A practical strategy to access chiral α-aryloxy carboxylic acids through ion-pairing directed asymmetric hydrogenation

2020 ◽  
Vol 7 (24) ◽  
pp. 4069-4073
Author(s):  
Lin Yao ◽  
Haixia Ma ◽  
Zhuang Nie ◽  
Huifang Nie ◽  
Dongxu Zhang ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Asymmetric Hydrogenation ◽  
Ion Pairing ◽  
Optically Active ◽  
Covalent Interaction ◽  
Highly Efficient ◽  
Practical Strategy

A series of optically active α-aryloxy functionalized carboxylic acids were obtained via non-covalent interaction assisted highly efficient asymmetric hydrogenation.

Highly Efficient Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Acids Catalyzed by Ruthenium(II)-Dipyridylphosphine Complexes

2007 ◽  
Vol 349 (4-5) ◽  
pp. 517-520 ◽  
Author(s):  
Liqin Qiu ◽  
Yue-Ming Li ◽  
Fuk Yee Kwong ◽  
Wing-Yiu Yu ◽  
Qing-Hua Fan ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Asymmetric Hydrogenation ◽  
Highly Efficient ◽  
Unsaturated Carboxylic Acids

ChemInform Abstract: Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2((S)-H8-BINAP).

ChemInform ◽  
2010 ◽  
Vol 28 (2) ◽  
pp. no-no
Author(s):  
T. UEMURA ◽  
X. ZHANG ◽  
K. MATSUMURA ◽  
N. SAYO ◽  
H. KUMOBAYASHI ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Optically Active ◽  
Enantioselective Synthesis ◽  
Highly Efficient

Highly enantioselective hydrogenation of α-oxy functionalized α,β-unsaturated acids catalyzed by a ChenPhos–Rh complex in CF3CH2OH

2016 ◽  
Vol 52 (11) ◽  
pp. 2273-2276 ◽  
Author(s):  
Lin Yao ◽  
Jialin Wen ◽  
Shaodong Liu ◽  
Renchang Tan ◽  
Noel Marie Wood ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Asymmetric Hydrogenation ◽  
Enantioselective Hydrogenation ◽  
Ionic Interaction ◽  
Efficient Catalyst ◽  
Highly Efficient ◽  
Unsaturated Carboxylic Acids

A Chenphos–Rh complex is demonstrated to be a highly efficient catalyst for asymmetric hydrogenation of α-oxy functionalized α,β-unsaturated carboxylic acidsviaan ionic interaction between the ligand and the substrate.

Highly Efficient Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Acids Catalyzed by Ruthenium(II)-Dipyridylphosphine Complexes.

ChemInform ◽  
2007 ◽  
Vol 38 (28) ◽  
Author(s):  
Liqin Qiu ◽  
Yue-Ming Li ◽  
Fuk Yee Kwong ◽  
Wing-Yiu Yu ◽  
Qing-Hua Fan ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Asymmetric Hydrogenation ◽  
Highly Efficient ◽  
Unsaturated Carboxylic Acids

Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2[(S)-H8-BINAP]

1996 ◽  
Vol 61 (16) ◽  
pp. 5510-5516 ◽  
Author(s):  
Toshitsugi Uemura ◽  
Xiaoyoung Zhang ◽  
Kazuhiko Matsumura ◽  
Noboru Sayo ◽  
Hidenori Kumobayashi ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Optically Active ◽  
Enantioselective Synthesis ◽  
Highly Efficient

Catalytic asymmetric hydrogenation reaction by in situ formed ultra-fine metal nanoparticles in live thermophilic hydrogen-producing bacteria

Nanoscale ◽  
2021 ◽  
Author(s):  
Wei Bing ◽  
Faming Wang ◽  
Yuhuan Sun ◽  
Jinsong Ren ◽  
Xiaogang Qu
Keyword(s):  
Metal Nanoparticles ◽  
Catalytic Hydrogenation ◽  
Asymmetric Hydrogenation ◽  
Environmentally Friendly ◽  
Hydrogenation Reaction ◽  
Highly Efficient ◽  
Hydrogenation Reactions ◽  
Live Bacteria ◽  
Catalytic Asymmetric Hydrogenation

An environmentally friendly biomimetic strategy has been presented and validated for the catalytic hydrogenation reaction in live bacteria. In situ formed ultra-fine metal nanoparticles can realize highly efficient asymmetric hydrogenation reactions.

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