Understanding the sigmatropic shifts of cyclopenta-2,4-dien-1-yltrimethylsilane in its Diels–Alder addition

2021 ◽  
Author(s):  
Min Zhang ◽  
Guangchao Liang
Keyword(s):  
Diels Alder ◽  
Dominant Factor ◽  
Dynamic Processes ◽  
Hydrogen Shifts

Investigation on the dynamic processes of 1-(C5H5)Si(Me)3 in its Diels–Alder addition showed that Si(Me)3 migration is the dominant factor and hydrogen shifts are negligible.

Surface reactions observed by photoemission electron microscopy (PEEM)

1992 ◽  
Vol 50 (1) ◽  
pp. 286-287
Author(s):  
H.H. Rotermund
Keyword(s):  
Electron Microscopy ◽  
Electron Microscope ◽  
Work Function ◽  
Chemical Reactions ◽  
Reaction Diffusion ◽  
Dynamic Processes ◽  
Clean Surface ◽  
Crystal Surfaces ◽  
Single Crystal Surfaces ◽  
Photoemission Electron

Chemical reactions at a surface will in most cases show a measurable influence on the work function of the clean surface. This change of the work function δφ can be used to image the local distributions of the investigated reaction,.if one of the reacting partners is adsorbed at the surface in form of islands of sufficient size (Δ>0.2μm). These can than be visualized via a photoemission electron microscope (PEEM). Changes of φ as low as 2 meV give already a change in the total intensity of a PEEM picture. To achieve reasonable contrast for an image several 10 meV of δφ are needed. Dynamic processes as surface diffusion of CO or O on single crystal surfaces as well as reaction / diffusion fronts have been observed in real time and space.

Thrombelastography during and after Elective Abdominal Surgery

1978 ◽  
Vol 39 (02) ◽  
pp. 488-495 ◽  
Author(s):  
J M Butler
Keyword(s):  
Abdominal Surgery ◽  
Factor Viii ◽  
Whole Blood ◽  
Dominant Factor ◽  
Fibrinogen Concentration ◽  
Factor Viii Activity ◽  
Elective Abdominal Surgery

SummaryThrombelastography has been performed on recalcified whole blood from 50 patients before, during and after elective abdominal surgery. The characteristic changes of the thrombelastographic indices r, k and mA are described.During operation r and k shortened, but no change in mA was observed. This response was in part associated with an increase in factor VIII activity. Following operation, while r time was somewhat shortened, much more marked changes in k and mA were evident. Increasing fibrinogen concentration was the dominant factor in determining the post-operative changes in the thrombelastograph.

The Diels-Alder Reaction of 2-Ethenyl-1,4-Benzodioxin: A New and Simple Synthesis of Bisaryl Ethers

Synlett ◽  
1989 ◽  
Vol 1989 (01) ◽  
pp. 30-32
Author(s):  
Thomas V. Lee ◽  
Alistair J. Leigh ◽  
Christopher B. Chapleo
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Simple Synthesis ◽  
Diels Alder Reaction

Effect of No-load and Load Condition on Transformer Sound

2018 ◽  
pp. 11-15
Author(s):  
Dr. Hitesh Paghadar
Keyword(s):  
Experimental Study ◽  
Power Transformer ◽  
Load Condition ◽  
Noise Pollution ◽  
Sound Level ◽  
Measurement Scale ◽  
Dominant Factor ◽  
Public Attention ◽  
Level Measurement ◽  
Human Ear

Increasing environment noise pollution is a matter of great concern and of late has been attracting public attention. Sound produces the minute oscillatory changes in air pressure and is audible to the human ear when in the frequency range of 20Hz to 20 kHz. The chief sources of audible sound are the magnetic circuit of transformer which produces sound due to magnetostriction phenomenon, vibration of windings, tank and other structural parts, and the noise produced by cooling equipments. This paper presents the validation for sound level measurement scale, why A-weighted scale is accepted for sound level measurement, experimental study carried out on 10MVA Power Transformer. Also presents the outcomes of comparison between No-Load sound & Load sound level measurement, experimental study carried out on different transformer like - 10MVA, 50MVA, 100MVA Power Transformer, to define the dominant factor of transformer sound generation.

Dynamic processes in dielectric glasses at low temperatures

1982 ◽  
Vol 136 (2) ◽  
pp. 317 ◽  
Author(s):  
B.P. Smolyakov ◽  
E.P. Khaimovich
Keyword(s):  
Low Temperatures ◽  
Dynamic Processes

TO THE STABILITY OF TANK VEHICLES IN THE BRAKE MODE

2019 ◽  
pp. 27-32
Author(s):  
Denys Popelysh ◽  
Yurii Seluk ◽  
Sergyi Tomchuk
Keyword(s):  
Mathematical Model ◽  
Control Systems ◽  
Distribution Systems ◽  
Traffic Accidents ◽  
Road Traffic ◽  
Center Of Mass ◽  
Dynamic Processes ◽  
Course Stability ◽  
The Stability ◽  
Tank Vehicles

This article discusses the question of the possibility of improving the roll stability of partially filled tank vehicles while braking. We consider the dangers associated with partially filled tank vehicles. We give examples of the severe consequences of road traffic accidents that have occurred with tank vehicles carrying dangerous goods. We conducted an analysis of the dynamic processes of fluid flow in the tank and their influence on the basic parameters of the stability of vehicle. When transporting a partially filled tank due to the comparability of the mass of the empty tank with the mass of the fluid being transported, the dynamic qualities of the vehicle change so that they differ significantly from the dynamic characteristics of other vehicles. Due to large displacements of the center of mass of cargo in the tank there are additional loads that act vehicle and significantly reduce the course stability and the drivability. We consider the dynamics of liquid sloshing in moving containers, and give examples of building a mechanical model of an oscillating fluid in a tank and a mathematical model of a vehicle with a tank. We also considered the method of improving the vehicle’s stability, which is based on the prediction of the moment of action and the nature of the dynamic processes of liquid cargo and the implementation of preventive actions by executive mechanisms. Modern automated control systems (anti-lock brake system, anti-slip control systems, stabilization systems, braking forces distribution systems, floor level systems, etc.) use a certain list of elements for collecting necessary parameters and actuators for their work. This gives the ability to influence the course stability properties without interfering with the design of the vehicle only by making changes to the software of these systems. Keywords: tank vehicle, roll stability, mathematical model, vehicle control systems.

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