  
Thanh Son Cam ◽  
Tatyana Alekseevna Vishnievskaia ◽  
Vadim Igorevich Popkov

AbstractA series of CuO/CeO2 catalysts were successfully synthesized via solution combustion method (SCS) using different fuels and tested for CO oxidation. The catalysts were characterized by energy-dispersive X-ray analysis (EDXA), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), N2 adsorption-desorption isotherms and H2 temperature-programmed reduction (H2-TPR). It was found that the used fuels strongly affected the characterization and the low-temperature reduction behavior of CuO/CeO2 catalysts. The CuO/CeO2-urea catalyst exhibited higher catalytic activity toward CO oxidation (t50=120∘C, t100=159∘C) than the 5 other synthesized catalysts. In addition, the CuO/CeO2-urea catalyst displayed high stability for CO oxidation during five cycles and water resistance. The enhanced catalytic CO oxidation of the synthesized samples can be attributed by a combination of factors, such as smaller crystallite size, higher specific surface area, larger amount of amorphous copper(II) oxide, more mesoporous and uniform spherical-like structure. These findings are worth considering in order to continue the study of the CuO/CeO2 catalyst with low-temperature CO oxidation.


RSC Advances ◽  
2017 ◽  
Vol 7 (55) ◽  
pp. 34482-34487 ◽  
Author(s):  
Xinwei Zou ◽  
Xiaoyan Yan ◽  
Guomin Li ◽  
Yuming Tian ◽  
Mingang Zhang ◽  
...  

Self-assembled porous In2O3/ZnO heterostructures are synthesized via a low temperature solution combustion method. An extremely high gas sensitivity can be reached when exposed to Cl2 at 370 °C.


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