Sustainable alternative to bisphenol A epoxy resin: high-performance recyclable epoxy vitrimers derived from protocatechuic acid

2020 ◽  
Vol 11 (27) ◽  
pp. 4500-4506 ◽  
Author(s):  
Yangqing Tao ◽  
Linxuan Fang ◽  
Menglu Dai ◽  
Caiyun Wang ◽  
Jing Sun ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
Epoxy Resins ◽  
High Performance ◽  
Protocatechuic Acid ◽  
High Efficiency ◽  
Thermal And Mechanical Properties ◽  
Naoh Solution

A series of epoxy vitrimers were prepared based on protocatechuic acid, which showed better thermal and mechanical properties than commercial BPA-based epoxy resins. The vitrimers can be reprocessed in high efficiency and degraded in NaOH solution.

Solvent Exchange to Exfoliate Graphene Oxides into Epoxy with Improved Mechanical and Thermal Properties

2015 ◽  
Vol 1110 ◽  
pp. 69-72
Author(s):  
Fu Ke Wang ◽  
Chao Bin He
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Epoxy Resins ◽  
Mechanical And Thermal Properties ◽  
Curing Agent ◽  
Solvent Exchange ◽  
Thermal And Mechanical Properties ◽  
Graphene Oxides ◽  
Curing Agents ◽  
Exchange Technique

The dispersion and exfoliation of graphene oxides in polymer matrix remains a challenge for graphene oxides based epoxy nanocomposites fabrication. In the present paper, we reported a simple and facile solvent exchange technique to successfully transfer graphene oxides (GOs) from aqueous solution to ethanol. In addition, we found that GO dispersion in epoxy resins was affected by the curing agents. Good dispersion of GOs in epoxy resin together with enhanced thermal and mechanical properties were observed when epoxy was cured with aliphatic curing agents. For aromatic curing agent, high loading of GOs leaded to GOs aggregation, but well dispersed GOs was observed at low loading of GOs. Especially, a 12 °C increase of glass transition temperature of the epoxy resin was observed with only 0.1 wt% GOs was added to the epoxy resin.

The Mechanical Properties of Organic Modified Epoxy Resin

2020 ◽  
Vol 43 (3) ◽  
pp. 10-14
Author(s):  
Georgel MIHU ◽  
Claudia Veronica UNGUREANU ◽  
Vasile BRIA ◽  
Marina BUNEA ◽  
Rodica CHIHAI PEȚU ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Composite Materials ◽  
Epoxy Resin ◽  
Epoxy Matrix ◽  
Epoxy Resins ◽  
Mechanical Tests ◽  
Organic Modification ◽  
Three Point Bending ◽  
Modified Epoxy

Epoxy resins have been presenting a lot of scientific and technical interests and organic modified epoxy resins have recently receiving a great deal of attention. For obtaining the composite materials with good mechanical proprieties, a large variety of organic modification agents were used. For this study gluten and gelatin had been used as modifying agents thinking that their dispersion inside the polymer could increase the polymer biocompatibility. Equal amounts of the proteins were milled together and the obtained compound was used to form 1 to 5% weight ratios organic agents modified epoxy materials. To highlight the effect of these proteins in epoxy matrix mechanical tests as three-point bending and compression were performed.

scholarly journals Studies on the Modification of Commercial Bisphenol-A-Based Epoxy Resin Using Different Multifunctional Epoxy Systems

2021 ◽  
Vol 2 (2) ◽  
pp. 419-430
Author(s):  
Ankur Bajpai ◽  
James R. Davidson ◽  
Colin Robert
Keyword(s):  
Mechanical Properties ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
Tensile Fracture ◽  
Chemical Structures ◽  
Amino Phenol ◽  
Epoxy Systems

The tensile fracture mechanics and thermo-mechanical properties of mixtures composed of two kinds of epoxy resins of different chemical structures and functional groups were studied. The base resin was a bi-functional epoxy resin based on diglycidyl ether of bisphenol-A (DGEBA) and the other resins were (a) distilled triglycidylether of meta-amino phenol (b) 1, 6–naphthalene di epoxy and (c) fluorene di epoxy. This research shows that a small number of multifunctional epoxy systems, both di- and tri-functional, can significantly increase tensile strength (14%) over neat DGEBA while having no negative impact on other mechanical properties including glass transition temperature and elastic modulus. In fact, when compared to unmodified DGEBA, the tri-functional epoxy shows a slight increase (5%) in glass transition temperature at 10 wt.% concentration. The enhanced crosslinking of DGEBA (90 wt.%)/distilled triglycidylether of meta-amino phenol (10 wt.%) blends may be the possible reason for the improved glass transition. Finally, the influence of strain rate, temperature and moisture were investigated for both the neat DGEBA and the best performing modified system. The neat DGEBA was steadily outperformed by its modified counterpart in every condition.

scholarly journals Thermal and mechanical properties of epoxy resin reinforced with modified iron oxide nanoparticles

2021 ◽  
pp. 50533
Author(s):  
Yasmine N. Baghdadi ◽  
Lucia Youssef ◽  
Kamal Bouhadir ◽  
Mohammad Harb ◽  
Samir Mustapha ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Iron Oxide ◽  
Epoxy Resin ◽  
Iron Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Thermal And Mechanical Properties

BPA-Free High-Performance Sustainable Polycarbonates Derived from Non-Estrogenic Bio-Based Phenols

2021 ◽  
Author(s):  
Michael Garrison ◽  
Perrin Storch ◽  
William S. Eck ◽  
Valerie Adams ◽  
Patrick Fedick ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Epoxy Resins ◽  
High Performance ◽  
High Volume ◽  
Endocrine Disrupter

Bisphenol A (BPA) is a versatile petrochemical used in the preparation of high volume polymers including polycarbonates and epoxy resins. Unfortunately, BPA is also an endocrine disrupter and has been...

Effect of alkali treatment on mechanical properties of jute fiber-reinforced partially biodegradable green composites using epoxy resin matrix

2019 ◽  
Vol 28 (6) ◽  
pp. 388-397
Author(s):  
Jai Inder Preet Singh ◽  
Sehijpal Singh ◽  
Vikas Dhawan
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Alkali Treatment ◽  
Matrix Material ◽  
Resin Matrix ◽  
Infrared Analysis ◽  
Test Results ◽  
Green Composites ◽  
Jute Fibers ◽  
Naoh Solution

In this work, partially biodegradable green composites have been developed with the help of compression molding technique. Jute fibers were selected as a reinforcement and epoxy resin as matrix material. The influence of alkali treatment on various mechanical properties of jute/epoxy composites was investigated, with concentrations ranging from 1%, 3%, 5%, 7%, and 9% NaOH solution. Various test results indicate that with an increase in concentration, tensile and flexural strength increases up to 5% concentration of NaOH, thereafter both the properties decrease, but impact strength increases up to 7% concentration and thereafter decreases. The results of mechanical characterizations were further validated through the study of morphology with scanning electron microscopy and Fourier transform infrared analysis. The optimal concentration of 5% concentration for alkali treatment of fibers have been suggested.

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