Facile star-shaped tetraphenylethylene-based molecules with fused ring-terminated diarylamine as interfacial hole transporting materials for inverted perovskite solar cells

Author(s):  
Yung-Chung Chen ◽  
Ding-Zhi Lin ◽  
Jhong-Ci Wang ◽  
Jen-Shyang Ni ◽  
Yang-Yen Yu ◽  
...  

Three p-type small molecules (CL-1–3) based on tetraphenylethylene as the core and different π-conjugation diarylamines as linkers are synthesized. The bilayer HTL of the NiOx/CL-3-based cell exhibits the best power conversion efficiency of 20.15%.

2019 ◽  
Vol 43 (31) ◽  
pp. 12211-12214 ◽  
Author(s):  
Fatima Al-Zohbi ◽  
Youssef Jouane ◽  
Safia Benhattab ◽  
Jérôme Faure-Vincent ◽  
François Tran-Van ◽  
...  

Carbazole-based HTMs with fused benzene rings as substituents show a power conversion efficiency exceeding 17% (13.7% for Spiro-OMeTAD under the same conditions).


ChemInform ◽  
2016 ◽  
Vol 47 (11) ◽  
pp. no-no
Author(s):  
Sadia Ameen ◽  
Malik Abdul Rub ◽  
Samia A. Kosa ◽  
Khalid A. Alamry ◽  
M. Shaheer Akhtar ◽  
...  

2020 ◽  
Vol 8 (4) ◽  
pp. 1858-1864 ◽  
Author(s):  
Xiangyu Kong ◽  
Yue Jiang ◽  
Xiayan Wu ◽  
Cong Chen ◽  
Jiali Guo ◽  
...  

Perovskite solar cells based on dopant-free PBDT[2F]T have achieved a power conversion efficiency (17.52%), combined with an impressive stability in contrast to that with the doped spiro-OMeTAD as a HTM in ambient atmosphere and even in high humidity.


2020 ◽  
Vol 4 (1) ◽  
pp. 21
Author(s):  
Ashique Kotta ◽  
Hyung-Kee Seo

Organic–inorganic hybrid perovskite solar cells have resulted in tremendous interest in developing future generation solar cells, due to their high efficiency exceeding 25%. For inverted type perovskite solar cells, the hole transporting layer plays a crucial role in improving the efficiency and stability of the perovskite solar cells by modifying band alignment, electric conductivity, and interfacial recombination losses. Here, vanadium doped NiO is selected as a hole transporting layer to study the impact of V dopant on the optoelectronic properties of NiO and photovoltaic performance. The prepared materials are characterized using XRD, SEM, TEM, and XPS. A TEM micrograph confirms that p-type materials have a small spherical dot structure. The V-doped NiO, used as a hole-extraction layer, can be prepared by a simple solvothermal decomposition method. The presence of V in the NiO layer has an influence on the conductivity of the NiO layer. Besides, synthesized p-type material can be used to fabricate a relatively low processing temperature, and has the advantage of a wide choice of transparent conductive oxide substrate. As a result, an inverted type planar perovskite solar cell incorporating of vanadium in NiO hole-transport layer improves the power conversion efficiency. The photovoltaic property of the prepared solar cell is measured under AM 1.5 G simulated light. The photocurrent density is 21.09 mA/cm2, open-circuit voltage is 1.04 V, and the fill factor is 0.63. As a result, the overall power conversion efficiency reaches 13.82%.


ChemSusChem ◽  
2015 ◽  
Vol 9 (1) ◽  
pp. 10-27 ◽  
Author(s):  
Sadia Ameen ◽  
Malik Abdul Rub ◽  
Samia A. Kosa ◽  
Khalid A. Alamry ◽  
M. Shaheer Akhtar ◽  
...  

2017 ◽  
Vol 53 (69) ◽  
pp. 9558-9561 ◽  
Author(s):  
Xuepeng Liu ◽  
Fantai Kong ◽  
Rahim Ghadari ◽  
Shengli Jin ◽  
Ting Yu ◽  
...  

Novel anthracene–arylamine hole transporting materials achieved a power conversion efficiency over 17% for perovskite solar cells.


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