Molecular oxofluorides OMFn of nickel, palladium and platinum: oxyl radicals with moderate ligand field inversion

2021 ◽  
Author(s):  
Lin Li ◽  
Helmut Beckers ◽  
Tony Stüker ◽  
Tilen Lindič ◽  
Tobias Schlöder ◽  
...  
Keyword(s):  
Transition Metal ◽  
Ligand Field ◽  
Late Transition Metal ◽  
Late Transition ◽  
Oxo Compounds ◽  
High Valent ◽  
Oxygen Bond ◽  
Field Inversion ◽  
Oxo Ligands

High-valent late transition metal oxo compounds attracted attention because of their peculiar metal–oxygen bond. Their oxo ligands exhibit an electrophilic and distinct radical oxyl (O˙−) rather than the more common nucleophilic (O2−) character.

Dispersion Forces, Disproportionation, and Stable High-Valent Late Transition Metal Alkyls

2016 ◽  
Vol 128 (47) ◽  
pp. 14986-14989 ◽  
Author(s):  
David J. Liptrot ◽  
Jing-Dong Guo ◽  
Shigeru Nagase ◽  
Philip P. Power
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Dispersion Forces ◽  
Late Transition ◽  
High Valent ◽  
Metal Alkyls

Dispersion Forces, Disproportionation, and Stable High-Valent Late Transition Metal Alkyls

2016 ◽  
Vol 55 (47) ◽  
pp. 14766-14769 ◽  
Author(s):  
David J. Liptrot ◽  
Jing-Dong Guo ◽  
Shigeru Nagase ◽  
Philip P. Power
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Dispersion Forces ◽  
Late Transition ◽  
High Valent ◽  
Metal Alkyls

Late transition metal-oxo compounds and open-framework materials that catalyze aerobic oxidations

2008 ◽  
pp. 245-272 ◽  
Author(s):  
Rui Cao ◽  
Jong Woo Han ◽  
Travis M. Anderson ◽  
Daniel A. Hillesheim ◽  
Kenneth I. Hardcastle ◽  
...  
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Open Framework ◽  
Framework Materials ◽  
Late Transition ◽  
Oxo Compounds

ChemInform Abstract: Late Transition Metal-Oxo Compounds and Open-Framework Materials That Catalyze Aerobic Oxidations

ChemInform ◽  
2009 ◽  
Vol 40 (52) ◽  
Author(s):  
Rui Cao ◽  
Jong Woo Han ◽  
Travis M. Anderson ◽  
Daniel A. Hillesheim ◽  
Kenneth I. Hardcastle ◽  
...  
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Open Framework ◽  
Framework Materials ◽  
Late Transition ◽  
Oxo Compounds

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

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