scholarly journals A perfect triangular dysprosium single-molecule magnet with virtually antiparallel Ising-like anisotropy

2020 ◽  
Vol 7 (16) ◽  
pp. 2941-2948
Author(s):  
Guang Lu ◽  
Yang Liu ◽  
Wei Deng ◽  
Guo-Zhang Huang ◽  
Yan-Cong Chen ◽  
...  
Keyword(s):  
Magnetic Dipole ◽  
Single Molecule ◽  
Ground State ◽  
Dipole Interaction ◽  
Magnetic Axis ◽  
Magnetic Dipole Interaction ◽  
Single Molecule Magnet

A perfect triangular Dy3 single-molecule magnet was reported. Each Dy(iii) magnetic axis is oriented almost normal to the plane of Dy3, and the intramolecular magnetic dipole interaction gives rise to a virtually antiparallel Ising-like ground state.

Magnetic dipole interaction studied by the differential angular correlation method

1963 ◽  
Vol 40 ◽  
pp. 656-669 ◽  
Author(s):  
E. Matthias ◽  
L. Boström ◽  
Alice Maciel ◽  
M. Salomon ◽  
T. Lindqvist
Keyword(s):  
Angular Correlation ◽  
Magnetic Dipole ◽  
Correlation Method ◽  
Dipole Interaction ◽  
Magnetic Dipole Interaction

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIIITrinuclear Single-Molecule Magnet with anST=9/2Spin Ground State

2005 ◽  
Vol 127 (9) ◽  
pp. 3090-3099 ◽  
Author(s):  
Marilena Ferbinteanu ◽  
Hitoshi Miyasaka ◽  
Wolfgang Wernsdorfer ◽  
Kazuya Nakata ◽  
Ken-ichi Sugiura ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Single Chain ◽  
Single Molecule Magnet

DFT Computational Rationalization of an Unusual Spin Ground State in an Mn12 Single-Molecule Magnet with a Low-Symmetry Loop Structure

2005 ◽  
Vol 117 (6) ◽  
pp. 919-923 ◽  
Author(s):  
Dolos Foguet-Albiol ◽  
Ted A. O'Brien ◽  
Wolfgang Wernsdorfer ◽  
Brian Moulton ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Loop Structure ◽  
Single Molecule Magnet ◽  
Low Symmetry ◽  
Spin Ground State

scholarly journals Influence of the supramolecular architecture on the magnetic properties of a DyIII single-molecule magnet: an ab initio investigation

2014 ◽  
Vol 5 ◽  
pp. 2267-2274 ◽  
Author(s):  
Julie Jung ◽  
Olivier Cador ◽  
Kevin Bernot ◽  
Fabrice Pointillart ◽  
Javier Luzon ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Magnetic Properties ◽  
Single Molecule ◽  
Ground State ◽  
Supramolecular Interactions ◽  
Supramolecular Organization ◽  
Supramolecular Architecture ◽  
Magnetic Ground State ◽  
Single Molecule Magnet ◽  
Hydrogen Bond Networks

Single-crystal angular-resolved magnetometry and wavefunction-based calculations have been used to reconsider the magnetic properties of a recently reported DyIII-based single-molecule magnet, namely [Dy(hfac)3(L1)] with hfac− = 1,1,1,5,5,5-hexafluoroacetylacetonate and L1 = 2-(4,5-bis(propylthio)-1,3-dithiol-2-ylidene)-6-(pyridin-2-yl)-5H-[1,3]dithiolo[4',5':4,5]benzo[1,2-d]imidazole. The magnetic susceptibility and magnetization at low temperature are found to be strongly influenced by supramolecular interactions. Moreover, taking into account the hydrogen-bond networks in the calculations allows to explain the orientation of the magnetic axes. This strongly suggests that hydrogen bonds play an important role in the modulation of the electrostatic environment around the DyIII center that governs the nature of its magnetic ground-state and the orientation of its anisotropy axes. We thus show here that SMM properties that rely on supramolecular organization may not be transferable into single-molecule devices.

scholarly journals An iron ketimide single-molecule magnet [Fe4(NCPh2)6] with suppressed through-barrier relaxation

2020 ◽  
Vol 11 (18) ◽  
pp. 4753-4757
Author(s):  
Andrew W. Cook ◽  
Joshua D. Bocarsly ◽  
Richard A. Lewis ◽  
Alexander J. Touchton ◽  
Simona Morochnik ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Single Molecule Magnet

The tetrametallic Fe ketimide cluster, [Fe4(NCPh2)6], exhibits a thermally persistent S = 7 ground-state along with single molecule magnet behavior.

Sign in / Sign up

Export Citation Format

Share Document