C–F bond activation of perfluorinated arenes using NHC-stabilized cobalt half-sandwich complexes

2021 ◽  
Author(s):  
Daniel Ertler ◽  
Maximilian W. Kuntze-Fechner ◽  
Simon Dürr ◽  
Katharina Lubitz ◽  
Udo Radius
Keyword(s):  
Bond Activation ◽  
Oxidative Addition ◽  
Sandwich Complexes ◽  
Half Sandwich ◽  
Addition Pathway

A study on the reactivity of cobalt half-sandwich complexes [Cp(*)Co(NHC)(olefin)] with perfluoroarenes demonstrates that C–F activation occurs along a one-electron oxidative addition pathway.

Half-sandwich complexes of Group 9 metals with N,Nʹ-ligands for CF3-carbenoid alkylation of N-(pyrimidin-2-yl)indole

2021 ◽  
pp. 121899
Author(s):  
Sofya S. Kuvshinova ◽  
Yulia V. Nelyubina ◽  
Vladimir A. Larionov ◽  
Daria V. Vorobyeva ◽  
Sergey N. Osipov ◽  
...  
Keyword(s):  
Sandwich Complexes ◽  
Half Sandwich

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

scholarly journals The synthesis and unexpected solution chemistry of thermochromic carborane-containing osmium half-sandwich complexes

2016 ◽  
Vol 45 (4) ◽  
pp. 1763-1768 ◽  
Author(s):  
Anaïs Pitto-Barry ◽  
Amy South ◽  
Alison Rodger ◽  
Nicolas P. E. Barry
Keyword(s):  
Solution Chemistry ◽  
Sandwich Complexes ◽  
Lewis Bases ◽  
Half Sandwich

The functionalisation of the 16-electron complex [Os(η6-p-cymene)(1,2-dicarba-closo-dodecarborane-1,2-dithiolato)] (1) with a series of Lewis bases to give the corresponding 18-electron complexes is reported.

Copolymerization of Ethylene with Norbornene Catalyzed by Cationic Rare-Earth Metal Half-Sandwich Complexes

2008 ◽  
Vol 41 (24) ◽  
pp. 9565-9569 ◽  
Author(s):  
Andrea Ravasio ◽  
Cristina Zampa ◽  
Laura Boggioni ◽  
Incoronata Tritto ◽  
Julia Hitzbleck ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Sandwich Complexes ◽  
Half Sandwich

Organometallic Half-Sandwich Complexes Promote the Formation of Linear Oligopeptides from Amino Acid Esters

1996 ◽  
Vol 2 (12) ◽  
pp. 1518-1526 ◽  
Author(s):  
Christian Robl ◽  
Michael Maurus ◽  
Karlheinz Sünkel ◽  
Wolfgang Beck ◽  
Roland Krämer ◽  
...  
Keyword(s):  
Amino Acid ◽  
Amino Acid Esters ◽  
Sandwich Complexes ◽  
Half Sandwich ◽  
Acid Esters

Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach

2016 ◽  
Vol 22 (44) ◽  
pp. 15645-15649 ◽  
Author(s):  
Carolina Valderas ◽  
Leyre Marzo ◽  
María C. de la Torre ◽  
José Luis García Ruano ◽  
José Alemán ◽  
...  
Keyword(s):  
Synthetic Approach ◽  
Sandwich Complexes ◽  
Half Sandwich

scholarly journals Self-assembly of arene ruthenium acylpyrazolone fragments to tetranuclear metallacycles. Molecular structures and solid-state 15N CPMAS NMR correlations

2016 ◽  
Vol 45 (9) ◽  
pp. 3974-3982 ◽  
Author(s):  
Riccardo Pettinari ◽  
Fabio Marchetti ◽  
Claudio Pettinari ◽  
Francesca Condello ◽  
Brian W. Skelton ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Self Assembly ◽  
Solid State Nmr ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Solid State Nmr Spectroscopy ◽  
Half Sandwich

Mono- and tetranuclear Ru(ii) half-sandwich complexes containing acylpyrazolone ligands. 13C and 15N solid state NMR spectroscopy.

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