Monoalkylation of aniline with trichloroacetimidate catalyzed by (±)-camphorsulfonic acid through an SN1 reaction based on dual hydrogen-bonding activation modes

2020 ◽  
Vol 44 (14) ◽  
pp. 5526-5534
Author(s):  
Ka Lu ◽  
Yang Dai ◽  
Chao-Xian Yan ◽  
Fang-Ling Yang ◽  
Xing Yang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Camphorsulfonic Acid

Herein, the monoalkylation of anilines with trichloroacetimidates catalyzed by CSA was investigated theoretically, and it was found that the reaction occurred through an SN1 reaction involving the dual hydrogen-bonding activation modes.

Excited-state hydrogen-bonding dynamics of camphorsulfonic acid doped polyaniline: a theoretical study

2014 ◽  
Vol 16 (47) ◽  
pp. 26261-26265 ◽  
Author(s):  
Yahong Zhang ◽  
Yuping Duan ◽  
Tongmin Wang
Keyword(s):  
Hydrogen Bonding ◽  
Excited State ◽  
Theoretical Study ◽  
Camphorsulfonic Acid ◽  
Doped Polyaniline ◽  
Hydrogen Bonding Dynamics

We present a TDDFT study on excited-state hydrogen-bonding dynamics of a camphorsulfonic acid doped polyaniline complex.

Hydrogen bonding in liquid methanol at ambient conditions and at high pressure

2000 ◽  
Vol 98 (3) ◽  
pp. 125-134 ◽  
Author(s):  
T. Weitkamp, J. Neuefeind, H. E. Fisch
Keyword(s):  
High Pressure ◽  
Hydrogen Bonding ◽  
Ambient Conditions

Fluorescence and pi-hydrogen bonding in naphthols

1968 ◽  
Vol 65 ◽  
pp. 1587-1589 ◽  
Author(s):  
Bithika Ghosh ◽  
Sadhan Basu
Keyword(s):  
Hydrogen Bonding

Theoretical study of intramolecular hydrogen bonding and molecular geometry of 2-trifluoromethylphenol

10.1002/jcc.2 ◽  
1996 ◽  
Vol 17 (16) ◽  
pp. 1804-1819 ◽  
Author(s):  
Attila Kov�cs ◽  
Istv�n Kolossv�ry ◽  
G�bor I. Csonka ◽  
Istv�n Hargittai
Keyword(s):  
Hydrogen Bonding ◽  
Theoretical Study ◽  
Molecular Geometry ◽  
Intramolecular Hydrogen Bonding ◽  
Intramolecular Hydrogen

PEMANFAATAN GLISERIN DARI RESIDU GLISERIN SEBAGAI PLASTICIZER UNTUK PEMBUATAN BIOPLASTIK DENGAN BAHAN BAKU PATI BONGGOL PISANG KEPOK

2017 ◽  
Vol 5 (4) ◽  
pp. 26-32 ◽  
Author(s):  
Azaria Robiana ◽  
M. Yashin Nahar ◽  
Hamidah Harahap
Keyword(s):  
Tensile Strength ◽  
Hydrogen Bonding ◽  
Fatty Acid ◽  
Maximum Yield ◽  
Sem Analysis ◽  
Water Molecules ◽  
Banana Weevil ◽  
Gelatinization Temperature ◽  
Recharge Area ◽  
Maximum Quantity

Glycerin residue is waste oleochemical industry that still contain glycerin. To produce quality and maximum quantity of glycerin, then research the effect of pH acidification using phosphoric acid. Glycerin analysis includes the analysis of pH, Fatty Acid and Ester (FAE), and analysis of the levels of glycerin. The maximum yield obtained at pH acidification 2 is grading 91,60% glycerin and Fatty Acid and Ester (FAE) 3,63 meq/100 g. Glycerin obtained is used as a plasticizer in the manufacture of bioplastics. Manufacture of bioplastics using the method of pouring a solution with varying concentrations of starch banana weevil (5% w/v and 7% w/v), variations of the addition of glycerin (1 ml, 3 ml, 5 ml and 7 ml), and a variety of gelatinization temperature (60°C, 70°C, and 80°C). Analysis of bioplastics include FTIR testing, tensile strength that is supported by SEM analysis. The results obtained in the analysis of FTIR does not form a new cluster on bioplastics starch banana weevil, but only a shift in the recharge area only, it is due to the addition of O-H groups originating from water molecules that enter the polysaccharide through a mechanism gelatinitation that generates interaction hydrogen bonding strengthened. The maximum tensile strength of bioplastics produced at a concentration of starch 7% w/v, 1 ml glycerine and gelatinization temperature of 80°C is 3,430 MPa. While the tensile strength bioplastic decreased with increasing glycerin which can be shown from the results of SEM where there is a crack, indentations and lumps of starch insoluble.

Hydrogen bonding and conformations in echitamine salts

1963 ◽  
Vol 119 (3-4) ◽  
pp. 252-256 ◽  
Author(s):  
Brahama D. Sharma ◽  
Richard E. Marsh ◽  
Jerry Donohue
Keyword(s):  
Hydrogen Bonding

A neutron diffraction study of hydrogen bonding in the deuterium (hydrogen) L-arginine phosphate monohydrate

1997 ◽  
Vol 212 (3) ◽  
Author(s):  
Z. Cheng ◽  
Y. Cheng ◽  
L. Guo ◽  
D. Xu
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Neutron Diffraction ◽  
Diffraction Study ◽  
Title Compound ◽  
Neutron Diffraction Study ◽  
Chemical Formula

AbstractThe crystal structure of the title compound D(H)LAP with chemical formula (D

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