A combined experimental and theoretical approach revealing a direct mechanism for bifunctional water splitting on doped copper phosphide

Nanoscale ◽  
2020 ◽  
Vol 12 (34) ◽  
pp. 17769-17779 ◽  
Author(s):  
Indranil Mondal ◽  
Arup Mahata ◽  
Heeyoung Kim ◽  
Ujjwal Pal ◽  
Filippo De Angelis ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxidation State ◽  
Theoretical Approach ◽  
Lattice Parameters ◽  
Lower Oxidation State ◽  
Direct Mechanism ◽  
Surface Doping ◽  
Copper Phosphide ◽  
Lower Oxidation

Surface doping of Fe in the hexagonal Cu3P composite does not alter the lattice parameters, but promotes the surface metallicity by stimulating lower oxidation state Cu species, resulting an increasing bifunctional water splitting activity.

scholarly journals Dinuclear uranium complexation and manipulation using robust tetraaryloxides

2016 ◽  
Vol 45 (40) ◽  
pp. 16026-16032 ◽  
Author(s):  
Jordann A. L. Wells ◽  
Megan L. Seymour ◽  
Markéta Suvova ◽  
Polly L. Arnold
Keyword(s):  
Oxidation State ◽  
Lower Oxidation State ◽  
Lower Oxidation

Two lower-oxidation state uranium cations can be readily combined and controlled in a robust and derivatisable tetra-aryloxide ligand framework. These di-UIII/IV systems are a new platform at which to use the multi-electron reductive capacity of the two actinide centres.

Synthesis and structures of mononuclear and dinuclear gallium complexes with α-diimine ligands: reduction of the metal or ligand?

2016 ◽  
Vol 45 (1) ◽  
pp. 246-252 ◽  
Author(s):  
Yanxia Zhao ◽  
Yanyan Liu ◽  
Qian-Shu Li ◽  
Ji-Hu Su
Keyword(s):  
Oxidation State ◽  
Oxidation States ◽  
Lower Oxidation State ◽  
Diimine Ligands ◽  
Diimine Ligand ◽  
Dianionic Ligands ◽  
Lower Oxidation ◽  
Gallium Complexes

A series of gallium complexes with different oxidation states of ligand and metal were obtained, both monoanionic and dianionic ligands can be further reduced, where reduction of the radical monoanionic α-diimine ligand into dianion or of Ga (+3) into the lower oxidation state Ga (+2) or Ga (+1.5) takes place.

Sorption characteristics of 99Tc onto bentonite material with different additives under anaerobic conditions

2006 ◽  
Vol 94 (8) ◽  
Author(s):  
Hana Vinšová ◽  
Petr Večerník ◽  
Věra Jedináková-Křížová
Keyword(s):  
Oxidation State ◽  
Anaerobic Conditions ◽  
Lower Oxidation State ◽  
Lower Oxidation ◽  
Sorption Characteristics

SummaryThe radionuclideIt was found that it is very difficult to create the same conditions present in the deep repository in the laboratory, which is why the reduction of the pertechnetate anion to its lower oxidation state (Tc(IV)) was not achieved. The retention of the pertechnate anion on bentonite is very low (

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