Two novel nickel cluster substituted polyoxometalates: syntheses, structures and their photocatalytic activities, magnetic behaviors, and ion-conduction properties
Two novel nickel cluster substituted polyoxometalates (POMs), H7Na19(H2O)26{Ni12(OH)9(PO4)4(A-α-SiW9O34)[W4O10(OH)(PO2(OH)2)2(A-α-SiW9O34)2]}·4C2H8N·27H2O (1) and H26.5K2.5Na(H2O)16[Ni6(OH)(BO3)2(dien)2(B-α-SiW10O37)2}2·24H2O (2) (dien = diethylenetriamine), have been successfully prepared. 1 is a Ni12-substituted POM comprised of a novel {Ni12(OH)9(PO4)4} core,...
2012 ◽
Vol 96
(1)
◽
pp. 166-173
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2011 ◽
Vol 133
(40)
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pp. 16023-16036
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