scholarly journals A titanium dioxide–carbon nanotube hybrid to simultaneously achieve the mechanical enhancement of natural rubber and its stability under extreme frictional conditions

2021 ◽  
Vol 2 (7) ◽  
pp. 2408-2418
Author(s):  
Le Wan ◽  
Cong Deng ◽  
Ze-Yong Zhao ◽  
Hai-Bo Zhao ◽  
Yu-Zhong Wang
Keyword(s):  
Titanium Dioxide ◽  
Carbon Nanotube ◽  
Natural Rubber ◽  
Titanium Oxide ◽  
The Stability

Titanium oxide-carbon nanotube hybrids may efficiently promote the stability of nature rubber under extreme frictional conditions.

scholarly journals Combination of Self-Healing Butyl Rubber and Natural Rubber Composites for Improving the Stability

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 443
Author(s):  
Kunakorn Chumnum ◽  
Ekwipoo Kalkornsurapranee ◽  
Jobish Johns ◽  
Karnda Sengloyluan ◽  
Yeampon Nakaramontri
Keyword(s):  
Natural Rubber ◽  
Dynamic Mechanical Properties ◽  
Attenuated Total Reflection ◽  
Rubber Matrix ◽  
Self Healing ◽  
Mechanical And Electrical Properties ◽  
Natural Rubber Composites ◽  
Tan Δ ◽  
The Stability ◽  
Physical And Chemical

The self-healing composites were prepared from the combination of bromobutyl rubber (BIIR) and natural rubber (NR) blends filled with carbon nanotubes (CNT) and carbon black (CB). To reach the optimized self-healing propagation, the BIIR was modified with ionic liquid (IL) and butylimidazole (IM), and blended with NR using the ratios of 70:30 and 80:20 BIIR:NR. Physical and chemical modifications were confirmed from the mixing torque and attenuated total reflection-fourier transform infrared spectroscopy (ATR-FTIR). It was found that the BIIR/NR-CNTCB with IL and IM effectively improved the cure properties with enhanced tensile properties relative to pure BIIR/NR blends. For the healed composites, BIIR/NR-CNTCB-IM exhibited superior mechanical and electrical properties due to the existing ionic linkages in rubber matrix. For the abrasion resistances, puncture stress and electrical recyclability were examined to know the possibility of inner liner applications and Taber abrasion with dynamic mechanical properties were elucidated for tire tread applications. Based on the obtained Tg and Tan δ values, the composites are proposed for tire applications in the future with a simplified preparation procedure.

Synthesis of Titanium Dioxide Nanoparticles in Natural Rubber Latex Medium

2014 ◽  
Vol 1024 ◽  
pp. 108-111 ◽  
Author(s):  
Kim Song Tan
Keyword(s):  
Titanium Dioxide ◽  
Natural Rubber ◽  
Titanium Dioxide Nanoparticles ◽  
Natural Rubber Latex ◽  
Weight Fraction ◽  
Reaction Vessel ◽  
Tetramethylammonium Hydroxide ◽  
Titanium Tetraisopropoxide ◽  
Rubber Latex ◽  
Shape And Size

The feasibility of synthesizing TiO2 nanoparticles using tetramethylammonium hydroxide (TMAOH) stabilized titanium tetraisopropoxide (TTIP) in natural rubber latex medium was investigated. The TiO2 nanoparticles were separated using centrifugation and were characterized using SEM, TEM and XRD. It was found that the weight fraction of latex loaded in the reaction vessel affects the shape and size of the TiO2 particles

scholarly journals Xanthate-modified nanoTiO2 as a novel vulcanization accelerator enhancing mechanical and antibacterial properties of natural rubber

2021 ◽  
Vol 10 (1) ◽  
pp. 478-487
Author(s):  
Yu Liu ◽  
Heliang Wang ◽  
Xiwei Guo ◽  
Mingyuan Yi ◽  
Lihong Wan ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Natural Rubber ◽  
High Performance ◽  
Antibacterial Properties ◽  
Ceric Ammonium Nitrate ◽  
Rubber Matrix ◽  
Aging Effects ◽  
Antibacterial Performance ◽  
First Time ◽  
Vulcanization Accelerator

Abstract With the emerging of sustainability, the fabrication of effective and eco-friendly agents for rubber industry has attracted extensive attention. In this study, a novel and nontoxic titanium dioxide-based vulcanization accelerator (xanthate-modified nanotitanium dioxide (TDSX)) with excellent antibacterial performance, for the first time, was synthesized under the catalyst of ceric ammonium nitrate. Notably, the thermal stability of xanthate was greatly enhanced after being grafted on titanium dioxide (TiO2) nanoparticles, in which the activation energy was increased from 6.4 to 92.5 kJ/mol, enabling the obtained TDSX with multiple functions, mainly consisting of fabulous vulcanization-promoting effects, reinforcing effects, antibacterial properties, and anti-ultraviolet aging effects for natural rubber (NR). Simultaneously, the TDSX can be effectively and uniformly dispersed in the rubber matrix along with the developed interface interaction between TDSX particles and rubber matrix. Compared to the traditional accelerators 2-mercaptobenzothiazole (M) system, the tensile strength and the tearing strength of NR/TDSX was improved by 26.3 and 40.4%, respectively. Potentially, our work for preparing green vulcanization accelerator can provide a new design strategy for multifunctional high performance elastomer materials.

Multi-walled carbon nanotube incorporated nanoporous titanium dioxide electrodes for hybrid polymer solar cells

2018 ◽  
Vol 219 ◽  
pp. 265-268 ◽  
Author(s):  
K. Balashangar ◽  
S. Paranthaman ◽  
M. Thanihaichelvan ◽  
P.A. Amalraj ◽  
D. Velauthapillai ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Solar Cells ◽  
Carbon Nanotube ◽  
Polymer Solar Cells ◽  
Hybrid Polymer ◽  
Multi Walled Carbon Nanotube ◽  
Nanoporous Titanium Dioxide

scholarly journals Thermal Properties and Non-Isothermal Crystallization Kinetics of Poly (δ-Valerolactone) and Poly (δ-Valerolactone)/Titanium Dioxide Nanocomposites

Crystals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 452 ◽  
Author(s):  
Waseem Saeed ◽  
Abdel-Basit Al-Odayni ◽  
Abdulaziz Alghamdi ◽  
Ali Alrahlah ◽  
Taieb Aouak
Keyword(s):  
Titanium Dioxide ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Three Dimensional ◽  
Degree Of Crystallinity ◽  
Simultaneous Occurrence ◽  
Scanning Calorimetry ◽  
Isothermal Crystallization Kinetics ◽  
The Stability ◽  
Kinetics Of

New poly (δ-valerolactone)/titanium dioxide (PDVL/TiO2) nanocomposites with different TiO2 nanoparticle loadings were prepared by the solvent-casting method and characterized by Fourier transform infra-red, differential scanning calorimetry, X-ray diffraction and scanning electron microscopy, and thermogravimetry analyses. The results obtained reveal good dispersion of TiO2 nanoparticles in the polymer matrix and non-formation of new crystalline structures indicating the stability of the crystallinity of TiO2 in the composite. A significant increase in the degree of crystallinity was observed with increasing TiO2 content. The non-isothermal crystallization kinetics of the PDVL/TiO2 system indicate that the crystallization process involves the simultaneous occurrence of two- and three-dimensional spherulitic growths. The thermal degradation analysis of this nanocomposite reveals a significant improvement in the thermal stability with increasing TiO2 loading.

scholarly journals Self-healing properties of carbon nanotube filled natural rubber/bromobutyl rubber blends

2017 ◽  
Vol 11 (3) ◽  
pp. 230-242 ◽  
Author(s):  
H. H. Le ◽  
S. Hait ◽  
A. Das ◽  
S. Wiessner ◽  
K. W. Stoeckelhuber ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Natural Rubber ◽  
Self Healing ◽  
Rubber Blends

scholarly journals Synthesis and Research of Nanocompositions of Oxide Materials Based on Titanium Dioxide for use as Contrast Agents in Optical Coherence Tomography

2021 ◽  
pp. 325-338
Author(s):  
Artem Nikolaevich Kupriyanov ◽  
Diana Evgen’evna Fidarova ◽  
Linda Ruslanovna Makhmudova ◽  
Magomed Rasulovich Gadzhiev ◽  
Shuainat Ruslanovna Nimatulaeva ◽  
...  
Keyword(s):  
Optical Coherence Tomography ◽  
Titanium Dioxide ◽  
Contrast Agent ◽  
Contrast Agents ◽  
Elemental Composition ◽  
Zirconium Dioxide ◽  
Titanium Dioxide Nanoparticles ◽  
Optical Coherence ◽  
Oxide Materials ◽  
The Stability

In this paper, the contrasting properties of titanium dioxide nanoparticles in various compositions were considered. In the course of the work, methods for the synthesis of oxide materials SiO2-TiO2, SiO2-ZrO2, TiO2-ZrO2 and SiO2-TiO2-ZrO2 were developed; the microstructure of oxide materials SiO2-TiO2, SiO2-ZrO2, TiO2-ZrO2and SiO2-TiO2-ZrO2was studied; the stability of oxide materials SiO2-TiO2, SiO2-ZrO2, TiO2-ZrO2and SiO2-TiO2-ZrO2 was determined. The elemental composition of the oxide materials SiO2-TiO2, SiO2-ZrO2, TiO2-ZrO2and SiO2-TiO2-ZrO2 has also been studied using SEM and XRD methods. It was found that SiO2-TiO2-ZrO2 nanocomposites with content of titanium dioxide from 8 to 9.5 % and zirconium dioxide from 0.5 to 2 % are completely insoluble in a highly alkaline medium. Thus, this composition is the most optimal for use as a contrast agent in optical coherence tomography.

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