Macroporous polystyrene degraded and functionalized chromium MPS-Cr(iii)-alen complex as a sustainable porous catalyst for CO2 fixation under atmospheric pressure and selective oxidation of aromatic alkenes

2020 ◽  
Vol 44 (32) ◽  
pp. 13852-13862
Author(s):  
Priyanka Paul ◽  
Noor Salam ◽  
Aslam Khan ◽  
Debasis Das ◽  
Seikh Mafiz Alam ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Atmospheric Pressure ◽  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Porous Catalyst ◽  
Mild Conditions ◽  
Benign Synthesis

The benign synthesis of porous polystyrene supported chromium(iii) catalyst has been carried out for the production of cyclic carbonates via CO2 fixation under atm. pressure and for the selective oxidation of aromatic alkenes under mild conditions.

scholarly journals Design of bifunctional quaternary phosphonium salt catalysts for CO2 fixation reaction with epoxides under mild conditions

2016 ◽  
Vol 18 (17) ◽  
pp. 4611-4615 ◽  
Author(s):  
Shiyao Liu ◽  
Naoki Suematsu ◽  
Keiji Maruoka ◽  
Seiji Shirakawa
Keyword(s):  
Co2 Fixation ◽  
Phosphonium Salt ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Reaction Conditions ◽  
Mild Conditions ◽  
Phosphonium Iodide ◽  
Fixation Reaction ◽  
Quaternary Phosphonium Salt

An efficient synthesis of cyclic carbonates from epoxides and CO2 under mild reaction conditions was achieved via the use of a designed bifunctional quaternary phosphonium iodide catalyst.

Gold incorporated hematite nanocatalyst for solvent-free CO2 fixation under atmospheric pressure

2020 ◽  
Vol 44 (27) ◽  
pp. 11887-11894
Author(s):  
Gouri Tudu ◽  
Sourav Ghosh ◽  
Tanmoy Biswas ◽  
Venkataramanan Mahalingam
Keyword(s):  
Atmospheric Pressure ◽  
Co2 Fixation ◽  
Solvent Free ◽  
Cyclic Carbonates

Au/α-Fe2O3 as a nanocatalyst for the conversion of epoxides to cyclic carbonates utilizing CO2 under 1 atm. pressure.

An efficient CO2 fixation reaction with epoxides catalysed by in situ formed blue vanadium catalyst from dioxovanadium(+5) complex: moisture enhanced and atmospheric oxygen retarded catalytic activity

2020 ◽  
Vol 44 (6) ◽  
pp. 2547-2554 ◽  
Author(s):  
Rakhimoni Borah ◽  
Naranarayan Deori ◽  
Sanfaori Brahma
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Co2 Fixation ◽  
Atmospheric Oxygen ◽  
Carbon Dioxide Fixation ◽  
Vanadium Catalyst ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Fixation Reaction

In situ formed vanadium(+4) species catalyzed carbon dioxide fixation reaction, leading to 99% conversion of epoxides to cyclic carbonates under mild conditions is reported here, along with the study on the in situ formed catalyst to some extent.

Halide-free catalytic carbon dioxide fixation of epoxides to cyclic carbonates under atmospheric pressure

2022 ◽  
Author(s):  
Venkataramanan Mahalingam ◽  
Antarip Mitra ◽  
Tanmoy Biswas ◽  
Sourav Ghosh ◽  
Gouri Tudu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Atmospheric Pressure ◽  
Co2 Fixation ◽  
Carbon Dioxide Fixation ◽  
Cyclic Carbonates

Epoxides to cyclic carbonates conversion utilizing CO2 is one of the efficient approaches for CO2 fixation. Atmospheric fixation of CO2 generally required the use of halogen containing catalysts or additionally...

CO2 fixation at atmospheric pressure: porous ZnSnO3 nanocrystals as a highly efficient catalyst for the synthesis of cyclic carbonates

RSC Advances ◽  
2016 ◽  
Vol 6 (37) ◽  
pp. 31153-31160 ◽  
Author(s):  
Susmita Roy ◽  
Biplab Banerjee ◽  
Asim Bhaumik ◽  
Sk. Manirul Islam
Keyword(s):  
Atmospheric Pressure ◽  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Reaction Conditions ◽  
Efficient Catalyst ◽  
Zinc Stannate ◽  
Highly Efficient ◽  
Self Assembled

Self-assembled, ultra small, porous zinc stannate nanocrystals have been synthesized, which catalyzes the formation of cyclic carbonates from various epoxide and CO2 under very mild reaction conditions.

Poly(ionic liquid)s with high density of nucleophile /electrophile for CO2 fixation to cyclic carbonates at mild conditions

2019 ◽  
Vol 32 ◽  
pp. 281-289 ◽  
Author(s):  
Yaqiang Xie ◽  
Jun Liang ◽  
Yawen Fu ◽  
Ju Lin ◽  
Hongtao Wang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Co2 Fixation ◽  
High Density ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Poly Ionic Liquid

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

2018 ◽  
Vol 54 (4) ◽  
pp. 342-345 ◽  
Author(s):  
Jun Liang ◽  
Ya-Qiang Xie ◽  
Xu-Sheng Wang ◽  
Qiang Wang ◽  
Tao-Tao Liu ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Cyclic Carbonate ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A mesoporous cationic Cr-based metal–organic framework (MOF), FJI-C10, has been obtained and exhibited excellent performances in chemical fixation of CO2 into cyclic carbonates under co-catalyst free and mild conditions.

Synthesis of nitriles from amines using nanoscale Co3O4-based catalysts via sustainable aerobic oxidation

2016 ◽  
Vol 14 (13) ◽  
pp. 3356-3359 ◽  
Author(s):  
Kishore Natte ◽  
Rajenahally V. Jagadeesh ◽  
Muhammad Sharif ◽  
Helfried Neumann ◽  
Matthias Beller
Keyword(s):  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Mild Conditions ◽  
Benign Synthesis

The selective oxidation of amines for the benign synthesis of nitriles under mild conditions is described.

Synthesis of α-alkylidene cyclic carbonates via CO2 fixation under ambient conditions promoted by an easily available silver carbamate

2021 ◽  
Vol 45 (9) ◽  
pp. 4340-4346 ◽  
Author(s):  
Giulio Bresciani ◽  
Marco Bortoluzzi ◽  
Claudia Ghelarducci ◽  
Fabio Marchetti ◽  
Guido Pampaloni
Keyword(s):  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Ambient Conditions ◽  
Mild Conditions ◽  
Silver Carbamate

A series of α-alkylidene cyclic carbonates has been synthesized under mild conditions using silver carbamate Ag(O2CNEt2) in combination with PPh3.

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