Construction of 3D lanthanide based MOFs with pores decorated with basic imidazole groups for selective capture and chemical fixation of CO2

2020 ◽  
Vol 44 (21) ◽  
pp. 9090-9096
Author(s):  
Sandeep Singh Dhankhar ◽  
C. M. Nagaraja
Keyword(s):  
Value Added ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Rational Construction

Rational construction of three new 3D lanthanide-based MOFs exhibiting selective CO2 capture and conversion to value-added cyclic carbonates under mild conditions is reported.

scholarly journals Study of Superbase-Based Deep Eutectic Solvents as the Catalyst in the Chemical Fixation of CO2 into Cyclic Carbonates under Mild Conditions

Materials ◽  
2017 ◽  
Vol 10 (7) ◽  
pp. 759 ◽  
Author(s):  
Sara García-Argüelles ◽  
Maria Ferrer ◽  
Marta Iglesias ◽  
Francisco Del Monte ◽  
María Gutiérrez
Keyword(s):  
Deep Eutectic Solvents ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions

Anion-induced 3d–4f luminescent coordination clusters: structural characteristics and chemical fixation of CO2 under mild conditions

2018 ◽  
Vol 47 (21) ◽  
pp. 7159-7165 ◽  
Author(s):  
Ruilian Zhang ◽  
Li Wang ◽  
Cong Xu ◽  
Huan Yang ◽  
Wanmin Chen ◽  
...  
Keyword(s):  
Structural Characteristics ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions

Anion-induced clusters with luminescence exhibit excellent catalysis to transform CO2 into cyclic carbonates under mild conditions.

scholarly journals Recent Advances in the Chemical Fixation of Carbon Dioxide: A Green Route to Carbonylated Heterocycle Synthesis

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 511 ◽  
Author(s):  
Renato Dalpozzo ◽  
Nicola Della Ca’ ◽  
Bartolo Gabriele ◽  
Raffaella Mancuso
Keyword(s):  
Carbon Dioxide ◽  
Value Added ◽  
The Other ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Heterocycle Synthesis ◽  
Green Industry ◽  
Green Route ◽  
Earth’S Climate ◽  
Fixation Of Carbon Dioxide

Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemicals are integral parts of today’s green industry. On the other hand, carbon dioxide is a ubiquitous, cheap, abundant, non-toxic, non-flammable and renewable C1 source. Among CO2 usages, this review aims to summarize and discuss the advances in the reaction of CO2, in the synthesis of cyclic carbonates, carbamates, and ureas appeared in the literature since 2017.

State-of-the-art catechol porphyrin COF catalyst for chemical fixation of carbon dioxide via cyclic carbonates and oxazolidinones

2016 ◽  
Vol 6 (15) ◽  
pp. 6152-6158 ◽  
Author(s):  
Vitthal Saptal ◽  
Digambar Balaji Shinde ◽  
Rahul Banerjee ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
State Of The Art ◽  
Value Added ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Metal Free ◽  
Highly Porous ◽  
Fixation Of Carbon Dioxide

A highly porous, crystalline catechol porphyrin COF was synthesized and applied as an organocatalyst for the fixation of carbon dioxide to synthesize value-added chemicals such as cyclic carbonates and oxazolidinones under solvent and transition-metal-free conditions.

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

2018 ◽  
Vol 54 (4) ◽  
pp. 342-345 ◽  
Author(s):  
Jun Liang ◽  
Ya-Qiang Xie ◽  
Xu-Sheng Wang ◽  
Qiang Wang ◽  
Tao-Tao Liu ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Cyclic Carbonate ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A mesoporous cationic Cr-based metal–organic framework (MOF), FJI-C10, has been obtained and exhibited excellent performances in chemical fixation of CO2 into cyclic carbonates under co-catalyst free and mild conditions.

Efficient chemical fixation of CO2 from direct air under environment-friendly co-catalyst and solvent-free ambient conditions

2021 ◽  
Author(s):  
Rajesh Das ◽  
THIRUMAVALAVAN EZHIL ◽  
Athulya S. Palakkal ◽  
Devaraj Muthukumar ◽  
Renjith S. Pillai ◽  
...  
Keyword(s):  
Environmental Remediation ◽  
Value Added ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Ambient Conditions ◽  
Energy Sustainability ◽  
Environment Friendly ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Value Added Products

The capture and conversion of CO2 from direct air into value-added products under mild conditions represents a promising step towards environmental remediation and energy sustainability. Consequently, herein, we report application...

An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions

2016 ◽  
Vol 18 (5) ◽  
pp. 1229-1233 ◽  
Author(s):  
Lin Wang ◽  
Guangyou Zhang ◽  
Koichi Kodama ◽  
Takuji Hirose
Keyword(s):  
Significant Loss ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions

An efficient organocatalytic system was developed for the synthesis of cyclic carbonates from epoxides and CO2 (25–45 °C, 1 atm) in high-to-excellent yields (85–97%). Moreover, the 2,6-pyridinedimethanol system could be recycled several times without significant loss of activity.

Metal β-diketonate complexes as highly efficient catalysts for chemical fixation of CO2 into cyclic carbonates under mild conditions

2019 ◽  
Vol 48 (42) ◽  
pp. 15970-15976 ◽  
Author(s):  
Hongmei Wang ◽  
Zulei Zhang ◽  
Hailong Wang ◽  
Liping Guo ◽  
Lei Li
Keyword(s):  
Room Temperature ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Highly Efficient

Metal β-diketonate complexes could efficiently catalyze the chemical fixation of CO2 at 1 atm and near room temperature.

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