Phenol Removal from Wastewater by CWPO process over Cu-MOF nanocatalyst- Process Modeling by Response Surface methodology (RSM) and kinetic and Isothermal Studies

2021 ◽  
Author(s):  
Ozra Golipoor ◽  
Seyed Ali Hosseini
Keyword(s):  
Aqueous Solution ◽  
Response Surface Methodology ◽  
Response Surface ◽  
Process Modeling ◽  
Metal Organic Frameworks ◽  
Phenol Removal ◽  
Porous Structures ◽  
Phenol Compounds ◽  
Metal Organic

Water-stable metal-organic frameworks (MOFs), with their unique porous structures, have attracted the attention of scientists exploring novel and efficient ways for the elimination of phenol compounds from aqueous solution. Several...

scholarly journals Highly sensitive detection of nitrobenzene by a series of fluorescent 2D zinc(ii) metal–organic frameworks with a flexible triangular ligand

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 23975-23984
Author(s):  
Xue Yang ◽  
Yixia Ren ◽  
Hongmei Chai ◽  
Xiufang Hou ◽  
Zhixiang Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
High Sensitivity ◽  
Fluorescent Sensors ◽  
Sensitive Detection ◽  
Donor Ligands ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection

Four fluorescent 2D Zn-MOFs based on a flexible triangular ligand and linear N-donor ligands are hydrothermally prepared and used to detect nitrobenzene in aqueous solution with high sensitivity, demonstrating their potential as fluorescent sensors.

scholarly journals Synthesis of metal–organic frameworks (MOFs) MIL-100(Fe) functionalized with thioglycolic acid and ethylenediamine for removal of eosin B dye from aqueous solution

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Adedibu C. Tella ◽  
Janet T. Bamgbose ◽  
Vincent O. Adimula ◽  
Mary Omotoso ◽  
Sunday E. Elaigwu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Thioglycolic Acid ◽  
Metal Organic Frameworks ◽  
Thiol Group ◽  
Spectroscopic Techniques ◽  
Base Interaction ◽  
Adsorption Capacities ◽  
Melting Point Analysis ◽  
Eosin B ◽  
Metal Organic

AbstractThe interaction of eosin B dye from aqueous solution with MIL-100(Fe) and functionalized MIL-100(Fe) metal–organic frameworks (MOFs) is reported in this study. MIL-100(Fe) was prepared and functionalized with thioglycolic acid (TH) and ethylenediammine (ED) separately by incorporating the thiol (–SH) and the amine (–NH2) group of the functionalizing agents into the open metal sites of the MIL-100(Fe) to obtain the acidic (TH-MIL-100) and basic (ED-MIL-100) forms of the MOF respectively. Characterization of the MOFs was done by melting point analysis, elemental analysis, spectroscopic techniques, scanning electron microscopy (SEM), and powdered X-ray diffraction (PXRD) analysis. The adsorption experiments were carried out at different conditions such as pH, adsorbent dosage, contact time, temperature, and initial concentration of the dye to estimate the optimum conditions and the maximum adsorption capacities. Adsorption capacities were observed to increase in the order of ED-MIL-100 < MIL-100 < TH-MIL-100, while the TH-MIL-100 was the most effective in the removal process due to acid–base interaction between the acidic thiol group (–SH) and the alkaline medium of eosin B dye solution. The Langmuir Isotherm was seen to fit well to adsorption data obtained for all three adsorbent materials studied, and adsorption processes followed the pseudo-second order kinetics. This study, therefore, indicates the suitability of functionalization of MIL-100(Fe) towards improving its adsorption capacity.

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