scholarly journals Analysing trimethylaluminum infiltration into polymer brushes using a scalable area selective vapor phase process

2021 ◽  
Author(s):  
M. Snelgrove ◽  
C. McFeely ◽  
K. Shiel ◽  
G. Hughes ◽  
P. Yadav ◽  
...  

This work identifies the critical factors when developing a polymer brush vapor phase infiltration process, while also demonstrating the use of novel pyridines for area selective purposes.

RSC Advances ◽  
2017 ◽  
Vol 7 (16) ◽  
pp. 9551-9561 ◽  
Author(s):  
An Li ◽  
Chen Huang ◽  
Cai-Wu Luo ◽  
Wen-Jun Yi ◽  
Zi-Sheng Chao

Quinoline was synthesized via the typical Skraup approach with a vapor-phase process. The mesoporous Ni/beta zeolite catalyst exhibited high-efficiency catalytic activity and an enhanced ability of anti-deactivation.


Small ◽  
2012 ◽  
Vol 8 (23) ◽  
pp. 3567-3567 ◽  
Author(s):  
Xuechang Zhou ◽  
Zhilu Liu ◽  
Zhuang Xie ◽  
Xuqing Liu ◽  
Zijian Zheng

2007 ◽  
Vol 1049 ◽  
Author(s):  
Jeffrey B. Sokoloff

AbstractIt is shown using a method based on the mean field theory of Miklavic Marcelja that it should be possible for osmotic pressure due to the counterions associated with the two polyelectrolyte polymer brush coated surfaces to support a reasonable load (i.e., about 105 Pa) with the brushes held sufficiently far apart to prevent entanglement of polymers belonging to the two brushes, thus avoiding what is likely to be the dominant mechanisms for static and dry friction.


Soft Matter ◽  
2021 ◽  
Author(s):  
Piotr Polanowski ◽  
Andrzej Sikorski

Monodisperse polymer brushes were studied by means of Monte Carlo simulations. A coarse-grained model of a polymer brush was designed in order and the Cooperative Motion Algorithm was employed to...


2021 ◽  
Author(s):  
Daniel Valles ◽  
Yerzhan Zholdassov ◽  
Adam Braunschweig

Hypersurface Photolithography (HP) is a printing method for fabricating structures and patterns composed of polymer brushes, and can be used to create patterns with complex topologies or for rapidly accelerating...


2020 ◽  
Vol 46 (3) ◽  
pp. 3009-3014 ◽  
Author(s):  
Chao Zhang ◽  
Ling Zhang ◽  
Xiaoxu Zhang ◽  
Peiyu Zheng ◽  
Fengyou Li

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1165 ◽  
Author(s):  
Tobias Mai ◽  
Karol Wolski ◽  
Agnieszka Puciul-Malinowska ◽  
Alexey Kopyshev ◽  
Ralph Gräf ◽  
...  

This article describes the synthesis of anionic polymer brushes and their mineralization with calcium phosphate. The brushes are based on poly(3-sulfopropyl methacrylate potassium salt) providing a highly charged polymer brush surface. Homogeneous brushes with reproducible thicknesses are obtained via surface-initiated atom transfer radical polymerization. Mineralization with doubly concentrated simulated body fluid yields polymer/inorganic hybrid films containing AB-Type carbonated hydroxyapatite (CHAP), a material resembling the inorganic component of bone. Moreover, growth experiments using Dictyostelium discoideum amoebae demonstrate that the mineral-free and the mineral-containing polymer brushes have a good biocompatibility suggesting their use as biocompatible surfaces in implantology or related fields.


2013 ◽  
Vol 791-793 ◽  
pp. 208-211 ◽  
Author(s):  
Xiao Meng Chu ◽  
Shao Jie Liu ◽  
Hui Jiao Yang ◽  
Feng Qing Zhao

This paper firstly summarized the latest research progress on the polymer brushes preparation by surface-initiated ARGET ATRP polymerization. It mainly includes the surface modifications of inorganic substrate (silicon dioxide and carbon nanotubes), and the organic substrate (cellulose and polymer microspheres). This method needs less catalyst and operates more easily, compared to the classical ATRP. Besides, it also has good polymerization controllability, and the polymer brushes have higher grafting density and molecular weight. Therefore, surface-initiated ARGET ATRP polymerization has become an effective method for modifying the surface of materials. Then, we prepared the polymer brush supported TEMPO by the surface-initiated ARGET ATRP and characterized.


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