Effect of the acid used in the evaporation-induced self-assembly method on Ce–Cu–Al trimetallic composite catalyst for its simultaneous removal of H2S and PH3

2021 ◽  
Vol 45 (13) ◽  
pp. 5822-5828
Author(s):  
Yingwu Wang ◽  
Qiang Lin ◽  
Ping Ning ◽  
Chi Wang ◽  
Heping Zeng ◽  
...  

The performance of Ce–Cu–Al trimetallic composite catalyst was further improved by examining the influence of the acid used. The effects of acids on the structural features, surface functionality, and activity of the catalysts were examined.

2009 ◽  
Vol 488 (1) ◽  
pp. 320-324 ◽  
Author(s):  
Xiqiang Tian ◽  
Lijuan Wan ◽  
Kai Pan ◽  
Chungui Tian ◽  
Honggang Fu ◽  
...  

ChemCatChem ◽  
2015 ◽  
Vol 7 (22) ◽  
pp. 3753-3762 ◽  
Author(s):  
Xiuzhong Fang ◽  
Cheng Peng ◽  
Honggen Peng ◽  
Wenming Liu ◽  
Xianglan Xu ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 312 ◽  
Author(s):  
Zhiwen Xi ◽  
Zhe Hong ◽  
Fangtao Huang ◽  
Zhirong Zhu ◽  
Wenzhi Jia ◽  
...  

A series of Pt/WOx-ZrO2-TiO2 catalysts with different Ti/Zr molar ratios was prepared by an evaporation induced self-assembly method, and used to efficient hydrogenolysis of glycerol to 1-PO and 1,3-PDO. BET, XRD, Raman, TEM, XPS and Py-IR were employed to characterize the physicochemical properties of the catalysts. The structural and acidic properties of the catalysts were affected by the Ti/Zr ratio of the support ZrO2-TiO2. Two new crystalline phases of ZrTiO4 and Ti2ZrO6 and the amount of acid sites were detected in the Pt/WOx-ZrO2-TiO2 catalysts. 1-PO is dominant in all products of glycerol hydrogenolysis over the supported Pt-WOx catalysts, which is attributed to more Lewis acid sites on the catalyst surface. The Pt/WOx-ZrO2-TiO2 catalyst with a Ti/Zr ratio of 7/3 showed the highest 1,3-PDO yield (25.3%) and 1-PO yield (42.3%), due to its more acid sites including Brønsted and Lewis, and higher concentration of surface Pt0.


2012 ◽  
Vol 358 (12-13) ◽  
pp. 1611-1616 ◽  
Author(s):  
Qingsong Jiang ◽  
Chan Li ◽  
Shugang Shi ◽  
Degang Zhao ◽  
Lun Xiong ◽  
...  

2014 ◽  
Vol 953-954 ◽  
pp. 1003-1007
Author(s):  
Yu Xiu Zhang ◽  
Li Yang ◽  
Dai Mei Chen ◽  
Shuang Deng ◽  
Ying Jie Shi

Abstract. The large-pore mesoporous Bi-B-TiO2 nanoparticles with the different Bi/Ti rations were prepared by EISA(evaporation-induced self-assembly) method. The prepared catalysts were characterized by X-ray diffraction, transmission electron microscopy, N2 absorption-desorption, ultraviolet visible light spectroscopy and photoluminescence spectroscopy technologies. The results revealed that all the samples are large aperture mesoporous structures. The crystallite sizes were in the range7-11nm, as confirmed by the results obtained from TEM images. The photodecomposition experiments showed that the photodegradation activity of Bi-B-doped TiO2 was higher than that of undoped TiO2 in degradation of 2, 4–dichlorophenol under visible light irradiation.


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