A unique dual fluorescence emission in solid-state from small molecule based on phenanthrocarbazole with AIE luminogen as single-molecule white-light emissive material

2021 ◽  
Author(s):  
Jirat Chatsirisupachai ◽  
Phattananawee Nalaoh ◽  
Chokchai Kaiyasuan ◽  
Pongsakorn Chasing ◽  
Taweesak Sudyoadsuk ◽  
...  
Keyword(s):  
Solid State ◽  
Small Molecule ◽  
Single Molecule ◽  
White Light ◽  
Biomedical Applications ◽  
Organic Molecules ◽  
Fluorescence Emission ◽  
Dual Fluorescence ◽  
Emissive Property

Purely organic molecules with dual emissive property have received increased attention in the last decade as they are now being utilized in practical optoelectronic, sensing and biomedical applications. We presented...

Single-component small-molecule white light organic phosphors

2017 ◽  
Vol 53 (66) ◽  
pp. 9269-9272 ◽  
Author(s):  
Ning-Ning Zhang ◽  
Cai Sun ◽  
Xiao-Ming Jiang ◽  
Xiu-Shuang Xing ◽  
Yong Yan ◽  
...  
Keyword(s):  
Solid State ◽  
Small Molecule ◽  
White Light ◽  
Light Emission ◽  
White Light Emission ◽  
Single Component ◽  
Supramolecular Aggregate ◽  
Organic Phosphors

A family of two small and easily synthesizable 1,2,3-triazole molecules with intrinsic white-light-emission in the solid state has been reported. The white light is assigned to the supramolecular aggregate emission (SAE) that is unusual for single-component white light phosphors.

Robust Circular Polarized Emission from Nanoscopic Single-Molecule Sources: Application to Solid State Devices

2006 ◽  
Vol 965 ◽  
Author(s):  
Ruthanne Hassey ◽  
Ellen J Swain ◽  
Nathan I Hammer ◽  
Emily L Richards ◽  
Dhandapani Venkataraman ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Solid State ◽  
Single Molecule ◽  
Polarization State ◽  
Fluorescence Emission ◽  
Polarization Component ◽  
Circularly Polarized ◽  
Solid State Devices ◽  
Polarized Emission ◽  
Circular Dichroïsm

ABSTRACTControlling the polarization state of fluorescence emission in solid state devices is an important goal in optical display technologies. High-purity (right or left) circular polarized emission is particularly desirable because an arbitrary linearly polarized state can be generated with much higher efficiency (lower loss) as compared with a non-polarized fluorescence input. Here we discuss observation of resonant chiroptical effects (fluorescence detected circular dichroism (FDCD), and circular polarized luminescence (CPL)) from single (bridged-triarylamine) helicene molecules in a solid-film format. In the FDCD experiment using 457-nm excitation – an excitation wavelength where the bulk circular dichroism is negligible – single-molecule fluorescence from enantiomerically pure helicene samples show surprising distribution of dissymmetry (g) parameters centered near zero but with a significant contribution from molecules showing an almost perfectly pure response to either right or left circularly polarized light. Experiments combining a well-defined circularly polarized excitation (either right or left) with decomposition of the fluorescence into left- and right-circular polarization component show only a weak correlation between the dissymmetry (sign and magnitude) of the CPL with the polarization state of the input. Current efforts are directed at wavelength resolved CPL, FDCD at wavelengths that are more closely match to bulk circular dichroism features, and orientational dependence of FDCD and CPL. These results provide new insight into chiroptical properties of chiral fluorophores at the single molecule level and suggests new optical device possibilities with chiral fluorophores.

White-light emission from a structurally simple hydrazone

2019 ◽  
Vol 55 (64) ◽  
pp. 9551-9554 ◽  
Author(s):  
Baihao Shao ◽  
Nell Stankewitz ◽  
Jacob A. Morris ◽  
Matthew D. Liptak ◽  
Ivan Aprahamian
Keyword(s):  
White Light ◽  
Light Emission ◽  
Fluorescence Emission ◽  
White Light Emission ◽  
Excitation Wavelength ◽  
Dual Fluorescence

Two hydrazones featuring a unique excitation wavelength-dependent dual fluorescence emission have been developed.

Modification of Blinking Statistics in Solid State Quantum Dot/Conjugated Organic Polymer Composite Nanostructures

2006 ◽  
Vol 959 ◽  
Author(s):  
Nathan I Hammer ◽  
Kevin T Early ◽  
Michael Y Odoi ◽  
Ravisubhash Tangirala ◽  
Kevin Sill ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Solid State ◽  
Quantum Dot ◽  
Single Molecule ◽  
Fluorescence Emission ◽  
Phase Segregation ◽  
Organic Polymer ◽  
Cdse Quantum Dots ◽  
The Stability ◽  
Fluorescence Intermittency

ABSTRACTFluorescence intermittency, or “blinking” in quantum dot systems has been the subject of great interest since the first observation of this phenomenon nearly 10 years ago. The stability of quantum dot fluorescence emission is especially important in the context of photovoltaic, optoelectronic, and biological applications, where device performance, or the ability to track labeled particles, is affected adversely by fluorescence intermittency. Single-molecule spectroscopy combined with atomic force microscopy measurements reveal that CdSe quantum dots functionalized with oligo(phenylene vinylene), OPV, ligands exhibit modified optical properties such as suppression of blinking when compared to conventional TOPO covered or ZnS-capped CdSe quantum dots. The blinking suppression is shown to be highly sensitive to the degree of ligand coverage on the quantum dot surface and this effect is interpreted as resulting from charge transport from photoexcited OPV into vacant trap sites on the quantum dot surface. This direct surface derivatization of quantum dots with organic ligands also enables a “tunable” quantum dot surface that allows dispersion of quantum dots in a variety of polymer supported thin films without phase segregation. This facilitates straightforward inclusion of these new hybrid materials into solid state formats and suggests exciting new applications of composite quantum dot/organic systems in optoelectronic systems.

Single Molecule Solid State Light Emitting Electrochemical Cells with Lifetimes Superior to 3000 Hours

2008 ◽  
Author(s):  
Henk Bolink ◽  
Rubén D. Costa ◽  
Enrique Orti ◽  
Michele Sessolo ◽  
Stefan Graber ◽  
...  
Keyword(s):  
Solid State ◽  
Single Molecule ◽  
Electrochemical Cells ◽  
Light Emitting

Enhanced-Fluorescence of a Dye on DNA- assembled Gold Nano-Dimers Discriminated by Lifetime Correlation Spectroscopy

2017 ◽  
Author(s):  
Pedro M. R. Paulo ◽  
David Botequim ◽  
Agnieszka Jóskowiak ◽  
Sofia Martins ◽  
Duarte M. F. Prazeres ◽  
...  
Keyword(s):  
Single Molecule ◽  
Fluorescence Emission ◽  
Directed Assembly ◽  
Plasmon Mode ◽  
Correlation Spectroscopy ◽  
Enhanced Fluorescence ◽  
Detection Volume ◽  
Relaxation Component ◽  
Good Agreement ◽  
Confocal Detection

<div> <div> <div> <p>We have employed DNA-directed assembly to prepare dimers of gold nanoparticles and used their longitudinally coupled plasmon mode to enhance the fluorescence emission of an organic red-emitting dye, Atto-655. The plasmon- enhanced fluorescence of this dye using dimers of 80 nm particles was measured at single molecule detection level. The top enhancement factors were above 1000-fold in 71% of the dimers within a total of 32 dimers measured, and, in some cases, they reached almost 4000-fold, in good agreement with model simulations. Additionally, fluorescence lifetime correlation analysis enabled the separation of enhanced from non-enhanced emission simultaneously collected in our confocal detection volume. This approach allowed us to recover a short relaxation component exclusive to enhanced emission that is attributed to the interaction of the dye with DNA in the interparticle gaps. </p> </div> </div> </div>

scholarly journals Solid‐State Near‐Infrared Circularly Polarized Luminescence from Chiral YbIII‐Single‐Molecule Magnet

2021 ◽  
Author(s):  
Fabrice Pointillart ◽  
Bertrand Lefeuvre ◽  
Carlo Andrea Mattei ◽  
Jessica Flores Gonzalez ◽  
Frédéric Gendron ◽  
...  
Keyword(s):  
Solid State ◽  
Single Molecule ◽  
Near Infrared ◽  
Circularly Polarized ◽  
Single Molecule Magnet ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence

Unravelling the dissolution mechanism of polyphosphate glasses by 31P NMR spectroscopy: ligand competition and reactivity of intermediate complexes

2021 ◽  
Author(s):  
Dahiana Andrea Avila Salazar ◽  
Peter Bellstedt ◽  
Atsuhiro Miura ◽  
Yuki Oi ◽  
Toshihiro Kasuga ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Biomedical Applications ◽  
Structural Changes ◽  
31P Nmr ◽  
Dissolution Mechanism ◽  
31P Nmr Spectroscopy ◽  
Glass Dissolution ◽  
Polyphosphate Glasses

Phosphate glass dissolution can be tailored via compositional and subsequent structural changes, which is of interest for biomedical applications such as therapeutic ion delivery. Here, solid-state 31P nuclear magnetic resonance...

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