scholarly journals Advances in deep eutectic solvents and water: applications in metal- and biocatalyzed processes, in the synthesis of APIs, and other biologically active compounds

2021 ◽  
Author(s):  
Luciana Cicco ◽  
Giuseppe Dilauro ◽  
Filippo Maria Perna ◽  
Paola Vitale ◽  
Vito Capriati
Keyword(s):  
Deep Eutectic Solvents ◽  
Biologically Active Compounds ◽  
Biologically Active ◽  
Active Compounds ◽  
Recent Advances ◽  
Environmentally Responsible

This review highlights recent advances in metal- and biocatalyzed transformations, in the synthesis of APIs and other biologically active compounds, when employing deep eutectic solvents and water as environmentally responsible solvents.

Recent Advances in the Green Synthesis of Heterocycles: From Building Blocks to Biologically Active Compounds

2021 ◽  
Vol 18 ◽  
Author(s):  
Christian Schäfer ◽  
Hyejin Cho ◽  
Bernadett Vlocskó ◽  
Guoshu Xie ◽  
Béla Török
Keyword(s):  
Green Synthesis ◽  
Building Blocks ◽  
Biologically Active Compounds ◽  
Biologically Active ◽  
Environmentally Benign ◽  
Active Compounds ◽  
Aromatic Heterocycles ◽  
High Interest ◽  
Recent Advances ◽  
Benign Synthesis

: Recent advances in the environmentally benign synthesis of common heterocycles are described. This account features three main parts; the preparation of non-aromatic heterocycles, one-ring aromatic heterocycles and their condensed analogs. Due to the great variety of and high interest in these compounds, this work focuses on providing representative examples of the preparation of the target compounds.

scholarly journals Electrophilic Iodination of Organic Compounds Using Elemental Iodine or Iodides: Recent Advances 2008–2021: Part I

Compounds ◽  
2022 ◽  
Vol 2 (1) ◽  
pp. 3-24
Author(s):  
Njomza Ajvazi ◽  
Stojan Stavber
Keyword(s):  
Organic Chemistry ◽  
Organic Compounds ◽  
Biologically Active Compounds ◽  
Biologically Active ◽  
Present Review ◽  
Active Compounds ◽  
Synthetic Organic Chemistry ◽  
Recent Advances ◽  
Elemental Iodine

The iodination of organic compounds is of great importance in synthetic organic chemistry. It opens comprehensive approaches for the synthesis of various biologically active compounds. The recent advances in iodination of organic compounds using elemental iodine or iodides, covering the last thirteen years, are the objective of the present review.

Recent advances in the catalytic synthesis of 3-aminooxindoles: an update

2020 ◽  
Vol 18 (25) ◽  
pp. 4692-4708 ◽  
Author(s):  
Jasneet Kaur ◽  
Banni Preet Kaur ◽  
Swapandeep Singh Chimni
Keyword(s):  
Natural Products ◽  
Catalytic Synthesis ◽  
Biologically Active Compounds ◽  
Core Structure ◽  
Biologically Active ◽  
Active Compounds ◽  
The Core ◽  
Recent Advances

3-Substituted-3-aminooxindoles are versatile scaffolds and these motifs constitute the core structure of number of natural products and biologically active compounds.

Catalytic, Enantioselective Diamination of Alkenes

Synthesis ◽  
2021 ◽  
Author(s):  
Scott E. Denmark ◽  
Zhong-Lin Tao
Keyword(s):  
Asymmetric Synthesis ◽  
Reaction Mechanisms ◽  
Short Review ◽  
Biologically Active Compounds ◽  
Biologically Active ◽  
Active Compounds ◽  
Recent Advances ◽  
Vicinal Diamines

AbstractEnantioselective diamination of alkenes represents one of the most straightforward methods to access enantioenriched, vicinal diamines, which are not only frequently encountered in biologically active compounds, but also have broad applications in asymmetric synthesis. Although the analogous dihydroxylation of olefins is well-established, the development of enantioselective olefin diamination lags far behind. Nevertheless, several successful methods have been developed that operate by different reaction mechanisms, including a cycloaddition pathway, a two-electron redox pathway, and a radical pathway. This short review summarizes recent advances and identifies limitations, with the aim of inspiring further developments in this area.1 Introduction2 Cycloaddition Pathway3 Two-Electron Redox Pathway3.1 Pd(0)/Pd(II) Diamination3.2 Pd(II)/Pd(IV) Diamination3.3 I(I)/I(III) Diamination3.4 Se(II)/Se(IV) Diamination4 One-Electron Radical Pathway4.1 Cu-Catalyzed Diamination4.2 Fe-Catalyzed Diamination5 Summary and Outlook

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