scholarly journals Effects of gas-phase and wet-chemical surface treatments on substrates induced vertical, valley–hill & micro-granular growth morphologies of close space sublimated CdTe films

2020 ◽  
Vol 2 (10) ◽  
pp. 4757-4769
Author(s):  
Kulandai Velu Ramanathan ◽  
Balakrishnan Shankar ◽  
Shantikumar V. Nair ◽  
Mariyappan Shanmugam
Keyword(s):  
Optical Properties ◽  
Charge Transport ◽  
Gas Phase ◽  
Surface Treatments ◽  
Transport Kinetics ◽  
Chemical Surface ◽  
Wet Chemical ◽  
Cdte Films

Substrates induced growth morphologies in CdTe. These were further treated by wet-chemical and gas-phase methods which effectively changed structure, optical properties and charge transport kinetics.

Structure and Optical Properties CdS and CdTe Films on Flexible Substrate Obtained by DC Magnetron Sputtering for Solar Cells

2017 ◽  
Vol 9 (5) ◽  
pp. 05035-1-05035-6 ◽  
Author(s):  
G. I. Kopach ◽  
◽  
R. P. Mygushchenko ◽  
G. S. Khrypunov ◽  
A. I. Dobrozhan ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solar Cells ◽  
Magnetron Sputtering ◽  
Flexible Substrate ◽  
Dc Magnetron Sputtering ◽  
Cdte Films

Sector growth and symmetry of (F,OH) apatite from the Asio mine, Japan

1994 ◽  
Vol 58 (391) ◽  
pp. 307-314 ◽  
Author(s):  
Mizuhiko Akizuki ◽  
Hirotugu Nisidoh ◽  
Yasuhiro Kudoh ◽  
Tomohiro Watanabe ◽  
Kazuo Kurata
Keyword(s):  
Optical Properties ◽  
Crystal Growth ◽  
Electron Diffraction ◽  
Chemical Analysis ◽  
Growth Surface ◽  
Complete Disappearance ◽  
X Ray ◽  
Solid Crystal ◽  
Wet Chemical ◽  
Growth Features

AbstractA study of apatite crystals from the Asio mine, Japan, showed sectoral texture related to the growth of the crystal, and with optically biaxial properties within the sectors. Wet chemical analysis gave a composition Ca5(PO4)3(F0.64,OH0.38,Cl0.01)1.03 for the specimen.Additional diffraction spots were not observed in precession and oscillation X-ray photographs and electron diffraction photographs. Since the internal textures correlate with the surface growth features, it is suggested that the internal textures and the unusual optical properties were produced during nonequilibrium crystal growth. The fluorine/hydroxyl sites in hexagonal apatite are symmetrically equivalent in the solid crystal but, at a growth surface, this equivalence may be lost, resulting in a reduction of crystal symmetry. Heating of the apatite to about 850°C results in the almost complete disappearance of the optical anomalies due to disordering, which may be related to the loss of hydroxyl from the crystal.

NOHSO4/HF – A Novel Etching System for Crystalline Silicon

2007 ◽  
Vol 62 (11) ◽  
pp. 1411-1421 ◽  
Author(s):  
Sebastian Patzig ◽  
Gerhard Roewer ◽  
Edwin Kroke ◽  
Ingo över
Keyword(s):  
Gas Phase ◽  
Chemical Etching ◽  
Silicon Surface ◽  
Crystalline Silicon ◽  
Etching Solution ◽  
Wide Range ◽  
Ft Ir ◽  
Wet Chemical ◽  
Wet Chemical Etching ◽  
Etching System

Solutions consisting of HF - NOHSO4 - H2SO4 exhibit a strong reactivity towards crystalline silicon which is controlled by the concentrations of the reactive species HF and NO+. Selective isotropic and anisotropic wet chemical etching with these solutions allows to generate a wide range of silicon surface morphology patterns. Traces of Ag+ ions stimulate the reactivity and lead to the formation of planarized (polished) silicon surfaces. Analyses of the silicon surface, the etching solution and the gas phase were performed with scanning electron microscopy (SEM), DR/FT-IR (diffusive reflection Fourier transform infra-red), FT-IR, Raman and NMR spectroscopy, respectively. It was found that the resulting silicon surface is hydrogen-terminated. The gas phase contains predominantly SiF4, NO and N2O. Furthermore, NH4+ is produced in solution. The study has confirmed the crucial role of nitrosyl ions for isotropic wet chemical etching processes. The novel etching system is proposed as an effective new way for selective surface texturing of multi- and monocrystalline silicon. A high etching bath service lifetime, besides a low contamination of the etching solution with reaction products, provides ecological and economical advantages for the semiconductor and solar industry.

Near-Infrared Optical Properties and Charge Transport in Expanded Porphyrins

2021 ◽  
Vol MA2021-01 (16) ◽  
pp. 761-761
Author(s):  
Gloria Cardenas-Jiron ◽  
Merlys Borges-Martinez ◽  
Nicolas Montenegro-Pohlhammer ◽  
Yoh Yamamoto ◽  
Tunna Baruah ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transport ◽  
Near Infrared ◽  
Expanded Porphyrins ◽  
Infrared Optical Properties

Structure and optical properties of cerium(III)-doped PbWO4 micro-crystals synthesized by a facile wet chemical method

2009 ◽  
Vol 11 (6) ◽  
pp. 1131-1136 ◽  
Author(s):  
Yan Fang ◽  
Ying Xiong ◽  
Yuanlin Zhou ◽  
Jinxiang Chen ◽  
Kaiping Song ◽  
...  
Keyword(s):  
Optical Properties ◽  
Chemical Method ◽  
Wet Chemical Method ◽  
Wet Chemical

Theoretical study of charge-transport and optical properties of indeno[1,2-b]fluorene-6,12-dione-based semiconducting materials

2018 ◽  
Vol 74 (6) ◽  
pp. 705-711 ◽  
Author(s):  
Jin-Dou Huang ◽  
Jinfeng Zhao ◽  
Kun Yu ◽  
Xiaohua Huang ◽  
Shi-Bo Cheng ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transport ◽  
Near Infrared ◽  
Reorganization Energy ◽  
Hole Mobility ◽  
Side Chains ◽  
Semiconducting Materials ◽  
Π Stacking ◽  
Electron Transfer Theory ◽  
Reorganization Energies

The conducting and optical properties of a series of indeno[1,2-b]fluorene-6,12-dione (IFD)-based molecules have been systematically studied and the influences of butyl, butylthio and dibutylamino substituents on the reorganization energies, intermolecular electronic couplings and charge-injection barriers of IFD have been discussed. The quantum-chemical calculations combined with electron-transfer theory reveal that the incorporation of sulfur-linked side chains decreases reorganization energy associated with hole transfer and optimizes intermolecular π–π stacking, which results in excellent ambipolar charge-transport properties (μh = 1.15 cm2 V−1 s−1 and μe = 0.08 cm2 V−1 s−1); in comparison, addition of dibutylamino side chains increases intermolecular steric interactions and hinders perfect intermolecular π–π stacking, which results in the weak electronic couplings and finally causes the low intrinsic hole mobility (μh = 0.01 cm2 V−1 s−1). Furthermore, electronic spectra of butyl-IFD, butylthio-IFD and dibutylamino-IFD were simulated and compared with the reported experimental data. Calculations demonstrate that IFD-based molecules possess potential for developing novel infrared and near-infrared probe materials via suitable chemical modifications.

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