Colorimetric assay for the sensitive detection of phosphate in water based on metal–organic framework nanospheres possessing catalytic activity

2020 ◽  
Vol 44 (45) ◽  
pp. 19683-19689
Author(s):  
Jiayan Wang ◽  
Wenying Li ◽  
Yue-Qing Zheng

For the first time, the inhibition of the catalytic activity of Cu-MOF caused by phosphate was used for phosphate detection.

RSC Advances ◽  
2015 ◽  
Vol 5 (119) ◽  
pp. 98215-98221 ◽  
Author(s):  
Fengjuan Cui ◽  
Qingfang Deng ◽  
Li Sun

Nanosized porous PB/MIL-101(Fe) was facilely prepared by growing Prussian blue (PB) on MIL-101(Fe). It has more active sites and pores for peroxidase substrates and gives a simple, sensitive colorimetric assay to detect H2O2and glucose.


2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.


2016 ◽  
Vol 138 (29) ◽  
pp. 9089-9092 ◽  
Author(s):  
Daniel Reinares-Fisac ◽  
Lina María Aguirre-Díaz ◽  
Marta Iglesias ◽  
Natalia Snejko ◽  
Enrique Gutiérrez-Puebla ◽  
...  

2016 ◽  
Vol 6 (11) ◽  
pp. 3727-3736 ◽  
Author(s):  
P. Cancino ◽  
A. Vega ◽  
Andrea Santiago-Portillo ◽  
Sergio Navalon ◽  
Mercedes Alvaro ◽  
...  

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.


2019 ◽  
Vol 72 (2) ◽  
pp. 272-282 ◽  
Author(s):  
Fei Xie ◽  
Xiao Li ◽  
Yujing Li ◽  
Xusheng Jiang ◽  
Qi Rui ◽  
...  

2018 ◽  
Vol 57 (24) ◽  
pp. 15149-15157 ◽  
Author(s):  
Soutick Nandi ◽  
Ena Sharma ◽  
Vishal Trivedi ◽  
Shyam Biswas

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