Synthesis and characterization of bis(dithiafulvenyl)-substituted fluorenones and fluorenylidene-1,3-dithioles

2020 ◽  
Vol 44 (22) ◽  
pp. 9179-9189
Author(s):  
Fatemeh Salami ◽  
Yuming Zhao

A series of π-conjugated oligomers containing redox-active dithiafulvenyl (DTF) end groups and fluorenone/fluorenylidene-1,3-dithiole central units was synthesized and their structural, electronic, and electrochemical properties were investigated.

2005 ◽  
Vol 24 (12) ◽  
pp. 2834-2847 ◽  
Author(s):  
Koushik Venkatesan ◽  
Thomas Fox ◽  
Helmut W. Schmalle ◽  
Heinz Berke

RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12995-13003
Author(s):  
Jialin Yang ◽  
Li Yang ◽  
Qianqian Chen ◽  
Keke Guo ◽  
Ji-Min Han

We report a pyridine-flanked diketopyrrolopyrrole monomer and all-acceptor conjugated polymers synthesized therefrom. Photophysical, thermal and electrochemical properties of the polymers have been determined.


2009 ◽  
Vol 13 (02) ◽  
pp. 223-234 ◽  
Author(s):  
Tomasz Goslinski ◽  
Ewa Tykarska ◽  
Wojciech Szczolko ◽  
Tomasz Osmalek ◽  
Aleksandra Smigielska ◽  
...  

The condensation reaction of 2-amino-3-[(3-pyridylmethyl)amino]-2(Z)-butene-1,4-dinitrile with a series of diketones led to novel dinitriles, of which 2-(2,5-dimethyl-1H-pyrrol-1-yl)-3-[methyl(3-pyridylmethylene)amino]-2(Z)-butene-1,4-dinitrile, the product of the Paal-Knorr reaction, was successfully utilized in the Linstead macrocyclization towards symmetrical and unsymmetrical porphyrazines. NMR and X-ray study revealed an almost perpendicular orientation of the pyrrolyl groups in relation to the porphyrazine platform. The newly synthesized macrocycles with different peripheral groups show interesting spectroscopic and electrochemical properties. Due to selective sensor/coordination properties they are expected to find applications as chemical sensors and electronic materials.


2005 ◽  
Vol 54 (12) ◽  
pp. 1599-1605 ◽  
Author(s):  
Elif Sahin ◽  
Pinar Camurlu ◽  
Levent Toppare ◽  
Viorela M Mercore ◽  
Ioan Cianga ◽  
...  

2014 ◽  
Vol 5 (11) ◽  
pp. 4483-4489 ◽  
Author(s):  
Elizabeth Amir ◽  
Masahito Murai ◽  
Roey J. Amir ◽  
John S. Cowart ◽  
Michael L. Chabinyc ◽  
...  

The properties of isomeric azulene derivatives based on 7- versus 5-membered ring substitution were examined by the synthesis and characterization of well-defined electroactive oligomers.


2019 ◽  
Vol 772 ◽  
pp. 429-437 ◽  
Author(s):  
Xing Liang ◽  
Guohua Gao ◽  
Shizhan Feng ◽  
Yuchuan Du ◽  
Guangming Wu

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