Hybrid cobalt-manganese oxides prepared by ordered steps with a ternary nanosheets structure and its high performance as binder-free electrode for energy storage

Nanoscale ◽  
2021 ◽  
Author(s):  
Qingjie Lu ◽  
Shiqiang Zhou ◽  
Mingpeng Chen ◽  
Bo Li ◽  
Haitang Wei ◽  
...  

Owing to without any additive in the preparation processes, binder-free electrodes for supercapacitors have attracted much attentions. Herein, a hybrid metal oxide which composed with graphene oxide (Co3O4/MnO2/GO) is prepared...

2018 ◽  
Vol 6 (18) ◽  
pp. 8396-8404 ◽  
Author(s):  
Cuiping Yu ◽  
Yan Wang ◽  
Jiewu Cui ◽  
Dongbo Yu ◽  
Xinyi Zhang ◽  
...  

Phase evolution of hybrid metal oxides derived from MOF-74 nanowires was investigated systematically, and NiO/NiCo2O4(1 : 1) nanowires with hollow structure exhibited excellent performance in energy storage.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Fuwei Liu ◽  
Luoyuan Xie ◽  
Li Wang ◽  
Wei Chen ◽  
Wei Wei ◽  
...  

AbstractMany hybrid electrodes for supercapacitors (SCs) are a reckless combination without proper structural design that keeps them from fulfilling their potential. Herein, we design a reduced graphene oxide/poly(3,4-ethylenedioxythiophene)/polyaniline (RGO/PEDOT/PANI) hybrid with hierarchical and porous structure for high-performance SCs, where components fully harness their advantages, forming an interconnected and conductive framework with substantial reactive sites.Thus, this hybrid achieves a high capacitance of 535 F g−1 along with good rate capability and cyclability. The planar SC based on this hybrid deliver an energy density of 26.89 Wh kg−1 at a power density of 800 W kg−1. The linear SC developed via modifying a cotton yarn with the hybrid exhibits good flexibility and structural stability, which operates normally after arbitrary deformations. This work provides a beneficial reference for developing SCs.


Micromachines ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 13 ◽  
Author(s):  
Bin Zhang ◽  
Jaehyun Lee ◽  
Mincheol Kim ◽  
Naeeung Lee ◽  
Hyungdong Lee ◽  
...  

The macroscopic assembly of two-dimensional materials into a laminar structure has received considerable attention because it improves both the mechanical and chemical properties of the original materials. However, conventional manufacturing methods have certain limitations in that they require a high temperature process, use toxic solvents, and are considerably time consuming. Here, we present a new system for the self-assembly of layer-by-layer (LBL) graphene oxide (GO) via an electrohydrodynamic (EHD) jet printing technique. During printing, the orientation of GO flakes can be controlled by the velocity distribution of liquid jet and electric field-induced alignment spontaneously. Closely-packed GO patterns with an ordered laminar structure can be rapidly realized using an interfacial assembly process on the substrates. The surface roughness and electrical conductivity of the LBL structure were significantly improved compared with conventional dispensing methods. We further applied this technique to fabricate a reduced graphene oxide (r-GO)-based supercapacitor and a three-dimensional (3D) metallic grid hybrid ammonia sensor. We present the EHD-assisted assembly of laminar r-GO structures as a new platform for preparing high-performance energy storage devices and sensors.


2017 ◽  
Vol 5 (32) ◽  
pp. 16865-16872 ◽  
Author(s):  
Dongbo Yu ◽  
Liang Ge ◽  
Xinlai Wei ◽  
Bin Wu ◽  
Jin Ran ◽  
...  

A promising strategy is demonstrated for the syntheses of metal organic framework/graphene oxide hybrid films with highly ordered layer-by-layer architecture, and the derived hybrids exhibit remarkable energy storage performances.


2021 ◽  
Author(s):  
Fuyao Zhong ◽  
Mingyu Ma ◽  
Zhuoran Zhong ◽  
Xinrong Lin ◽  
Mao Chen

A covalently cross-linked polyaniline network is synthesized via interfacial Buchwald-Hartwig polymerization/deprotection, enabling the generation of additive/binder-free and high-performance conducting thin-films for energy storage.


2018 ◽  
Vol 18 (12) ◽  
pp. 8352-8359 ◽  
Author(s):  
Xibin Liu ◽  
Gaohua liao ◽  
Xiang Qi ◽  
Xiaoan Mei ◽  
Jifei Wang ◽  
...  

Hybrid fibers based on MnO2/reduced graphene oxide have been fabricated for flexible energy storage devices. Graphene oxide nanoflakes were reduced in a polytetrafluoroethylene (PTFE) pipeline under the appropriate condition to develop a fiber current collector, which also provides the possibility of weaving. The RGO fiber with the radius of about 35 μm has a resistance of 150 Ω · cm. MnO2 nanoflakes directly grow on the RGO fiber surface acting as the electrode material of the device. The MnO2/RGO hybrid fibers provide excellent energy storage performances. The as-fabricated SC exhibits a high areal capacitance of 1.37 F·cm−2 at the scan rate of 1 mV·s−1, and outstanding long-term cycling stability of 93.75% retention after 5000 cycles. This work demonstrates a cost-effective and versatile strategy for wearable energy storage devices.


The Analyst ◽  
2018 ◽  
Vol 143 (11) ◽  
pp. 2546-2554 ◽  
Author(s):  
X. Luo ◽  
M. Huang ◽  
D. He ◽  
M. Wang ◽  
Y. Zhang ◽  
...  

Porous binary metal oxide NiCo2O4 NWA/CC was prepared and utilized as a 3D binder-free open electrode for enzyme-free sensing with high performance.


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