Validation of the supramolecular synthon preference through DFT and physicochemical property investigations of pyridyl salts of organo-sulfonates

2021 ◽  
Vol 45 (10) ◽  
pp. 4780-4790 ◽  
Author(s):  
Arshid A. Ganie ◽  
Thufail M. Ismail ◽  
P. K. Sajith ◽  
Aijaz A. Dar

Understanding of the supramolecular synthon competition is sparse and the synthon hierarchy studies are limited. Herein, we validate the synthon preferences in multi-functional organic precursor through DFT and crystallographic studies.

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19924-19934
Author(s):  
Pinky Sagar ◽  
Gopal Krishna Gupta ◽  
Monika Srivastava ◽  
Amit Srivastava ◽  
S. K. Srivastava

TE-CQDs synthesized via the hydrothermal method for the detection of Fe3+ in HBS.


2020 ◽  
Vol 2 (2) ◽  
Author(s):  
K. Thongchai ◽  
P. Chuysinuan ◽  
T. Thanyacharoen ◽  
S. Techasakul ◽  
S. Ummartyotin

2019 ◽  
Vol 33 (09) ◽  
pp. 1950100 ◽  
Author(s):  
S. Hosseinzadeh ◽  
P. Elahi ◽  
M. Behboudnia ◽  
M. H. Sheikhi ◽  
S. M. Mohseni

The crystallization and magnetic behavior of yttrium iron garnet (YIG) prepared by metallo-organic decomposition (MOD) method are discussed. The chemistry and physics related to synthesis of iron and yttrium carboxylates based on 2-ethylhexanoic acid (2EHA) are studied, since no literature was found which elucidates synthesis of metallo-organic precursor of YIG in spite of the literatures of doped YIG samples such as Bi-YIG. Typically, the metal carboxylates used in preparation of ceramic oxide materials are 2-ethylhexanoate (2EH) solvents. Herein, the synthesis, thermal behavior and solubility of yttrium and iron 2EH used in synthesis of YIG powder by MOD are reported. The crystallization and magnetic parameters, including saturation magnetization and coercivity of these samples, smoothly change as a function of the annealing temperature. It is observed that high sintering temperature of [Formula: see text] to [Formula: see text] promotes the diffraction peaks of YIG, therefore, we can conclude that the formation of YIG in MOD method increases the crystallization temperature. The maximum value of saturation magnetization and minimum value of coercivity and remanence are observed for the sample sintered at [Formula: see text] which are 13.7 emu/g, 10.38 Oe and 1.5 emu/g, respectively. This study cites the drawbacks in chemical synthesis of metallo-organic-based YIG production.


2010 ◽  
Vol 10 (4) ◽  
pp. 1798-1807 ◽  
Author(s):  
Anil D. Naik ◽  
Marinela M. Dîrtu ◽  
Alexandre Léonard ◽  
Bernard Tinant ◽  
Jacqueline Marchand-Brynaert ◽  
...  

CrystEngComm ◽  
2005 ◽  
Vol 7 (95) ◽  
pp. 586 ◽  
Author(s):  
Simon J. Brooks ◽  
Philip A. Gale ◽  
Mark E. Light

Chemosphere ◽  
2012 ◽  
Vol 89 (11) ◽  
pp. 1316-1322 ◽  
Author(s):  
Xiaoli Tian ◽  
Tingting Li ◽  
Kun Yang ◽  
Yong Xu ◽  
Huifeng Lu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document