Direct conversion of cellulose into isosorbide over Ni doped NbOPO4 catalysts in water

2020 ◽  
Vol 44 (25) ◽  
pp. 10292-10299
Author(s):  
Minyao He ◽  
Jiaxing Guo ◽  
Xincheng Wang ◽  
Yongji Song ◽  
ShanShan Liu ◽  
...  

Ni doped NbOPO4 catalysts were used efficiently for the one-pot conversion of cellulose to isosorbide under aqueous conditions.

2019 ◽  
Vol 84 (17) ◽  
pp. 11323-11334 ◽  
Author(s):  
Arun Kumar ◽  
Naveen Kumar ◽  
Ritika Sharma ◽  
Gaurav Bhargava ◽  
Dinesh Mahajan

RSC Advances ◽  
2018 ◽  
Vol 8 (53) ◽  
pp. 30163-30170 ◽  
Author(s):  
Lei Feng ◽  
Gang Li ◽  
Yueer Yan ◽  
Wenrong Hou ◽  
Yahong Zhang ◽  
...  

Methyl glycerate (MGLY) and methyl glycolate (MG) are directly produced in maximum yield by the one-pot conversion of hexose, and the formation of MGLY and MG experience different reaction routes.


2021 ◽  
Vol 18 ◽  
Author(s):  
Yatin U. Gadkari ◽  
Rajesh D. Shanbhag ◽  
Vikas N. Telvekar

: An efficient methodology for the synthesis of 1,3-thiazolidin-4-ones using L-Proline as catalyst under aqueous conditions has been developed. The one-pot, multicomponent reaction of aromatic/heterocyclic aldehyde, aromatic amine and thioglycolic acid at room temperature give 1,3-thiazolidin-4-ones in moderate to good yields. Further, the current approach is notably greener than traditional methods with E-factor of 3.1 and the eco scale score of 96. The developed protocol offers several features, such as being simple, environmentally benign, energy-efficient, economical, mild conditions, shorter reaction time.


2020 ◽  
Vol 16 ◽  
pp. 1713-1721
Author(s):  
Isaline Bonnin ◽  
Raphaël Mereau ◽  
Thierry Tassaing ◽  
Karine De Oliveira Vigier

The catalytic conversion of (ligno)cellulose is currently subject of intense research. Isosorbide is one of the interesting products that can be produced from (ligno)cellulose as it can be used for the synthesis of a wide range of pharmaceuticals, chemicals, and polymers. Isosorbide is obtained after the hydrolysis of cellulose to glucose, followed by the hydrogenation of glucose to sorbitol that is then dehydrated to isosorbide. The one-pot process requires an acid and a hydrogenation catalyst. Several parameters are of importance during the direct conversion of (ligno)cellulose such as the acidity, the crystallinity and the particle size of cellulose as well as the nature of the feedstocks. This review highlights all these parameters and all the strategies employed to produce isosorbide from (ligno)cellulose in a one-pot process.


2012 ◽  
Vol 326-328 ◽  
pp. 372-376
Author(s):  
Seyed Javad Ahmadi ◽  
Sodeh Sadjadi ◽  
Morteza Hosseinpour

An efficient method for the synthesis of 4-amino-5-pyrimidinecarbonitriles by three-component reaction of malononitrile, aldehydes and N-unsubstituted amidines, under aqueous conditions, using CuO nanoparticles as catalyst is reported. The protocol offers advantages in terms of higher yields, short reaction times, and mild reaction conditions, with reusability of the catalyst.


2010 ◽  
Vol 40 (13) ◽  
pp. 2007-2013 ◽  
Author(s):  
Rahim Hekmatshoar ◽  
Ghodsieh Nanva Kenary ◽  
Sodeh Sadjadi ◽  
Yahya S. Beheshtiha

2017 ◽  
Vol 6 (3) ◽  
Author(s):  
Lucília S. Ribeiro ◽  
José J.M. Órfão ◽  
Manuel F.R. Pereira

AbstractDifferent supported metal catalysts were tested for the one-pot transformation of corncob xylan to xylitol. The influence of several factors, such as catalytic support, nature of metal, metal loading, amount of catalyst, hydrogen pressure and reaction temperature, was investigated. The results revealed that xylan can be converted into xylitol with a yield close to 80% after 2 h of reaction using Ru supported on carbon nanotubes (CNT, 0.4 wt% metal loading) with excellent stability after repeated use, at a temperature of 170°C and an H


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