Nano-ZnO decorated ZnSnO3 as efficient fillers in PVDF matrixes: toward simultaneous enhancement of energy storage density and efficiency and improved energy harvesting activity

Nanoscale ◽  
2020 ◽  
Vol 12 (40) ◽  
pp. 20908-20921
Author(s):  
Abhishek Sasmal ◽  
Samar Kumar Medda ◽  
P. Sujatha Devi ◽  
Shrabanee Sen

Along with enhanced dielectric permittivity and suppressed dielectric loss, PVDF-ZnO@ZnSnO3 films showed simultaneous enhancement in electrical energy storage density and storage efficiency compared to PVDF-ZnSnO3 composites.

Author(s):  
Satyanarayan Patel ◽  
Manish Kumar ◽  
Yashwant Kashyap

Present work shows waste energy (thermal/mechanical) harvesting and storage capacity in bulk lead-free ferroelectric 0.6Ba(Zr0.2Ti0.8)O3-0.4(Ba0.7Ca0.3)TiO3 (0.6BZT-0.4BCT) ceramics. The thermal energy harvesting is obtained by employing the Olsen cycle under different stress biasing, whereas mechanical energy harvesting calculated using the thermo-mechanical cycle at various temperature biasing. To estimate the energy harvesting polarization-electric field loops were measured as a function of stress and temperatures. The maximum thermal energy harvesting is obtained equal to 158 kJ/m3 when the Olsen cycle operated as 25-81 °C (at contact stress of 5 MPa) and 0.25-2 kV/mm. On the other hand, maximum mechanical energy harvesting is calculated as 158 kJ/m3 when the cycle operated as 5-160 MPa (at a constant temperature of 25 °C) and 0.25-2 kV/mm. It is found that the stress and temperature biasing are not beneficial for thermal and mechanical energy harvesting. Further, a hybrid cycle, where both stress and temperature are varied, is also studied to obtain enhanced energy harvesting. The improved energy conversion potential is found as 221 kJ/m3 when the cycle operated as 25-81 °C, 5-160 MPa and 0.25-2 kV/mm. The energy storage density varies from 43 to 66 kJ/m3 (increase in temperature: 25-81 °C) and 43 to 80 kJ/m3 (increase in stress: 5 to 160 MPa). Also, the pre-stress can be easily implemented on the materials, which improve energy storage density almost 100% by domain pining and ferroelastic switching. The results show that stress confinement can be an effective way to enhance energy storage.


Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3006
Author(s):  
Serge Nyallang Nyamsi ◽  
Ivan Tolj

Two-tank metal hydride pairs have gained tremendous interest in thermal energy storage systems for concentrating solar power plants or industrial waste heat recovery. Generally, the system’s performance depends on selecting and matching the metal hydride pairs and the thermal management adopted. In this study, the 2D mathematical modeling used to investigate the heat storage system’s performance under different thermal management techniques, including active and passive heat transfer techniques, is analyzed and discussed in detail. The change in the energy storage density, the specific power output, and the energy storage efficiency is studied under different heat transfer measures applied to the two tanks. The results showed that there is a trade-off between the energy storage density and the energy storage efficiency. The adoption of active heat transfer enhancement (convective heat transfer enhancement) leads to a high energy storage density of 670 MJ m−3 (close to the maximum theoretical value of 755.3 MJ m−3). In contrast, the energy storage efficiency decreases dramatically due to the increase in the pumping power. On the other hand, passive heat transfer techniques using the bed’s thermal conductivity enhancers provide a balance between the energy storage density (578 MJ m−3) and the energy efficiency (74%). The utilization of phase change material as an internal heat recovery medium leads to a further reduction in the heat storage performance indicators (142 MJ m−3 and 49%). Nevertheless, such a system combining thermochemical and latent heat storage, if properly optimized, can be promising for thermal energy storage applications.


2020 ◽  
pp. 002199832095188
Author(s):  
Xiaobao Zhang ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu

Overcoming sticky problems of large dielectric loss and poor breakdown strength ( Eb) is prerequisite of actual applications for high dielectric constant polymer composites. Herein, three kinds of multi-layer structure composites with different spatial structures (2MP-CE/CNT, CE/CNT-2MP-CE/CNT, MP-CE/CNT-MP) were prepared based on carbon nanotubes (CNTs), cyanate ester (CE) resin and mica paper (MP). Compared with traditional single-layer CE/CNT composite, multi-layer CE/CNT-2MP-CE/CNT composites, of which the middle layer is two pieces of MPs with a thickness of 60 µm, while both bottom and top layers are CE/CNT composite, simultaneously achieve 105 reduction in dielectric loss and 18.1 times increase in energy storage density ( Ue). Through modulating two sheets of MPs and CE/CNT as top and bottom layer, respectively, 2MP-CE/CNT composite with 60 μm MPs has the largest breakdown strength ( Eb), its Eb and Ue are severally about 7.1 and 19.5 times of those of CE/CNT composite. The relationship and mechanism between spatial structure and integrated performance such as dielectric properties, Eb and Ue of composites were systematically investigated. The attractive integrated performances of CE/CNT-2MP-CE/CNT and 2MP-CE/CNT composites are attributed to their unique composition and spatial structures, which bring special micro-capacitance and interfacial polarization, and thus leading to outstanding performances. Therefore, this investigation provides a strategy for getting desirable performances through building composites with specific spatial structure.


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