scholarly journals A novel thermoplastic shape memory polymer with solid-state plasticity derived from exchangeable hydrogen bonds

RSC Advances ◽  
2020 ◽  
Vol 10 (16) ◽  
pp. 9387-9395 ◽  
Author(s):  
Xu Zhang ◽  
Guangping Sun ◽  
Xuequan Zhang
Keyword(s):  
Solid State ◽  
Hydrogen Bonds ◽  
Shape Memory ◽  
Shape Memory Polymer ◽  
Memory Ability ◽  
Exchangeable Hydrogen

Thermoplastic SMP equipped with a combination of performances including inherent reprocessability, satisfactory shape memory ability and swift shape re-configurability in the solid state.

Biodegradable Shape-Memory Polymer Networks:  Characterization with Solid-State NMR

2005 ◽  
Vol 38 (9) ◽  
pp. 3793-3799 ◽  
Author(s):  
Marko Bertmer ◽  
Alina Buda ◽  
Iris Blomenkamp-Höfges ◽  
Steffen Kelch ◽  
Andreas Lendlein
Keyword(s):  
Solid State ◽  
Shape Memory ◽  
Solid State Nmr ◽  
Shape Memory Polymer ◽  
Polymer Networks

Solid-State NMR Characterization of Biodegradable Shape-Memory Polymer Networks

2005 ◽  
Vol 230 (1) ◽  
pp. 110-115 ◽  
Author(s):  
Marko Bertmer ◽  
Alina Buda ◽  
Iris Blomenkamp-Höfges ◽  
Steffen Kelch ◽  
Andreas Lendlein
Keyword(s):  
Solid State ◽  
Shape Memory ◽  
Solid State Nmr ◽  
Shape Memory Polymer ◽  
Polymer Networks ◽  
Nmr Characterization

Synthesis and Solid-State Structure of (4-Hydroxy-3,5-diiodophenyl)phosphine Oxides. Dimeric Motifs with the Assistance of O-H···O=P Hydrogen Bonds

2015 ◽  
Vol 19 (5) ◽  
pp. 469-474 ◽  
Author(s):  
Nicholas Bewick ◽  
Agata Arendt ◽  
Yan Li ◽  
S.awomir Szafert ◽  
Tadeusz Lis ◽  
...  
Keyword(s):  
Solid State ◽  
Hydrogen Bonds ◽  
Phosphine Oxides ◽  
State Structure ◽  
Solid State Structure

scholarly journals Design of Shape Memory Thermoplastic Material Systems for FDM-Type Additive Manufacturing

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4254
Author(s):  
Paulina A. Quiñonez ◽  
Leticia Ugarte-Sanchez ◽  
Diego Bermudez ◽  
Paulina Chinolla ◽  
Rhyan Dueck ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory ◽  
Thermomechanical Processing ◽  
Material Selection ◽  
Shape Memory Polymer ◽  
Fused Filament Fabrication ◽  
Materials Development ◽  
Thermoplastic Material ◽  
Polymer Systems ◽  
Injection Molded

The work presented here describes a paradigm for the design of materials for additive manufacturing platforms based on taking advantage of unique physical properties imparted upon the material by the fabrication process. We sought to further investigate past work with binary shape memory polymer blends, which indicated that phase texturization caused by the fused filament fabrication (FFF) process enhanced shape memory properties. In this work, two multi-constituent shape memory polymer systems were developed where the miscibility parameter was the guide in material selection. A comparison with injection molded specimens was also carried out to further investigate the ability of the FFF process to enable enhanced shape memory characteristics as compared to other manufacturing methods. It was found that blend combinations with more closely matching miscibility parameters were more apt at yielding reliable shape memory polymer systems. However, when miscibility parameters differed, a pathway towards the creation of shape memory polymer systems capable of maintaining more than one temporary shape at a time was potentially realized. Additional aspects related to impact modifying of rigid thermoplastics as well as thermomechanical processing on induced crystallinity are also explored. Overall, this work serves as another example in the advancement of additive manufacturing via materials development.

Autonomous Off‐Equilibrium Morphing Pathways of a Supramolecular Shape‐Memory Polymer

2021 ◽  
pp. 2102473
Author(s):  
Wenjun Peng ◽  
Guogao Zhang ◽  
Qian Zhao ◽  
Tao Xie
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer

scholarly journals Pressure Orientation-Dependent Recovery of 3D-Printed PLA Objects with Varying Infill Degree

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1275 ◽  
Author(s):  
Guido Ehrmann ◽  
Andrea Ehrmann
Keyword(s):  
Shape Memory ◽  
Fused Deposition Modeling ◽  
Static Load ◽  
Shape Memory Polymer ◽  
Applied Pressure ◽  
Poly Lactic Acid ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Load Tests ◽  
3D Printed

Poly(lactic acid) is not only one of the most often used materials for 3D printing via fused deposition modeling (FDM), but also a shape-memory polymer. This means that objects printed from PLA can, to a certain extent, be deformed and regenerate their original shape automatically when they are heated to a moderate temperature of about 60–100 °C. It is important to note that pure PLA cannot restore broken bonds, so that it is necessary to find structures which can take up large forces by deformation without full breaks. Here we report on the continuation of previous tests on 3D-printed cubes with different infill patterns and degrees, now investigating the influence of the orientation of the applied pressure on the recovery properties. We find that for the applied gyroid pattern, indentation on the front parallel to the layers gives the worst recovery due to nearly full layer separation, while indentation on the front perpendicular to the layers or diagonal gives significantly better results. Pressing from the top, either diagonal or parallel to an edge, interestingly leads to a different residual strain than pressing from front, with indentation on top always firstly leading to an expansion towards the indenter after the first few quasi-static load tests. To quantitatively evaluate these results, new measures are suggested which could be adopted by other groups working on shape-memory polymers.

scholarly journals Harnessing reversible dry adhesion using shape memory polymer microparticles

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19616-19622
Author(s):  
Wenbing Li ◽  
Junhao Liu ◽  
Wanting Wei ◽  
Kun Qian
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Memory Effects ◽  
Reversible Adhesion ◽  
Dry Adhesion ◽  
Bonding Property ◽  
Shape Memory Effects ◽  
Polymer Microparticles

Shape memory polymers can provide excellent bonding property because of their shape memory effects. This paper proposes an adhesive unit that is capable of repeatable smart adhesion and exhibits reversible adhesion under heating.

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