Chiral helical polymer materials derived from achiral monomers and their chiral applications

2020 ◽  
Vol 11 (34) ◽  
pp. 5407-5423
Author(s):  
Yingjie Zhang ◽  
Jianping Deng

Helix-sense-selective polymerization (HSSP) of achiral monomers and chiral post-induction of racemic helical polymers provide two alternative approaches for constructing chiral helical polymer materials.

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1857
Author(s):  
Adrián Álvarez-Vázquez ◽  
Miguel Muñiz-Calvente ◽  
Pelayo Fernández Fernández ◽  
Alfonso Fernández-Canteli ◽  
María Jesús Lamela-Rey ◽  
...  

Many design scenarios of components made of polymer materials are concerned with notches as representative constructive details. The failure hazard assessment of these components using models based on the assumption of cracked components leads to over-conservative failure estimations. Among the different alternative approaches proposed that are based on the apparent fracture toughness, KcN is considered. In so doing, the current deterministic underlying concept must be replaced by a probabilistic one to take into account the variability observed in the failure results in order to ensure a reliable design. In this paper, an approach based on the critical distance principle is proposed for the failure assessment of notched EPOLAM 2025 CT samples with each different notch radii (ρ) including a probabilistic assessment of the failure prediction. First, each apparent fracture toughness is transformed into the equivalent fracture toughness for ρ=0 based on the critical distances theory. Then, once all results are normalized to the same basic conditions, a Weibull cumulative distribution function is fitted, allowing the probability of failure to be predicted for different notch radii. In this way, the total number of the specimens tested in the experimental campaign is reduced, whereas the reliability of the material characterization improves. Finally, the applicability of the proposed methodology is illustrated by an example using the own experimental campaign performed on EPOLAM 2025 CT specimens with different notch radii (ρ).


2020 ◽  
Vol 11 (31) ◽  
pp. 8224-8230 ◽  
Author(s):  
Jupen Liu ◽  
Zhonglong Luo ◽  
Le Yu ◽  
Ping Zhang ◽  
Hongqiu Wei ◽  
...  

Passerini multicomponent polymerization-induced assembly is reported to design a water-soluble, AIE-active, double-helical polymer with reversible multi-responsiveness to external stimuli and rapid visible-light degradability.


RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 59066-59072 ◽  
Author(s):  
Biao Zhao ◽  
Jianping Deng

Micelles provide microenvironment effects for asymmetric polymerization: an unprecedented methodology for controlling the preferential helicity of synthetic helical polymers.


2017 ◽  
Vol 8 (24) ◽  
pp. 3740-3745 ◽  
Author(s):  
Sandra Arias ◽  
Manuel Núñez-Martínez ◽  
Emilio Quiñoá ◽  
Ricardo Riguera ◽  
Félix Freire

Macroscopically enantiomeric chiral nanospheres made from P or M helical polymer metal complexes can be obtained via dynamic coordination chemistry.


2021 ◽  
Vol 12 (13) ◽  
pp. 1857-1897
Author(s):  
Randall A. Scanga ◽  
James F. Reuther

This review surveys recent progress towards robust chiral nanostructure fabrication techniques using synthetic helical polymers, the unique inferred properties that these materials possess, and their intricate connection to natural, biological chirality.


2015 ◽  
Vol 51 (52) ◽  
pp. 10423-10426 ◽  
Author(s):  
Zhaozhong Yi ◽  
Hitoshi Okuda ◽  
Yasuhito Koyama ◽  
Ryota Seto ◽  
Satoshi Uchida ◽  
...  

Two types of one-handed exact helical polymers, coil- and screw-shaped polymers, were selectively synthesized by a two-point-covalent-linking protocol.


Nanoscale ◽  
2017 ◽  
Vol 9 (45) ◽  
pp. 17752-17757 ◽  
Author(s):  
Rafael Rodríguez ◽  
Sandra Arias ◽  
Emilio Quiñoá ◽  
Ricardo Riguera ◽  
Félix Freire

The secondary structure of chiral helical polymers forming helical polymer–metal complexes (HPMCs) plays a major role in their subsequent nanostructuration.


Author(s):  
D.T. Grubb

Diffraction studies in polymeric and other beam sensitive materials may bring to mind the many experiments where diffracted intensity has been used as a measure of the electron dose required to destroy fine structure in the TEM. But this paper is concerned with a range of cases where the diffraction pattern itself contains the important information.In the first case, electron diffraction from paraffins, degraded polyethylene and polyethylene single crystals, all the samples are highly ordered, and their crystallographic structure is well known. The diffraction patterns fade on irradiation and may also change considerably in a-spacing, increasing the unit cell volume on irradiation. The effect is large and continuous far C94H190 paraffin and for PE, while for shorter chains to C 28H58 the change is less, levelling off at high dose, Fig.l. It is also found that the change in a-spacing increases at higher dose rates and at higher irradiation temperatures.


Author(s):  
E. Loren Buhle ◽  
Pamela Rew ◽  
Ueli Aebi

While DNA-dependent RNA polymerase represents one of the key enzymes involved in transcription and ultimately in gene expression in procaryotic and eucaryotic cells, little progress has been made towards elucidation of its 3-D structure at the molecular level over the past few years. This is mainly because to date no 3-D crystals suitable for X-ray diffraction analysis have been obtained with this rather large (MW ~500 kd) multi-subunit (α2ββ'ζ). As an alternative, we have been trying to form ordered arrays of RNA polymerase from E. coli suitable for structural analysis in the electron microscope combined with image processing. Here we report about helical polymers induced from holoenzyme (α2ββ'ζ) at low ionic strength with 5-7 mM MnCl2 (see Fig. 1a). The presence of the ζ-subunit (MW 86 kd) is required to form these polymers, since the core enzyme (α2ββ') does fail to assemble into such structures under these conditions.


Sign in / Sign up

Export Citation Format

Share Document