Stimuli-responsive supramolecular polymer network based on bi-pillar[5]arene for efficient adsorption of multiple organic dye contaminants

2020 ◽  
Vol 44 (29) ◽  
pp. 12531-12537 ◽  
Author(s):  
Tai-Bao Wei ◽  
Li-Hua Qi ◽  
Qin-Peng Zhang ◽  
Wen-Huan Zhang ◽  
Hong Yao ◽  
...  

A novel supramolecular polymer network gel has been successfully prepared via bi-pillar[5]arene and a tripodal guest, exhibiting multi-stimuli-responsiveness and efficient adsorption of organic dyes.

Soft Matter ◽  
2018 ◽  
Vol 14 (42) ◽  
pp. 8529-8536 ◽  
Author(s):  
You-Ming Zhang ◽  
Yong-Fu Li ◽  
Hu Fang ◽  
Jun-Xia He ◽  
Bi-Rong Yong ◽  
...  

A novel pseudorotaxanes-type crosslinker of a supramolecular polymer network (WP5-PN) was constructed based on water-soluble pillar[5]arene (WP5) and naphthalene dimethylamine derivative (PN) via host-guest interactions.


2017 ◽  
Vol 8 (25) ◽  
pp. 3783-3787 ◽  
Author(s):  
Yuezhou Liu ◽  
Liqing Shangguan ◽  
Hu Wang ◽  
Danyu Xia ◽  
Bingbing Shi

A novel external stimuli-responsive supramolecular polymer network gel was fabricated by orthogonal Ag-coordination and pillar[5]arene-based host–guest interactions.


2014 ◽  
Vol 50 (6) ◽  
pp. 722-724 ◽  
Author(s):  
Jiayi Zhan ◽  
Qi Li ◽  
Qiuyue Hu ◽  
Qianqian Wu ◽  
Cunmin Li ◽  
...  

2019 ◽  
Vol 30 (12) ◽  
pp. 2299-2303 ◽  
Author(s):  
Zengjie Liu ◽  
Jiarui Wu ◽  
Chunyu Wang ◽  
Jie Yang ◽  
Yan Wang ◽  
...  

2020 ◽  
Vol 97 (3-4) ◽  
pp. 137-145
Author(s):  
Jun-Nian An ◽  
Wen-Juan Qu ◽  
Qin-Peng Zhang ◽  
Xiao-Qiang Ma ◽  
Wen-Bo Zhu ◽  
...  

2021 ◽  
Vol 22 (11) ◽  
pp. 5740
Author(s):  
Ramón Cervera-Procas ◽  
José-Luis Serrano ◽  
Ana Omenat

Highly functional macromolecules with a well-defined architecture are the key to designing efficient and smart materials, and these polymeric systems can be tailored for specific applications in a diverse range of fields. Herein, the formation of a new liquid crystalline polymeric network based on the crosslinking of dendrimeric entities by the CuI-catalyzed variant of the Huisgen 1,3-dipolar cycloaddition of azides and alkynes to afford 1,2,3-triazoles is reported. The polymeric material obtained in this way is easy to process and exhibits a variety of properties, which include mesomorphism, viscoelastic behavior, and thermal contraction. The porous microstructure of the polymer network determines its capability to absorb solvent molecules and to encapsulate small molecules, like organic dyes, which can be released easily afterwards. Moreover, all these properties may be easily tuned by modifying the chemical structure of the constituent dendrimers, which makes this system a very interesting one for a number of applications.


2017 ◽  
Vol 50 (15) ◽  
pp. 5759-5766 ◽  
Author(s):  
Yan Wang ◽  
Ming-Zhe Lv ◽  
Nan Song ◽  
Zeng-Jie Liu ◽  
Chunyu Wang ◽  
...  

2016 ◽  
Vol 2 (1) ◽  
pp. e1501297 ◽  
Author(s):  
Qian Zhao ◽  
Weike Zou ◽  
Yingwu Luo ◽  
Tao Xie

Stimuli-responsive materials with sophisticated yet controllable shape-changing behaviors are highly desirable for real-world device applications. Among various shape-changing materials, the elastic nature of shape memory polymers allows fixation of temporary shapes that can recover on demand, whereas polymers with exchangeable bonds can undergo permanent shape change via plasticity. We integrate the elasticity and plasticity into a single polymer network. Rational molecular design allows these two opposite behaviors to be realized at different temperature ranges without any overlap. By exploring the cumulative nature of the plasticity, we demonstrate easy manipulation of highly complex shapes that is otherwise extremely challenging. The dynamic shape-changing behavior paves a new way for fabricating geometrically complex multifunctional devices.


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