Flavanthrone – a new ligand with accessible radical anion and dianion states: preparation of zwitterionic {(Cp2V)2(flavanthrone)} and {(Cp2V)2(chloranil)} complexes

2020 ◽  
Vol 44 (26) ◽  
pp. 10849-10858 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Mikhail G. Andronov ◽  
Mikhail S. Batov ◽  
Alexey V. Kuzmin ◽  
Salavat S. Khasanov ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Radical Anion ◽  
Radical Anions ◽  
Optical And Magnetic Properties

Molecular structure, optical and magnetic properties of the radical anions and dianions of flavanthrone dye are presented. Flavanthrone and chloranil coordinate two vanadocenes forming zwitter-ionic {(Cp2V+)2(Flavanthrone2−)} and {(Cp2V+)2(QCl42−)}.

scholarly journals Crystalline salts of metal phthalocyanine radical anions [M(Pc˙3−)]˙− (M = CuII, PbII, VIVO, SnIVCl2) with cryptand(Na+) cations: structure, optical and magnetic properties

2017 ◽  
Vol 41 (14) ◽  
pp. 6866-6874 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Maxim A. Faraonov ◽  
Alexey V. Kuzmin ◽  
Salavat S. Khasanov ◽  
Yoshiaki Nakano ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Radical Anion ◽  
Radical Anions ◽  
Metal Phthalocyanine ◽  
Metal Phthalocyanines ◽  
Optical And Magnetic Properties

Radical anion salts of metal phthalocyanines (M = CuII, PbII, VIVO and SnIVCl2) with the {cryptand(Na+)} cations have been obtained and studied.

Negatively charged singly-bonded dimers of C1-[C70(CF3)10] and bare C70 fullerene

2019 ◽  
Vol 43 (6) ◽  
pp. 2726-2733 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Salavat S. Khasanov ◽  
Alexey A. Goryunkov ◽  
Sergey I. Troyanov ◽  
Victor A. Brotsman ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Optical And Magnetic Properties

Singly-bonded {C70(CF3)10−}2 and (C70−)2 dimers are obtained as crystalline salts allowing their molecular structure, and optical and magnetic properties to be studied.

scholarly journals Radical anion and dianion salts of titanyl macrocycles with acceptor substituents or an extended π-system

2017 ◽  
Vol 46 (11) ◽  
pp. 3547-3555 ◽  
Author(s):  
Maxim A. Faraonov ◽  
Dmitri V. Konarev ◽  
Alexey M. Fatalov ◽  
Salavat S. Khasanov ◽  
Sergey I. Troyanov ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Radical Anion ◽  
System P ◽  
Optical And Magnetic Properties

Crystalline anionic salts of titanyl macrocycles: (PPN+)2{OTiIV(PcCl84−)}2− (1), (PPN+){OTiIV(Nc˙3−)}˙−·solv (2) and (PPN+)2{OTiIV(AceTPrzPz4−)}2−·solv (see figure, 3) have been obtained and their optical and magnetic properties are studied.

Solid State Structure, and Optical and Magnetic Properties, of Free Base Tetra(4-pyridyl)porphyrin {H2T(4-Py)P}•– Radical Anions

2018 ◽  
Vol 83 (4) ◽  
pp. 1861-1866 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Aleksey V. Kuzmin ◽  
Salavat S. Khasanov ◽  
Alexander F. Shestakov ◽  
Evgeniya I. Yudanova ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Solid State ◽  
Radical Anions ◽  
Free Base ◽  
State Structure ◽  
Solid State Structure ◽  
Optical And Magnetic Properties

Molecular Structure, Optical and Magnetic Properties of Dianionic Free-Base Tetrapyrazinoporphyrazine Macrocycle

2018 ◽  
Vol 3 (16) ◽  
pp. 4339-4343 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Maxim A. Faraonov ◽  
Alexey V. Kuzmin ◽  
Alexey M. Fatalov ◽  
Nikita G. Osipov ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Free Base ◽  
Optical And Magnetic Properties

scholarly journals Molecular Structure, Optical, and Magnetic Properties of Free-Base Naphthalocyanine Dianions

2018 ◽  
Vol 2018 (26) ◽  
pp. 3410-3415 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Salavat S. Khasanov ◽  
Yoshiaki Nakano ◽  
Alexander F. Shestakov ◽  
Manabu Ishikawa ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Free Base ◽  
Optical And Magnetic Properties

Molecular structures, and optical and magnetic properties of free-base tetrapyrazinoporphyrazine in various reduction states

2019 ◽  
Vol 43 (48) ◽  
pp. 19214-19222 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Maxim A. Faraonov ◽  
Alexey V. Kuzmin ◽  
Nikita G. Osipov ◽  
Salavat S. Khasanov ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Characterization ◽  
Radical Anion ◽  
Molecular Structures ◽  
The Novel ◽  
Free Base ◽  
Optical And Magnetic Properties

The synthesis, and spectral and structural characterization of the novel radical anion and dianion salts of free-base tetrapyrazinoporphyrazine (H2TPyzPz) as well as studies of their magnetic properties have been described.

Effect of reduction on the molecular structure and optical and magnetic properties of fluorinated copper(ii) phthalocyanines

2020 ◽  
Vol 49 (46) ◽  
pp. 16821-16829
Author(s):  
Dmitri V. Konarev ◽  
Maxim A. Faraonov ◽  
Mikhail S. Batov ◽  
Mikhail G. Andronov ◽  
Alexey V. Kuzmin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Structure And Properties ◽  
Optical And Magnetic Properties

New salts based on reduced fluorinated copper(ii) phthalocyanines were obtained. The effect of reduction on the molecular structure and properties of the  [CuII(FxPc)]n− (x = 8 and 16) species in reduced states (n = 1 and 2) was studied.

Sign in / Sign up

Export Citation Format

Share Document