A two-step gas/liquid strategy for the production of N-doped defect-rich transition metal dichalcogenide nanosheets and their antibacterial applications

Nanoscale ◽  
2020 ◽  
Vol 12 (15) ◽  
pp. 8415-8424 ◽  
Author(s):  
Tao Wang ◽  
Xiao Zhang ◽  
Linqiang Mei ◽  
Dongqing Ma ◽  
You Liao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Transition Metal Dichalcogenide ◽  
Liquid Exfoliation ◽  
Gas Expansion

A simple two-step strategy based on gas expansion combined liquid exfoliation to synthesize defect-rich N-doped MoS2 and N-doped WS2 nanosheets (NSs) was proposed. The NSs with improved peroxidase-like catalytic activity can be applied as effective nanoantimicrobials.

One-Step Synthesis of MoS2/WS2 Layered Heterostructures and Catalytic Activity of Defective Transition Metal Dichalcogenide Films

ACS Nano ◽  
2016 ◽  
Vol 10 (2) ◽  
pp. 2004-2009 ◽  
Author(s):  
John M. Woods ◽  
Yeonwoong Jung ◽  
Yujun Xie ◽  
Wen Liu ◽  
Yanhui Liu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Transition Metal Dichalcogenide ◽  
One Step

The effect of partial exchange of sulphonated macroporous styrene-divinylbenzene copolymers for different ions on their catalytic activity

1981 ◽  
Vol 46 (10) ◽  
pp. 2354-2363 ◽  
Author(s):  
Svatomír Kmošták ◽  
Karel Setínek
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Ions ◽  
Gas Phase ◽  
Transition Metal Ions ◽  
Exchange Capacity ◽  
Total Exchange Capacity ◽  
Styrene Divinylbenzene ◽  
Na Ions ◽  
Type Of Transition

The catalytic activity of sulphonated macroporous styrene-divinylbenzene copolymers, the exchange capacity of which was neutralized from 30, 50 and 80% by Fe(III) ions and from 30% by Na ions and that of Wofatit Y-37 ion exchanger neutralized from 10% of its total exchange capacity by several transition metal ions and by sodium has been studied in isomerisation of cyclohexene and dehydration of 1-propanol in the gas phase at 130 °C. It was demonstrated that in both reactions transition metal ions exhibit additional effect to the expected neutralization of the polymer acid groups. In the case of cyclohexene isomerization, this effect depends on the degree of crosslinking of polymer mass of the catalyst. Such dependence has not been, however, observed in dehydration of 1-propanol. The type of transition metal ions did not exhibit any significant effect on the catalytic activity of the polymer catalysts studied.

scholarly journals Visualization of Multifractal Superconductivity in a Two-Dimensional Transition Metal Dichalcogenide in the Weak-Disorder Regime

Nano Letters ◽  
2020 ◽  
Vol 20 (7) ◽  
pp. 5111-5118 ◽  
Author(s):  
Carmen Rubio-Verdú ◽  
Antonio M. Garcı́a-Garcı́a ◽  
Hyejin Ryu ◽  
Deung-Jang Choi ◽  
Javier Zaldı́var ◽  
...  
Keyword(s):  
Transition Metal ◽  
Transition Metal Dichalcogenide ◽  
Two Dimensional ◽  
Weak Disorder

Identification of Point Defects in Atomically Thin Transition-Metal Dichalcogenide Semiconductors as Active Dopants

Nano Letters ◽  
2021 ◽  
Vol 21 (8) ◽  
pp. 3341-3354
Author(s):  
Seung-Young Seo ◽  
Dong-Hwan Yang ◽  
Gunho Moon ◽  
Odongo F. N. Okello ◽  
Min Yeong Park ◽  
...  
Keyword(s):  
Transition Metal ◽  
Point Defects ◽  
Transition Metal Dichalcogenide

scholarly journals Second-harmonic generation enhancement in monolayer transition-metal dichalcogenides by using an epsilon-near-zero substrate

2021 ◽  
Vol 3 (1) ◽  
pp. 272-278
Author(s):  
Pilar G. Vianna ◽  
Aline dos S. Almeida ◽  
Rodrigo M. Gerosa ◽  
Dario A. Bahamon ◽  
Christiano J. S. de Matos
Keyword(s):  
Dielectric Constant ◽  
Transition Metal ◽  
Harmonic Generation ◽  
Nonlinear Effect ◽  
Second Harmonic ◽  
2D Materials ◽  
Transition Metal Dichalcogenides ◽  
Transition Metal Dichalcogenide ◽  
Metal Dichalcogenides ◽  
Epsilon Near Zero

The scheme illustrates a monolayer transition-metal dichalcogenide on an epsilon-near-zero substrate. The substrate near-zero dielectric constant is used as the enhancement mechanism to maximize the SHG nonlinear effect on monolayer 2D materials.

scholarly journals Epitaxial Single‐Crystal Growth of Transition Metal Dichalcogenide Monolayers via the Atomic Sawtooth Au Surface

2021 ◽  
pp. 2006601
Author(s):  
Soo Ho Choi ◽  
Hyung‐Jin Kim ◽  
Bumsub Song ◽  
Yong In Kim ◽  
Gyeongtak Han ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Transition Metal ◽  
Single Crystal ◽  
Single Crystal Growth ◽  
Transition Metal Dichalcogenide

Weak Kondo effect in the monocrystalline transition metal dichalcogenide ZrTe2

2021 ◽  
Vol 103 (17) ◽  
Author(s):  
Yihao Wang ◽  
Changzheng Xie ◽  
Junbo Li ◽  
Zan Du ◽  
Liang Cao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Kondo Effect ◽  
Transition Metal Dichalcogenide

scholarly journals Flat-band topology of magic angle graphene on a transition metal dichalcogenide

2020 ◽  
Vol 102 (23) ◽  
Author(s):  
Tianle Wang ◽  
Nick Bultinck ◽  
Michael P. Zaletel
Keyword(s):  
Transition Metal ◽  
Flat Band ◽  
Magic Angle ◽  
Transition Metal Dichalcogenide

scholarly journals Reactive plasma cleaning and restoration of transition metal dichalcogenide monolayers

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Daniil Marinov ◽  
Jean-François de Marneffe ◽  
Quentin Smets ◽  
Goutham Arutchelvan ◽  
Kristof M. Bal ◽  
...  
Keyword(s):  
High Temperature ◽  
Transition Metal ◽  
Field Effect Transistors ◽  
Removal Rate ◽  
2D Materials ◽  
Scale Up ◽  
Transition Metal Dichalcogenides ◽  
Chemical Properties ◽  
Plasma Cleaning ◽  
Transition Metal Dichalcogenide

AbstractThe cleaning of two-dimensional (2D) materials is an essential step in the fabrication of future devices, leveraging their unique physical, optical, and chemical properties. Part of these emerging 2D materials are transition metal dichalcogenides (TMDs). So far there is limited understanding of the cleaning of “monolayer” TMD materials. In this study, we report on the use of downstream H2 plasma to clean the surface of monolayer WS2 grown by MOCVD. We demonstrate that high-temperature processing is essential, allowing to maximize the removal rate of polymers and to mitigate damage caused to the WS2 in the form of sulfur vacancies. We show that low temperature in situ carbonyl sulfide (OCS) soak is an efficient way to resulfurize the material, besides high-temperature H2S annealing. The cleaning processes and mechanisms elucidated in this work are tested on back-gated field-effect transistors, confirming that transport properties of WS2 devices can be maintained by the combination of H2 plasma cleaning and OCS restoration. The low-damage plasma cleaning based on H2 and OCS is very reproducible, fast (completed in a few minutes) and uses a 300 mm industrial plasma etch system qualified for standard semiconductor pilot production. This process is, therefore, expected to enable the industrial scale-up of 2D-based devices, co-integrated with silicon technology.

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