Unique reactivity of an α-ketiminopyridine ligand with metal–alkyls: Synthesis and ROP of ε-caprolactone

2021 ◽  
Author(s):  
Miroslav Novák ◽  
Roman Jambor ◽  
Zdeňka Růžičková ◽  
Štěpán Podzimek
Keyword(s):  
Metal Alkyls

The reaction of an α-ketimininopyridine ligand 2-((Me)CN(C6H3-2,6-iPr2))-6-(OMe)C5H3N (L1) with metal–alkyls, such as MeLi, Et2Zn, Me3Al and Me2AlCl, was studied.

scholarly journals Correlating Axial and Equatorial Ligand Field Effects to the Single-Molecule Magnet Performances of a Family of Dysprosium Bis-Methanediide Complexes

2021 ◽  
Author(s):  
Lewis Thomas-Hargreaves ◽  
Marcus Giansiracusa ◽  
Matthew Gregson ◽  
Emanuele Zanda ◽  
Felix O'Donnell ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Single Molecule ◽  
Ligand Field ◽  
Single Molecule Magnet ◽  
Field Effects ◽  
Equatorial Ligand ◽  
Metal Alkyls

Treatment of the new methanediide-methanide complex [Dy(SCS)(SCSH)(THF)] (1Dy, SCS = {C(PPh2S)2}2-) with alkali metal alkyls and auxillary ethers produces the bis-methanediide complexes [Dy(SCS)2][Dy(SCS)2(K(DME)2)2] (2Dy), [Dy(SCS)2][Na(DME)3] (3Dy) and [Dy(SCS)2][K(2,2,2-cryptand)] (4Dy). For...

A Valence Bond Perspective on the Molecular Shapes of Simple Metal Alkyls and Hydrides

1998 ◽  
Vol 120 (8) ◽  
pp. 1842-1854 ◽  
Author(s):  
Clark R. Landis ◽  
Timothy K. Firman ◽  
Daniel M. Root ◽  
Thomas Cleveland
Keyword(s):  
Valence Bond ◽  
Simple Metal ◽  
Metal Alkyls

ChemInform Abstract: PHOTOELECTRON SPECTRA OF SOME TRANSITION METAL ALKYLS AND OXOALKYLS

1978 ◽  
Vol 9 (52) ◽  
Author(s):  
J. C. GREEN ◽  
D. R. LLOYD ◽  
L. GALYER ◽  
K. MERTIS ◽  
G. WILKINSON
Keyword(s):  
Transition Metal ◽  
Photoelectron Spectra ◽  
Metal Alkyls

SN2 and E2 Branching of Main-Group-Metal Alkyl Intermediates in Alkane CH Oxidation: Mechanistic Investigation Using Isotopically Labeled Main-Group-Metal Alkyls

2020 ◽  
Vol 39 (10) ◽  
pp. 1907-1916 ◽  
Author(s):  
Niles Jensen Gunsalus ◽  
Anjaneyulu Koppaka ◽  
Brian G. Hashiguchi ◽  
Michael M. Konnick ◽  
Sae Hume Park ◽  
...  
Keyword(s):  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Mechanistic Investigation ◽  
Metal Alkyls
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