Temperature dependent quantum cutting in cubic BaGdF5:Eu3+ nanophosphors

2021 ◽  
Author(s):  
Yogendra Nath Chouryal ◽  
Rahul Kumar Sharma ◽  
Konstantin V. Ivanovskikh ◽  
Aleksey V. Ishchenko ◽  
Qiufeng Shi ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Temperature Dependent ◽  
Structure Directing Agent ◽  
Quantum Cutting ◽  
Task Specific Ionic Liquid

A task-specific ionic liquid (IL) is employed as a structure directing agent for the synthesis of quantum cutting BaGdF5:Eu3+ nanophosphors.

scholarly journals Using Reverse Osmosis Membrane at High Temperature for Water Recovery and Regeneration from Thermo-Responsive Ionic Liquid-Based Draw Solution for Efficient Forward Osmosis

Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 588
Author(s):  
Eiji Kamio ◽  
Hiroki Kurisu ◽  
Tomoki Takahashi ◽  
Atsushi Matsuoka ◽  
Tomohisa Yoshioka ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
High Temperature ◽  
Energy Saving ◽  
Osmotic Pressure ◽  
Reverse Osmosis ◽  
Forward Osmosis ◽  
Solution Temperature ◽  
Water Recovery ◽  
Temperature Dependent ◽  
Draw Solution

Forward osmosis (FO) membrane process is expected to realize energy-saving seawater desalination. To this end, energy-saving water recovery from a draw solution (DS) and effective DS regeneration are essential. Recently, thermo-responsive DSs have been developed to realize energy-saving water recovery and DS regeneration. We previously reported that high-temperature reverse osmosis (RO) treatment was effective in recovering water from a thermo-responsive ionic liquid (IL)-based DS. In this study, to confirm the advantages of the high-temperature RO operation, thermo-sensitive IL-based DS was treated by an RO membrane at temperatures higher than the lower critical solution temperature (LCST) of the DS. Tetrabutylammonium 2,4,6-trimethylbenznenesulfonate ([N4444][TMBS]) with an LCST of 58 °C was used as the DS. The high-temperature RO treatment was conducted at 60 °C above the LCST using the [N4444][TMBS]-based DS-lean phase after phase separation. Because the [N4444][TMBS]-based DS has a significantly temperature-dependent osmotic pressure, the DS-lean phase can be concentrated to an osmotic pressure higher than that of seawater at room temperature (20 °C). In addition, water can be effectively recovered from the DS-lean phase until the DS concentration increased to 40 wt%, and the final DS concentration reached 70 wt%. From the results, the advantages of RO treatment of the thermo-responsive DS at temperatures higher than the LCST were confirmed.

Pure-silica ZSM-22 zeolite rapidly synthesized by novel ionic liquid-directed dry-gel conversion

RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 49647-49654 ◽  
Author(s):  
Haimeng Wen ◽  
Yu Zhou ◽  
Jingyan Xie ◽  
Zhouyang Long ◽  
Wei Zhang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Conversion Process ◽  
Rapid Synthesis ◽  
Structure Directing Agent ◽  
Dry Gel Conversion ◽  
Pure Silica

Rapid synthesis of pure-silica ZSM-22 was achieved through dry-gel conversion process by using ionic liquid as the structure directing agent.

scholarly journals Task specific ionic liquid as solvent, catalyst and reagent for regioselective ring opening of epoxides in water

2019 ◽  
Vol 12 (8) ◽  
pp. 2098-2103 ◽  
Author(s):  
Eshagh Rezaee Nezhad ◽  
Sami Sajjadifar ◽  
Fariba Heidarizadeh ◽  
Saaid Karimian
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Ring Opening Of Epoxides ◽  
Task Specific Ionic Liquid

scholarly journals Task-Specific Ionic Liquid Enables Highly Efficient Low Temperature Desalination by Directional Solvent Extraction

2020 ◽  
Author(s):  
Jiaji Guo ◽  
Zachary D. Tucker ◽  
Yu Wang ◽  
Brandon L. Ashfeld ◽  
Tengfei Luo
Keyword(s):  
Ionic Liquid ◽  
Solvent Extraction ◽  
Critical Role ◽  
Water Shortage ◽  
Computational Simulations ◽  
Water Energy Nexus ◽  
Directed Synthesis ◽  
Desalination Technology ◽  
Task Specific Ionic Liquid ◽  
Global Water

Seawater desalination plays a critical role in addressing the global water shortage challenge, and directional solvent extraction (DSE) is an emerging desalination technology to address this challenge. Herein, we demonstrate that through a combination of target-directed synthesis and computational simulations, task-specific ionic liquids (ILs) may significantly advance current DSE technology by improving the energy efficiency toward impacting the global water-energy nexus.

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