Porphyrin-based metal–organic framework catalysts for photoreduction of CO2: understanding the effect of node connectivity and linker metalation on activity

2020 ◽  
Vol 44 (36) ◽  
pp. 15362-15368
Author(s):  
Jiarui Jin
Keyword(s):  
Synergistic Effect ◽  
Metal Organic Framework ◽  
Photocatalytic Activities ◽  
Node Connectivity ◽  
Metal Organic ◽  
Organic Framework

The synergistic effect of linker defects and metalation on the photocatalytic activities of porphyrin-based MOFs.

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Precise regulating synergistic effect in metal–organic framework for stepwise-controlled adsorption

2021 ◽  
Author(s):  
Jiaxing Zhu ◽  
Yi Yu ◽  
Hongchuan Fan ◽  
Huaqiang Cai ◽  
Zhenxia Chen ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Shape Change ◽  
Metal Organic Framework ◽  
Pore Shape ◽  
Metal Organic ◽  
Controlled Adsorption ◽  
Dyes Mixture ◽  
Organic Framework

MAC-20 shows a unique two-step pore-shape change and executes a stepwise-controlled adsorption of dyes mixture in order of their sizes.

scholarly journals Merging Photoredox and Organometallic Catalysts in a Metal-Organic Framework Significantly Boosts Photocatalytic Activities

2018 ◽  
Vol 57 (43) ◽  
pp. 14090-14094 ◽  
Author(s):  
Yuan-Yuan Zhu ◽  
Guangxu Lan ◽  
Yingjie Fan ◽  
Samuel S. Veroneau ◽  
Yang Song ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Organometallic Catalysts ◽  
Photocatalytic Activities ◽  
Metal Organic ◽  
Organic Framework

Exploring the multifunctionality in metal–organic framework materials: how do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

2018 ◽  
Vol 42 (8) ◽  
pp. 6408-6415 ◽  
Author(s):  
Marina O. Barsukova ◽  
Sergey A. Sapchenko ◽  
Konstantin A. Kovalenko ◽  
Denis G. Samsonenko ◽  
Andrei S. Potapov ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Coordination Polymers ◽  
Metal Organic Framework ◽  
Luminescence Properties ◽  
Iodine Vapor ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

A synergistic effect causes MOF materials to demonstrate excellent iodine vapor retention and luminescence properties.

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