Recent progress of transition metal-catalysed regioselective C–H transformations based on noncovalent interactions

2020 ◽  
Vol 18 (22) ◽  
pp. 4126-4134 ◽  
Author(s):  
Yoichiro Kuninobu ◽  
Takeru Torigoe
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Noncovalent Interactions ◽  
Recent Advances

Recent advances in the transition metal-catalysed regioselective C–H transformations controlled by noncovalent interactions between substrates and reagents or ligands are summarised.

Recent advances in transition metal based compound catalysts for water splitting from the perspective of crystal engineering

CrystEngComm ◽  
2020 ◽  
Vol 22 (9) ◽  
pp. 1531-1540 ◽  
Author(s):  
Min Ju ◽  
Xiaoting Wang ◽  
Xia Long ◽  
Shihe Yang
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Crystal Engineering ◽  
Recent Progress ◽  
Recent Advances

A review of the recent progress on the transition metal based catalysts for water splitting with emphasis on crystal engineering.

Recent advances on transition-metal-catalysed asymmetric reductive amination

2021 ◽  
Author(s):  
Yingying Tian ◽  
Le'an Hu ◽  
Yuan-Zheng Wang ◽  
Xumu Zhang ◽  
Qin Yin
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Reductive Amination ◽  
Nitrogen Sources ◽  
Recent Advances

This review focuses on the recent progress of homogeneous transition-metal-catalysed asymmetric reductive amination of ketones with diverse nitrogen sources.

Catalytic Deoxygenative Cyclopropanation of 1,2-Dicarbonyl or Monocarbonyl Compounds via Molybdenum Catalysis

Synlett ◽  
2021 ◽  
Author(s):  
Jia-Le Wang ◽  
Chun-Xiang Zhuo
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Diazo Compounds ◽  
Recent Advances ◽  
Metal Carbenes ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The cyclopropanation of alkenes through the transition-metal-catalyzed decomposition of diazo compounds is a powerful and straightforward strategy to produce cyclopropanes. Nevertheless, the appeal of further application of this strategy is tempered by the potentially explosive nature of the diazo substrates. Therefore, it is highly desirable to develop sustainable and operationally safe surrogates for diazo compounds. In this synpacts article, we discuss recent advances on the cyclopropane syntheses through the catalytic cyclopropanation of alkenes and metal-carbenes generated in-situ from non-diazo precursors, as well as highlight our recent progress on the unprecedented molybdenum-catalyzed deoxygenative cyclopropanation reaction of 1,2-dicarbonyl or monocarbonyl compounds.

Recent advances in transition-metal-catalyzed reactions of alkynes with isoxazoles

2017 ◽  
Vol 15 (40) ◽  
pp. 8483-8492 ◽  
Author(s):  
Long Li ◽  
Tong-De Tan ◽  
Ying-Qi Zhang ◽  
Xin Liu ◽  
Long-Wu Ye
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Efficient Synthesis ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Catalyzed Reactions ◽  
Metal Catalyzed

In this review, recent progress in the transition-metal-catalyzed formal annulations of alkynes with isoxazoles for the efficient synthesis of N-heterocycles is discussed.

Recent Progress in Amination Enabled by Transition-Metal-Free C(sp2)–O/C(sp2)–S Bond Cleavage Strategy

Synthesis ◽  
2021 ◽  
Author(s):  
Xin-Ge Yang ◽  
Xue-Qiang Wang ◽  
Shen-Huan Li ◽  
Cheng-Yu Long
Keyword(s):  
Transition Metal ◽  
Natural Product ◽  
Aromatic Amines ◽  
Recent Progress ◽  
Bond Cleavage ◽  
Metal Free ◽  
Complementary Methods ◽  
The Past ◽  
Recent Advances ◽  
Metal Catalyzed

AbstractRecently, intense efforts have been dedicated to the development of novel synthetic strategies to access aromatic amines due to their importance in the pharmaceuticals, agrochemicals, materials, and natural product areas. Although numerous transition-metal-catalyzed C–N formation strategies have been described for the preparation of aromatic amines in the past few decades, complementary methods under transition-metal-free conditions are still required. We present the recent advances in the exploration of innovative amination approaches via C(sp2)–O/C(sp2)–S bond cleavage in this review.1 Introduction2 Stoichiometric Base-Promoted Amination3 Base-Catalyzed Amination4 Photoredox-Catalyzed Amination5 Acid-Promoted Amination6 Conclusion and Perspectives

Recent progress of transition metal nitrides for efficient electrocatalytic water splitting

2019 ◽  
Vol 3 (2) ◽  
pp. 366-381 ◽  
Author(s):  
Xiang Peng ◽  
Chaoran Pi ◽  
Xuming Zhang ◽  
Shuai Li ◽  
Kaifu Huo ◽  
...  
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Recent Progress ◽  
Metal Nitrides ◽  
Transition Metal Nitrides ◽  
Metal Nitride ◽  
Transition Metal Nitride ◽  
Recent Advances ◽  
Electrochemical Water Splitting

Recent advances in transition metal nitride-based catalysts for efficient electrochemical water splitting have been reviewed.

Recent Advances in Cobalt-Catalyzed Csp2 and Csp3 Cross-Couplings

Synthesis ◽  
2017 ◽  
Vol 49 (17) ◽  
pp. 3887-3894 ◽  
Author(s):  
Jeffrey Hammann ◽  
Maximilian Hofmayer ◽  
Ferdinand Lutter ◽  
Lucie Thomas ◽  
Paul Knochel
Keyword(s):  
Transition Metal ◽  
Recent Progress ◽  
Cross Coupling ◽  
Short Review ◽  
Review Article ◽  
Transition Metal Catalysis ◽  
Coupling Reactions ◽  
Metal Catalysis ◽  
Cross Coupling Reactions ◽  
Recent Advances

The present short review article highlights recent progress in the field of transition-metal catalysis. An overview on recent work involving cobalt-catalyzed cross-coupling reactions and some recent advances from our laboratories are given.1 Introduction2 Csp2–Csp2 Cobalt-Catalyzed Cross-Couplings3 Csp2–Csp3 Cobalt-Catalyzed Cross-Couplings4 Conclusion

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

Recent advances of layered-transition metal oxides for energy-related applications

2021 ◽  
Vol 36 ◽  
pp. 514-550
Author(s):  
Zhihao Lei ◽  
Jang Mee Lee ◽  
Gurwinder Singh ◽  
C.I. Sathish ◽  
Xueze Chu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Recent Advances ◽  
Layered Transition Metal

Recent advances in transition metal-catalyzed asymmetric electrocatalysis

2021 ◽  
Vol 444 ◽  
pp. 214065
Author(s):  
Priyanka Chakraborty ◽  
Rajib Mandal ◽  
Nidhi Garg ◽  
Basker Sundararaju
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed
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