scholarly journals Defect tolerant device geometries for lead-halide perovskites

2021 ◽  
Author(s):  
Basita Das ◽  
Zhifa Liu ◽  
Irene Aguilera ◽  
Uwe Rau ◽  
Thomas Kirchartz

The term defect tolerance is widely used in literature to describe materials such as lead-halides perovskites, where solution-processed polycrystalline thin films exhibit long non-radiative lifetimes of microseconds or longer. Studies...

Author(s):  
Tyler J. Smart ◽  
Hiroyuki Takenaka ◽  
Tuan Anh Pham ◽  
Liang Z. Tan ◽  
Jin Z. Zhang ◽  
...  

2015 ◽  
Vol 9 (7) ◽  
pp. 444-449 ◽  
Author(s):  
Sergii Yakunin ◽  
Mykhailo Sytnyk ◽  
Dominik Kriegner ◽  
Shreetu Shrestha ◽  
Moses Richter ◽  
...  

2020 ◽  
Vol 7 (7) ◽  
pp. 1902950 ◽  
Author(s):  
Randy P Sabatini ◽  
Chwenhaw Liao ◽  
Stefano Bernardi ◽  
Wenxin Mao ◽  
Matthew S. Rahme ◽  
...  

2020 ◽  
Vol 13 (6) ◽  
pp. 1888-1891
Author(s):  
Alexander Colsmann ◽  
Tobias Leonhard ◽  
Alexander D. Schulz ◽  
Holger Röhm

This comment analyzes pitfalls when investigating piezoresponse and ferroelectricity in organic-metal halide perovskite thin films.


2018 ◽  
Vol 11 (3) ◽  
pp. 702-713 ◽  
Author(s):  
Daniele Meggiolaro ◽  
Silvia G. Motti ◽  
Edoardo Mosconi ◽  
Alex J. Barker ◽  
James Ball ◽  
...  

Electron/hole traps related to interstitial iodine defects show the typical features of iodine photo-electrochemistry, inducing MAPbI3 defect tolerance.


Author(s):  
Tsung Sheng Kao ◽  
Yu-Hsun Chou ◽  
Kuo-Bin Hong ◽  
Jiong-Fu Huang ◽  
Fang-Chung Chen ◽  
...  

2019 ◽  
Vol 2 (2) ◽  
pp. 67
Author(s):  
Zhiya Dang ◽  
Duc Anh Dinh

Lead halide perovskites are the new rising generation of semiconductor materials due to their unique optical and electrical properties. The investigation of the interaction of halide perovskites and light is a key issue not only for understanding their photophysics but also for practical applications. Hence, tremendous efforts have been devoted to this topic and brunch into two: (i) decomposition of the halide perovskites thin films under light illumination; and (ii) influence of light soaking on their photoluminescence (PL) properties. In this review, we for the first time thoroughly compare the illumination conditions and the sample environment to correlate the PL changes and decomposition of perovskite under light illumination. In the case of vacuum and dry nitrogen, PL of the halide perovskite (MAPbI3–xClx, MAPbBr3–xClx, MAPbI3) thin films decreases due to the defects induced by light illumination, and under high excitations, the thin film even decomposes. In the presence of oxygen or moisture, light induces the PL enhancement of halide perovskite (MAPbI3) thin films at low light illumination, while increasing the excitation, which causes the PL to quench and perovskite thin film to decompose. In the case of mixed halide perovskite ((MA)Pb(BrxI1-x)3) light induces reversible segregation of Br domains and I domains. 


Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7827
Author(s):  
Vanira Trifiletti ◽  
Sally Luong ◽  
Giorgio Tseberlidis ◽  
Stefania Riva ◽  
Eugenio S. S. Galindez ◽  
...  

Lead halide perovskites have been revolutionary in the last decade in many optoelectronic sectors. Their bismuth-based counterparts have been considered a good alternative thanks to their composition of earth-abundant elements, good chemical stability, and low toxicity. Moreover, their electronic structure is in a quasi-zero-dimensional (0D) configuration, and they have recently been explored for use beyond optoelectronics. A significant limitation in applying thin-film technology is represented by the difficulty of synthesizing compact layers with easily scalable methods. Here, the engineering of a two-step synthesis in an air of methylammonium bismuth iodide compact thin films is reported. The critical steps of the process have been highlighted so that the procedure can be adapted to different substrates and application areas.


Author(s):  
Zhendong Guo ◽  
Jing Wang ◽  
Wanjian Yin

The soft lattices of lead-halide perovskites (LHPs) are responsible for their unique material properties, including polaron formation, defect tolerance, anharmonic vibration, and large electrostrictive response, which result in exotic carrier...


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