Pt–BiVO4/TiO2 composites as Z-scheme photocatalysts for hydrogen production from ethanol: the effect of BiVO4 and Pt on the photocatalytic efficiency

2021 ◽  
Vol 45 (9) ◽  
pp. 4481-4495
Author(s):  
Sahar Mansour ◽  
Rym Akkari ◽  
Erika Soto ◽  
Semy Ben Chaabene ◽  
Noelia Mota ◽  
...  

The photodeposition of platinum particles on the BiVO4/TiO2 composite surface promotes the H2 production by reducing H+ species.

2016 ◽  
Vol 14 (4) ◽  
pp. 851-858 ◽  
Author(s):  
Mohammad Reza Gholipour ◽  
Francois Béland ◽  
Trong-On Do

Abstract Hydrogen production from water splitting via photocatalytic reactions can be an alternative clean energy of fossil fuels in the future. Graphitic carbon nitride (g-C3N4) is one of the active photocatalysts in the visible light region that can be combined with other semiconductors in order to increase its photocatalytic efficiency. TiO2 is one of the most appropriate choices to combine with g-C3N4 because of its conduction band edge and variety forms of nanostructures. In this work, nanosheets of g-C3N4 were mixed with the nanoparticles of titanate in order to enhance charge separation and photocatalytic efficiency. Consequently, the hydrogen evolution of this novel nanocomposite produced almost double hydrogen in comparison with g-C3N4.


Author(s):  
Lei Li ◽  
Yan Zhao ◽  
Qian Wang ◽  
Zheng-Yu Liu ◽  
Xiu-Guang Wang ◽  
...  

Improving the photocatalytic efficiency for hydrogen evolution from water splitting plays vital roles for the feasible applications of clean and sustainable hydrogen energy production. A crystalline microporous CuII-based metal-organic framework...


2017 ◽  
Vol 5 (17) ◽  
pp. 7833-7838 ◽  
Author(s):  
Pengyan Wu ◽  
Min Jiang ◽  
Yang Li ◽  
Yanhong Liu ◽  
Jian Wang

Photoactive MOF modified with a thin PDMS layer exhibits high stability and ultrahigh photocatalytic efficiency for H2 production in water.


RSC Advances ◽  
2021 ◽  
Vol 11 (60) ◽  
pp. 37966-37980
Author(s):  
Angelina V. Zhurenok ◽  
Dina V. Markovskaya ◽  
Evgeny Yu. Gerasimov ◽  
Svetlana V. Cherepanova ◽  
Andrey V. Bukhtiyarov ◽  
...  

The determination of the preferred location of platinum particles in TiO2–Cd1−xZnxS systems was carried out for the first time.


Author(s):  
Yaoyao Wang ◽  
Xueyang Ji ◽  
Meng Yu ◽  
Jun Tao

Inhibition of the recombination of photo-induced electrons and holes is critical for light harvesting and enhancing the photocatalytic efficiency of hydrogen production in metal-organic frameworks (MOFs). Herein, Cs3Bi2I9 (CBI) quantum...


2018 ◽  
Vol 3 (41) ◽  
pp. 11454-11459 ◽  
Author(s):  
Ana Paula Garcia ◽  
Waleska Campos Guaglianoni ◽  
Danielle Rodrigues Garcia ◽  
Luana Goés Soares ◽  
Maurício de Oliveira Vaz ◽  
...  

Author(s):  
Steven D. Toteda

Zirconia oxygen sensors, in such applications as power plants and automobiles, generally utilize platinum electrodes for the catalytic reaction of dissociating O2 at the surface. The microstructure of the platinum electrode defines the resulting electrical response. The electrode must be porous enough to allow the oxygen to reach the zirconia surface while still remaining electrically continuous. At low sintering temperatures, the platinum is highly porous and fine grained. The platinum particles sinter together as the firing temperatures are increased. As the sintering temperatures are raised even further, the surface of the platinum begins to facet with lower energy surfaces. These microstructural changes can be seen in Figures 1 and 2, but the goal of the work is to characterize the microstructure by its fractal dimension and then relate the fractal dimension to the electrical response. The sensors were fabricated from zirconia powder stabilized in the cubic phase with 8 mol% percent yttria. Each substrate was sintered for 14 hours at 1200°C. The resulting zirconia pellets, 13mm in diameter and 2mm in thickness, were roughly 97 to 98 percent of theoretical density. The Engelhard #6082 platinum paste was applied to the zirconia disks after they were mechanically polished ( diamond). The electrodes were then sintered at temperatures ranging from 600°C to 1000°C. Each sensor was tested to determine the impedance response from 1Hz to 5,000Hz. These frequencies correspond to the electrode at the test temperature of 600°C.


2020 ◽  
pp. 124-135
Author(s):  
I. N. G. Wardana ◽  
N. Willy Satrio

Tofu is main food in Indonesia and its waste generally pollutes the waters. This study aims to change the waste into energy by utilizing the electric charge in the pores of tofu waste to produce hydrogen in water. The tofu pore is negatively charged and the surface surrounding the pore has a positive charge. The positive and negative electric charges stretch water molecules that have a partial charge. With the addition of a 12V electrical energy during electrolysis, water breaks down into hydrogen. The test was conducted on pre-treated tofu waste suspension using oxalic acid. The hydrogen concentration was measured by a MQ-8 hydrogen sensor. The result shows that the addition of turmeric together with sodium bicarbonate to tofu waste in water, hydrogen production increased more than four times. This is due to the fact that magnetic field generated by delocalized electron in aromatic ring in turmeric energizes all electrons in the pores of tofu waste, in the sodium bicarbonate, and in water that boosts hydrogen production. At the same time the stronger partial charge in natrium bicarbonate shields the hydrogen proton from strong attraction of tofu pores. These two combined effect are very powerful for larger hydrogen production in water by tofu waste.


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