Columnar self-assembly, electrochemical and luminescence properties of basket-shaped liquid crystalline derivatives of Schiff-base-moulded p-tert-butyl-calix[4]arene

2020 ◽  
Vol 44 (47) ◽  
pp. 20610-20619
Author(s):  
Vinay S. Sharma ◽  
Anuj S. Sharma ◽  
Sheena J. B. Worthington ◽  
Priyanka A. Shah ◽  
Pranav S. Shrivastav

A new family of blue-light emitting supramolecular basket-shaped liquid crystalline compounds based on p-tert-butyl-calix[4]arene core to form self-assembly and columnar hexagonal phase.

2020 ◽  
Vol 5 (10) ◽  
pp. 1691-1705
Author(s):  
Vinay S. Sharma ◽  
Anuj S. Sharma ◽  
Nikhil K. Agarwal ◽  
Priyanka A. Shah ◽  
Pranav S. Shrivastav

A new family of blue-light-emitting supramolecular bowl-shaped columnar hexagonal liquid crystals based on p-tert-butylcalix[4]arene and functionalized via chalconyl–ester-linked biphenyl amine derivatives form a self-assembly and their applications.


Polyhedron ◽  
2011 ◽  
Vol 30 (6) ◽  
pp. 1040-1047 ◽  
Author(s):  
Chira R. Bhattacharjee ◽  
Gobinda Das ◽  
Pankaj Goswami ◽  
Paritosh Mondal ◽  
Subbarao Krishna Prasad ◽  
...  

2019 ◽  
Vol 43 (4) ◽  
pp. 1910-1925 ◽  
Author(s):  
Vinay S. Sharma ◽  
Akshara P. Shah ◽  
Anuj S. Sharma ◽  
Mohd Athar

A new class of blue light-emitting supramolecular liquid crystalline cone or bowl-shaped compounds were synthesized from substituted 1,3,4-oxadiazoles and 1,3,4-thiadiazoles with calix[4]arene derivatives.


2021 ◽  
Author(s):  
Vinay Kumar Sharma ◽  
Anuj Sharma ◽  
Vekata Subba Rao Ganga ◽  
Pranav Shrivastav ◽  
Priyanka A Jain ◽  
...  

A new class of highly efficient blue emitters consisting of phenanthroimidazole-carbazole hybrid disc shaped molecules with two Schiff base units have been designed and well characterized. All the prepared materials...


Author(s):  
Vinay S. Sharma ◽  
Anuj S. Sharma ◽  
Nikhil K. Agarwal ◽  
Priyanka A. Shah ◽  
Pranav S. Shrivastav

Correction for ‘Self-assembled blue-light emitting materials for their liquid crystalline and OLED applications: from a simple molecular design to supramolecular materials’ by Vinay S. Sharma et al., Mol. Syst. Des. Eng., 2020, 5, 1691–1705, DOI: 10.1039/D0ME00117A.


2010 ◽  
Vol 107 (2) ◽  
pp. 024316 ◽  
Author(s):  
Kajari Das ◽  
Shailesh N. Sharma ◽  
Mahesh Kumar ◽  
S. K. De

2018 ◽  
Vol 42 (18) ◽  
pp. 15044-15051 ◽  
Author(s):  
Vinay S. Sharma ◽  
Anuj S. Sharma ◽  
Rajesh H. Vekariya

A new family of bowl-shaped molecules with a calix[4]arene rigid core and appended on four-sides, that display a wide range of hexagonal columnar phases, has been synthesised and well characterized.


Gels ◽  
2018 ◽  
Vol 4 (3) ◽  
pp. 78 ◽  
Author(s):  
Katja Steck ◽  
Claudia Schmidt ◽  
Cosima Stubenrauch

Gelled lyotropic liquid crystals can be formed by adding a gelator to a mixture of surfactant and solvent. If the gel network and the liquid-crystalline phase coexist without influencing each other, the self-assembly is called orthogonal. In this study, the influence of the organogelator 12-hydroxyoctadecanoic acid (12-HOA) on the lamellar and hexagonal liquid crystalline phases of the binary system H2O–C12E7 (heptaethylene glycol monododecyl ether) is investigated. More precisely, we added 12-HOA at mass fractions from 0.015 to 0.05 and studied the resulting phase diagram of the system H2O–C12E7 by visual observation of birefringence and by 2H NMR spectroscopy. In addition, the dynamic shear moduli of the samples were measured in order to examine their gel character. The results show that 12-HOA is partly acting as co-surfactant, manifested by the destabilization of the hexagonal phase and the stabilization of the lamellar phase. The higher the total surfactant concentration, the more 12-HOA is incorporated in the surfactant layer. Accordingly, its gelation capacity is substantially reduced in the surfactant solution compared to the system 12-HOA–n-decane, and large amounts of gelator are required for gels to form, especially in the lamellar phase.


2005 ◽  
Vol 38 (9) ◽  
pp. 3554-3557 ◽  
Author(s):  
Jianwei Xu ◽  
Xueming Liu ◽  
Tingting Lin ◽  
Junchao Huang ◽  
Chaobin He

2021 ◽  
Vol 9 ◽  
Author(s):  
Hiroaki Iguchi ◽  
Hidenori Furutani ◽  
Nobuo Kimizuka

A new family of liquid π-donors, lipophilic dihydrophenazine (DHP) derivatives, show remarkably high π-electron-donor property which exhibit supramolecular alternating copolymerization with 7,7,8,8-tetracyanoquinodimethane (TCNQ), giving ionic charge-transfer (ICT) complexes. The ICT complexes form distinct columnar liquid crystalline (LC) mesophases with well-defined alternating molecular alignment as demonstrated by UV-Vis-NIR spectra, IR spectra, and X-ray diffraction (XRD) patterns. These liquid crystalline ICT complexes display unique phase transitions in response to mechanical stress: the columnar ICT phase is converted to macroscopically oriented smectic-like mesophases upon applying shear force. Although there exist reports on the formation of ICT in the crystalline state, this study provides the first rational identification of ICT mesophases based on the spectroscopic and structural data. The liquid crystalline ICT phases are generated by strong electronic interactions between the liquid π-donors and solid acceptors. It clearly shows the significance of simultaneous fulfillment of strong π-donating ability and ordered self-assembly of the stable ICT pairs. The flexible, stimuli-responsive structural transformation of the ICT complexes offer a new perspective for designing processable CT systems with controlled hierarchical self-assembly and electronic structures.


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