A new 3D Ag(i)-based high-energy metal organic frameworks (HE-MOFs): synthesis, crystal structure and explosive performance

2021 ◽  
Vol 45 (7) ◽  
pp. 3552-3558
Author(s):  
Jiaping Zhu ◽  
Jielai Xu ◽  
Chaojian Yao ◽  
Tong Zhan ◽  
Weibing Liu ◽  
...  

A new 3D HE-MOF, [Ag2(TABT)(NO3)2]n, where TABT represents 4,4′,5,5′-tetraamine-3,3′-bis-1,2,4-triazole, was synthesized by hydrothermal method, exhibiting high density, good thermostability, insensitivity and relative high detonation performance.

2014 ◽  
Vol 13 (05n06) ◽  
pp. 1460002
Author(s):  
Lan Ma ◽  
Huamin Tang ◽  
Chaohua Zhou ◽  
Hongpeng Zhang ◽  
Chunxiao Yan ◽  
...  

A kind of typical metal-organic frameworks (MOFs) material, HKUST-1 was prepared by hydrothermal method and characterized by XRD and SEM. The results of characterizations manifested that HKUST-1 showed a regular octahedral crystal structure. The as-prepared HKUST-1 was modified by several kinds of organic base materials and the CO 2 adsorption behaviors of modified HKUST-1 materials were evaluated. The CO 2 adsorption capacities of different base modified HKUST-1 varied with the base intensity of modified organic base materials.


2017 ◽  
Vol 53 (54) ◽  
pp. 7489-7492 ◽  
Author(s):  
Cheng Shen ◽  
Yang Liu ◽  
Zhong-qin Zhu ◽  
Yuan-gang Xu ◽  
Ming Lu

Two HE-MOFs, {Ag2(DNMAF)(H2O)2}n (1) and {Ag2(DNMAF)}n (2), were prepared using K2DNMAF in a mild self-assembly strategy.


2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.


2021 ◽  
Vol 5 (20) ◽  
pp. 7654-7665
Author(s):  
Olivia Basu ◽  
Subhabrata Mukhopadhyay ◽  
Avik De ◽  
Anupam Das ◽  
Samar K. Das

Hassle-free encapsulation of fullerene C60 in ZIF-8 has been performed to preserve the molecularity and solution-like properties of C60 in solid-state. The resulting composite shows efficient heterogeneous electrocatalytic oxygen reduction reaction.


Crystals ◽  
2016 ◽  
Vol 6 (10) ◽  
pp. 132 ◽  
Author(s):  
Marina Barsukova ◽  
Tatiana Goncharova ◽  
Denis Samsonenko ◽  
Danil Dybtsev ◽  
Andrei Potapov

Author(s):  
Zhimin Li ◽  
Yi-Qiang Xu ◽  
Chao Wang ◽  
Guorong Lei ◽  
Rui Zhang ◽  
...  

Constructing high performance hypergolic propellant is of vital importance yet challenging. Herein, by taking metal organic framework(MOF) as a propotypical system, we proposed that co-assembled functional cyanotetrazolylborohydride (CTB) and imidazole...


The Analyst ◽  
2021 ◽  
Author(s):  
Meihui Ying ◽  
Guizeng Yang ◽  
Yuanjie Xu ◽  
Hui-Ling Ye ◽  
Xing Lin ◽  
...  

Metal-organic frameworks (MOFs) have attracted extensive attention in the construction of colorimetric detection methods due to their easy modification and high density of active sites. However, most of the reported...


Sign in / Sign up

Export Citation Format

Share Document