Polyester nitrile N-oxides for click reactions synthesized with nitroalkane precursors as the initiator

2020 ◽  
Vol 11 (18) ◽  
pp. 3115-3119 ◽  
Author(s):  
Toyokazu Tsutsuba ◽  
Hiromitsu Sogawa ◽  
Toshikazu Takata
Keyword(s):  
Click Reaction ◽  
Polymer Synthesis ◽  
Star Polymer ◽  
Click Reactions ◽  
Catalyst Free

Polyesters that have a nitrile N-oxide function at the initiation end were prepared and applied to a catalyst-free click reaction for star polymer synthesis.

Star-polymer synthesis via radical reversible addition-fragmentation chain-transfer polymerization

2001 ◽  
Vol 39 (16) ◽  
pp. 2777-2783 ◽  
Author(s):  
Martina Stenzel-Rosenbaum ◽  
Thomas P. Davis ◽  
Vicki Chen ◽  
Anthony G. Fane
Keyword(s):  
Chain Transfer ◽  
Polymer Synthesis ◽  
Star Polymer ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

scholarly journals SYNTHESIS OF AN AZIDE–THIOL LINKER FOR HETEROGENEOUS POLYMER FUNCTIONALIZATION VIA THE “CLICK” REACTION

2018 ◽  
Vol 55 (1B) ◽  
pp. 152
Author(s):  
Thuy Thu Truong
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Click Reaction ◽  
Proton Nuclear Magnetic Resonance ◽  
Reaction Yield ◽  
Reaction Conditions ◽  
Click Reactions ◽  
Heterogeneous Polymer ◽  
Ft Ir ◽  
First Time ◽  
Layer Chromatography

In this study, the synthesis of a telechelic linker bearing both azide and thiol functional groups was described. The reaction conditions were investigated to optimize the reaction yield. The product was analyzed using thin layer chromatography (TLC) and proton nuclear magnetic resonance (1H NMR). The employment of the obtained azide–thiol linker in heterogeneous polymer “click” functionalization was demonstrated for the first time, which was monitored by an online FT–IR method. The obtained telechelic azide–thiol linker is envisioned to be useful chemical tools to link macromolecular chains via orthogonal click reactions.

An all-optical photorefractive miktoarm star polymer synthesized via a combination of RAFT polymerization and click reaction

2019 ◽  
Vol 143 ◽  
pp. 104321 ◽  
Author(s):  
Wansheng Zong ◽  
Su Wang ◽  
Juan Li ◽  
Jintao Wang ◽  
Mingming Li ◽  
...  
Keyword(s):  
Click Reaction ◽  
Raft Polymerization ◽  
Star Polymer ◽  
All Optical ◽  
Miktoarm Star

Copper(i) complexes bearing mesoionic carbene ligands: influencing the activity in catalytic halo-click reactions

2020 ◽  
Vol 49 (43) ◽  
pp. 15504-15510
Author(s):  
Lisa Suntrup ◽  
Julia Beerhues ◽  
Oliver Etzold ◽  
Biprajit Sarkar
Keyword(s):  
Click Reaction ◽  
Carbene Ligands ◽  
Click Reactions ◽  
Dicopper Complexes

A series of mono- and dicopper complexes with mesoionic carbenes are tested as pre-catalysts for the halo-click reaction.

scholarly journals Silver-catalysed azide–alkyne cycloaddition (AgAAC): assessing the mechanism by density functional theory calculations

2016 ◽  
Vol 3 (9) ◽  
pp. 160090 ◽  
Author(s):  
Biswadip Banerji ◽  
K. Chandrasekhar ◽  
Sunil Kumar Killi ◽  
Sumit Kumar Pramanik ◽  
Pal Uttam ◽  
...  
Keyword(s):  
Density Functional ◽  
Click Reaction ◽  
Cycloaddition Reaction ◽  
Triazole Ring ◽  
Density Functional Theory Calculations ◽  
Dipolar Cycloaddition ◽  
Reaction Conditions ◽  
Functional Theory ◽  
Click Reactions ◽  
Counter Ions

‘Click reactions’ are the copper catalysed dipolar cycloaddition reaction of azides and alkynes to incorporate nitrogens into a cyclic hydrocarbon scaffold forming a triazole ring. Owing to its efficiency and versatility, this reaction and the products, triazole-containing heterocycles, have immense importance in medicinal chemistry. Copper is the only known catalyst to carry out this reaction, the mechanism of which remains unclear. We report here that the ‘click reactions’ can also be catalysed by silver halides in non-aqueous medium. It constitutes an alternative to the well-known CuAAC click reaction. The yield of the reaction varies on the type of counter ion present in the silver salt. This reaction exhibits significant features, such as high regioselectivity, mild reaction conditions, easy availability of substrates and reasonably good yields. In this communication, the findings of a new catalyst along with the effect of solvent and counter ions will help to decipher the still obscure mechanism of this important reaction.

AIE-active self-assemblies from a catalyst-free thiol-yne click reaction and their utilization for biological imaging

2018 ◽  
Vol 92 ◽  
pp. 61-68 ◽  
Author(s):  
Ruming Jiang ◽  
Meng Cao ◽  
Meiying Liu ◽  
Liangji Liu ◽  
Qiang Huang ◽  
...  
Keyword(s):  
Click Reaction ◽  
Biological Imaging ◽  
Catalyst Free ◽  
Free Thiol

Polymer Synthesis via Click Reactions

2014 ◽  
pp. 1-7
Author(s):  
Haiqiang Wu ◽  
Jingzhi Sun ◽  
Anjun Qin ◽  
Ben Zhong Tang
Keyword(s):  
Polymer Synthesis ◽  
Click Reactions

Simple Chemical Modification Using Perfluoroalkyl‐Substituted Stable Nitrile N ‐Oxide on Bulk Surface via Catalyst‐Free Click Reaction

2020 ◽  
Vol 5 (17) ◽  
pp. 5312-5315 ◽  
Author(s):  
Chen‐Gang Wang ◽  
Sumitra Cheawchan ◽  
Airong Qiagedeer ◽  
Shunsuke Monjiyama ◽  
Satoshi Uchida ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Click Reaction ◽  
Catalyst Free ◽  
Bulk Surface ◽  
Simple Chemical

Synthesis of allyl cellulose in NaOH/urea aqueous solutions and its thiol–ene click reactions

2015 ◽  
Vol 6 (18) ◽  
pp. 3543-3548 ◽  
Author(s):  
Haoze Hu ◽  
Jun You ◽  
Weiping Gan ◽  
Jinping Zhou ◽  
Lina Zhang
Keyword(s):  
Aqueous Solutions ◽  
Click Reaction ◽  
Allyl Chloride ◽  
Cellulose Derivatives ◽  
Click Reactions

Allyl cellulose can be synthesized from cellulose and allyl chloride in NaOH/urea aqueous solutions and is further used to synthesize a variety of new cellulose derivatives through the thiol–ene click reaction.

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