scholarly journals Synthesis of lutein esters using a novel biocatalyst of Candida antarctica lipase B covalently immobilized on functionalized graphitic carbon nitride nanosheets

RSC Advances ◽  
2020 ◽  
Vol 10 (15) ◽  
pp. 8949-8957
Author(s):  
Huijuan Shangguan ◽  
Shan Zhang ◽  
Xin Li ◽  
Qi Zhou ◽  
Jie Shi ◽  
...  

The functionalized graphitic carbon nitride nanosheets (g-C3N4-Ns) as the immobilized carrier for the accommodation of Candida antarctica lipase B (CALB), which obtains the highest esterification rate (92%) in lutein esters synthesis.

2018 ◽  
Vol 129 ◽  
pp. 12-24 ◽  
Author(s):  
Nathalia Saraiva Rios ◽  
Maisa Pessoa Pinheiro ◽  
Magno Luís Bezerra Lima ◽  
Denise Maria Guimarães Freire ◽  
Ivanildo José da Silva ◽  
...  

2019 ◽  
Vol 1091 ◽  
pp. 69-75 ◽  
Author(s):  
Na Wu ◽  
Yi-Ting Wang ◽  
Xiao-Yan Wang ◽  
Feng-Na Guo ◽  
Hui Wen ◽  
...  

2002 ◽  
Vol 80 (6) ◽  
pp. 565-570 ◽  
Author(s):  
Szilvia Gedey ◽  
Arto Liljeblad ◽  
László Lázár ◽  
Ferenc Fülöp ◽  
Liisa T Kanerva

The Candida antarctica lipase B-catalyzed reactions of five β-amino esters with neat butyl butanoate and with 2,2,2-trifluoroethyl butanoate in diisopropyl ether were studied, as were the reactions of the same β-amino esters and their N-butanamides with neat butanol. The possibility for sequential resolution, where the amino and ester functions of the substrate both react with an achiral butanoate, became less likely with increasing size of the substrate from ethyl 3-aminobutanoate (1a) to pentanoate (1b) or larger. On the other hand, the alcoholyses of N-acylated β-amino esters successfully proceeded in butanol with E > 100. Gram-scale resolution of the N-butanoylated 1a was performed to demonstrate the usefulness of the method. Key words: lipase, interesterification, acylation, alcoholysis, resolution, β-amino esters.


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