Transition metal based heterogeneous electrocatalysts for the oxygen evolution reaction at near-neutral pH

Nanoscale ◽  
2020 ◽  
Vol 12 (18) ◽  
pp. 9924-9934
Author(s):  
Yan Dong ◽  
Colin W. Oloman ◽  
Elod L. Gyenge ◽  
Jianwei Su ◽  
Liang Chen
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Buffer Solution ◽  
Neutral Ph ◽  
Neutral Electrolyte

Transition metal (e.g. Co, Mn, Ni, Cu, Fe and binary TM) based catalysts achieve high OER performance in near neutral electrolyte, such as phosphate (Pi) buffer solution, borate (Bi) buffer solution, and carbonate (Ci) buffer solution.

Octanuclear Cu(II) cluster-tungstosilicate composite as efficient electrocatalyst for oxygen evolution reaction at near-neutral pH

2021 ◽  
Author(s):  
Junqi Lin ◽  
Xin Chen ◽  
Nini Wang ◽  
Shanshan Liu ◽  
Yanmei Chen ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Metal Clusters ◽  
Catalytic Efficiency ◽  
Water Soluble ◽  
Transition Metal Clusters ◽  
Neutral Ph

Transition metal clusters have been used for water oxidation with high catalytic efficiency. However, they are water soluble and often used homogeneously rather than heterogeneously. Herein, a water soluble octanuclear...

Graphene-Induced Growth of Co3O4 Nanoplates with Modulable Oxygen Vacancies for Improved OER Properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Xinheng Li ◽  
Lei Qi ◽  
Mei Wang
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Hydrothermal Treatment ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Oxygen Vacancies ◽  
Transition Metal Oxide ◽  
Oxide Hydroxide

Transition metal oxide/ hydroxide is intensively studied for oxygen evolution reaction (OER). Herein, graphene-induced growth of Co3O4 nanoplates with modulable oxygen vacancies via hydrothermal treatment is reported. With the increase...

scholarly journals The Effect of Iron Impurities on Transition Metal Catalysts for the Oxygen Evolution Reaction in Alkaline Environment: Activity Mediators or Active Sites?

2020 ◽  
Author(s):  
Ioannis Spanos ◽  
Justus Masa ◽  
Aleksandar Zeradjanin ◽  
Robert Schlögl
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Water Electrolysis ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Alkaline Water Electrolysis ◽  
Co Catalysts ◽  
Model Transition

AbstractThere is an ongoing debate on elucidating the actual role of Fe impurities in alkaline water electrolysis, acting either as reactivity mediators or as co-catalysts through synergistic interaction with the main catalyst material. This perspective summarizes the most prominent oxygen evolution reaction (OER) mechanisms mostly for Ni-based oxides as model transition metal catalysts and highlights the effect of Fe incorporation on the catalyst surface in the form of impurities originating from the electrolyte or co-precipitated in the catalyst lattice, in modulating the OER reaction kinetics, mechanism and stability. Graphic Abstract

The oxygen evolution reaction enabled by transition metal phosphide and chalcogenide pre-catalysts with dynamic changes

2019 ◽  
Vol 55 (60) ◽  
pp. 8744-8763 ◽  
Author(s):  
Wei Li ◽  
Dehua Xiong ◽  
Xuefei Gao ◽  
Lifeng Liu
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Dynamic Changes ◽  
Metal Phosphide ◽  
Electrocatalytic Performance ◽  
Metal Phosphides ◽  
Compositional Changes ◽  
Transition Metal Phosphide ◽  
Transition Metal Phosphides

Dynamic morphological, structural and compositional changes will occur when transition metal phosphides and chalcogenides are used to catalyze the oxygen evolution reaction, which can substantially enhance their electrocatalytic performance.

Ternary NiFeMn layered double hydroxides as highly-efficient oxygen evolution catalysts

2016 ◽  
Vol 52 (5) ◽  
pp. 908-911 ◽  
Author(s):  
Zhiyi Lu ◽  
Li Qian ◽  
Yang Tian ◽  
Yaping Li ◽  
Xiaoming Sun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Layered Double Hydroxides ◽  
Oxygen Evolution Reaction ◽  
Highly Efficient ◽  
Metal Ratio ◽  
Double Hydroxides

A ternary NiFeMn-LDH with an optimized transition metal ratio is developed as an advanced catalyst for the oxygen evolution reaction.

Electrocatalytic Performance of Mn-adsorbed g-C3N4: A First-Principles Study

2021 ◽  
Author(s):  
Liu Guo ◽  
Rui Li ◽  
Jiawei Jiang ◽  
Ji-Jun Zou ◽  
Wenbo Mi
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Active Center ◽  
Metal Atom ◽  
First Principles ◽  
Oxygen Evolution Reaction ◽  
Single Atom ◽  
Transition Metal Atom ◽  
First Principles Study ◽  
Magnetic Elements

Single-atom catalysts with magnetic elements as the active center have been widely exploited for efficient oxygen evolution reaction (OER) electrocatalyst. Here, different contents of transition metal atom Mn adsorbed on...

Deeply Reconstructed Hierarchical and Defective NiOOH/FeOOH Nanoboxes with Accelerated Kinetics for Oxygen Evolution Reaction

2021 ◽  
Author(s):  
Ping Yan ◽  
Qian Liu ◽  
Hui Zhang ◽  
Luchun Qiu ◽  
Hao Bin Wu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Alkaline Media ◽  
Metal Phosphides ◽  
Transition Metal Phosphides

Transition metal phosphides (TMPs) have been reported as efficient pre-catalysts for oxygen evolution reaction (OER) in alkaline media. The in-situ generated metal oxyhydroxides on the surface of TMPs serve as...

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