scholarly journals Theoretical design of bis-azole derivatives for energetic compounds

RSC Advances ◽  
2020 ◽  
Vol 10 (22) ◽  
pp. 13185-13195 ◽  
Author(s):  
Keyu Pu ◽  
Linyuan Wang ◽  
Jian Liu ◽  
Kai Zhong
Keyword(s):  
Nitrogen Content ◽  
Energetic Materials ◽  
High Heat ◽  
Heat Of Formation ◽  
Energetic Compounds ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
New Class ◽  
Theoretical Design ◽  
External Stimuli

Bis-azole derivatives are a new class of energetic materials with features that include high nitrogen content, high heat of formation (HOF), high detonation performance and insensitivity to external stimuli.

Two High Nitrogen Content Energetic Compounds: 3,6-Diguanidino-1,2,4,5-Tetrazine and Its Diperchlorate

2012 ◽  
Vol 57 (3) ◽  
pp. 729-736 ◽  
Author(s):  
Zhi-min Li ◽  
Shao-hua Xie ◽  
Jian-guo Zhang ◽  
Jin-ling Feng ◽  
Kun Wang ◽  
...  
Keyword(s):  
Nitrogen Content ◽  
Energetic Compounds ◽  
High Nitrogen Content ◽  
High Nitrogen

scholarly journals Recent Advances in Synthesis and Properties of Nitrated-Pyrazoles Based Energetic Compounds

Molecules ◽  
2020 ◽  
Vol 25 (15) ◽  
pp. 3475 ◽  
Author(s):  
Shijie Zhang ◽  
Zhenguo Gao ◽  
Di Lan ◽  
Qian Jia ◽  
Ning Liu ◽  
...  
Keyword(s):  
Energetic Materials ◽  
High Performance ◽  
High Efficiency ◽  
Low Cost ◽  
Rapid Development ◽  
Development Trend ◽  
High Heat ◽  
High Energy ◽  
Heat Of Formation ◽  
Energetic Compounds

Nitrated-pyrazole-based energetic compounds have attracted wide publicity in the field of energetic materials (EMs) due to their high heat of formation, high density, tailored thermal stability, and detonation performance. Many nitrated-pyrazole-based energetic compounds have been developed to meet the increasing demands of high power, low sensitivity, and eco-friendly environment, and they have good applications in explosives, propellants, and pyrotechnics. Continuous and growing efforts have been committed to promote the rapid development of nitrated-pyrazole-based EMs in the last decade, especially through large amounts of Chinese research. Some of the ultimate aims of nitrated-pyrazole-based materials are to develop potential candidates of castable explosives, explore novel insensitive high energy materials, search for low cost synthesis strategies, high efficiency, and green environmental protection, and further widen the applications of EMs. This review article aims to present the recent processes in the synthesis and physical and explosive performances of the nitrated-pyrazole-based Ems, including monopyrazoles with nitro, bispyrazoles with nitro, nitropyrazolo[4,3-c]pyrazoles, and their derivatives, and to comb the development trend of these compounds. This review intends to prompt fresh concepts for designing prominent high-performance nitropyrazole-based EMs.

Synthesis and properties of salts derived from C4N182−, C4N18H3− and C4N18H3− anions

2020 ◽  
Vol 8 (47) ◽  
pp. 25035-25039
Author(s):  
Zhen Dong ◽  
Zhiwen Ye
Keyword(s):  
Nitrogen Content ◽  
Energetic Materials ◽  
Decomposition Temperature ◽  
Detonation Properties ◽  
High Nitrogen Content ◽  
High Nitrogen

Three types of energetic materials with high nitrogen content, high decomposition temperature and good detonation properties were obtained.

scholarly journals Computational Study of Coordinated Ni(II) Complex with High Nitrogen Content Ligands

2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
Bo Tang ◽  
Jia-Hai Ye ◽  
Xue-Hai Ju
Keyword(s):  
Nitrogen Content ◽  
Energetic Materials ◽  
Density Functional ◽  
Computational Study ◽  
Frontier Molecular Orbital ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Geometrical Structures ◽  
Bond Lengths ◽  
Coordination Process

Density functional computations were performed on two tetracoordinated Ni(II) complexes as high nitrogen content energetic materials (1: dinickel bishydrazine ter[(1H-Tetrazol-3-yl)methan-3yl]-1H-tetrazole and 2: dinickel tetraazide ter[(1H-Tetrazol-3-yl)methan-3yl]-1H-tetrazolate). The geometrical structures, relative stabilities and sensitivities, and thermodynamic properties of the complexes were investigated. The energy gaps of frontier molecular orbital (HOMO and LUMO) and vibrational spectroscopies were also examined. There are minor Jahn-Teller distortions in both complexes 1 and 2, with two long Ni–N bond lengths and two short ones. The enthalpies of combustion for both complexes are over 3600 kJ/mol. The N–N bond lengths in the moieties of hydrazine and azide ligands increase in the coordination process compared to those of the isolated molecules.

Poultry Manure as a Fertilizer

EDIS ◽  
2013 ◽  
Vol 2013 (11) ◽  
Author(s):  
Michael A. Davis ◽  
Doug R. Sloan ◽  
Gerald Kidder ◽  
R. D. Jacobs
Keyword(s):  
Organic Matter ◽  
Environmental Factors ◽  
Nitrogen Content ◽  
Soil Amendment ◽  
Poultry Manure ◽  
Nutrient Retention ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Animal Science ◽  
Fact Sheet

Animal manures have been used as natural crop fertilizers for centuries. Because of poultry manure’s high nitrogen content, it has long been recognized as one of the most desirable manures. Besides fertilizing crops, manures also supply other essential plant nutrients and serve as a soil amendment by adding organic matter, which helps improve the soil’s moisture and nutrient retention. Organic matter persistence will vary with temperature, drainage, rainfall, and other environmental factors. This 2-page fact sheet was written by Michael A. Davis, D.R. Sloan, Gerald Kidder, and R.D. Jacobs, and published by the UF Department of Animal Science, November 2013. http://edis.ifas.ufl.edu/aa205

scholarly journals How Does an Acidic Support Affect the Hydrotreatment of a Gas Oil with High Nitrogen Content?

2019 ◽  
Vol 33 (2) ◽  
pp. 1467-1472 ◽  
Author(s):  
Minh-Tuan Nguyen ◽  
Gerhard D. Pirngruber ◽  
Florian Albrieux ◽  
Fabien Chainet ◽  
Melaz Tayakout-Fayolle ◽  
...  
Keyword(s):  
Nitrogen Content ◽  
Gas Oil ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Acidic Support

NO x and N2O Emissions During Fluidized Bed Combustion of Leather Wastes

2005 ◽  
Vol 128 (2) ◽  
pp. 99-103 ◽  
Author(s):  
Alberto Bahillo ◽  
Lourdes Armesto ◽  
Andrés Cabanillas ◽  
Juan Otero
Keyword(s):  
Nitrogen Content ◽  
Fluidized Bed ◽  
Oxygen Content ◽  
N2o Emission ◽  
N2o Emissions ◽  
Fluidized Bed Combustion ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Leather Wastes ◽  
Leather Waste

Transformation of hide (animal skins) into leather is a complicated process during which significant amounts of wastes are generated. Fluidized bed combustion has been extended to burn different wastes that have problems with their disposal showing its technical feasibility. Considering the characteristics of the leather waste, especially the heating value (12.5-21MJ∕kg), it is a fairly good fuel. Moreover, leather waste has a high volatile matter, 65%, similar to other biomasses and unusual high nitrogen content, 14%. The aim of this work was to study leather wastes combustion in fluidized bed presenting experimental results regarding NOx and N2O emissions. A series of experiments were carried out in a fluidized bed pilot plant to understand the importance of operating parameters such as furnace temperature, oxygen content in gases, staged combustion and residence time on the NOx and N2O emission level. Despite having high nitrogen content, low conversion of N-fuel to NOx and N2O was measured during the combustion of leather waste in BFB. Bed temperature and oxygen content were found as the most important single parameters on N2O emission and only oxygen content has a significant influence on NOx emission. Leather waste exhibits a great NOx∕O2 trend; NOx emission decreases as the oxygen concentration decreases while the effect of combustion temperature on NOx is insignificant. Staged combustion does not give a reduction in NOx.

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