Catalytic exchange of hydrogen isotopes intensified by two-phase stratified flow in wettability designable microchannels

Lab on a Chip ◽  
2020 ◽  
Vol 20 (12) ◽  
pp. 2154-2165
Author(s):  
Yuexiao Song ◽  
Feng Xin ◽  
Yongsheng Xu
Keyword(s):  
Liquid Phase ◽  
Stratified Flow ◽  
Hydrogen Isotopes ◽  
Microchannel Reactor ◽  
Two Phase ◽  
Catalytic Exchange

Liquid phase catalytic exchange of hydrogen isotopes is intensified by stratified flow in a microchannel reactor coated with hydrophobic Pt/AC/PDMS.

An assessment on hydrogen isotopes separation by liquid phase catalytic exchange process

2015 ◽  
Vol 305 (1) ◽  
pp. 117-126 ◽  
Author(s):  
Gheorghe Ionita ◽  
Ciprian Bucur ◽  
Ionut Spiridon ◽  
Ioan Stefanescu
Keyword(s):  
Liquid Phase ◽  
Exchange Process ◽  
Hydrogen Isotopes ◽  
Isotopes Separation ◽  
Catalytic Exchange

SYNTHESIS OF HYDROGEN IN ACOUSTOPLASMA DISCHARGE IN A LIQUID-PHASE STREAM

2019 ◽  
pp. 42-48 ◽  
Author(s):  
N. A. Bulychev
Keyword(s):  
Liquid Phase ◽  
Organic Compounds ◽  
Electrode Materials ◽  
Solid Phase ◽  
Plasma Discharge ◽  
Raw Material ◽  
Two Phase ◽  
Reduced Pressure ◽  
External Power Source ◽  
Phase Medium

In this paper, the plasma discharge in a high-pressure fluid stream in order to produce gaseous hydrogen was studied. Methods and equipment have been developed for the excitation of a plasma discharge in a stream of liquid medium. The fluid flow under excessive pressure is directed to a hydrodynamic emitter located at the reactor inlet where a supersonic two-phase vapor-liquid flow under reduced pressure is formed in the liquid due to the pressure drop and decrease in the flow enthalpy. Electrodes are located in the reactor where an electric field is created using an external power source (the strength of the field exceeds the breakdown threshold of this two-phase medium) leading to theinitiation of a low-temperature glow quasi-stationary plasma discharge.A theoretical estimation of the parameters of this type of discharge has been carried out. It is shown that the lowtemperature plasma initiated under the flow conditions of a liquid-phase medium in the discharge gap between the electrodes can effectively decompose the hydrogen-containing molecules of organic compounds in a liquid with the formation of gaseous products where the content of hydrogen is more than 90%. In the process simulation, theoretical calculations of the voltage and discharge current were also made which are in good agreement with the experimental data. The reaction unit used in the experiments was of a volume of 50 ml and reaction capacity appeared to be about 1.5 liters of hydrogen per minute when using a mixture of oxygen-containing organic compounds as a raw material. During their decomposition in plasma, solid-phase products are also formed in insignificant amounts: carbon nanoparticles and oxide nanoparticles of discharge electrode materials.

Axial dispersion in the liquid phase in a horizontal two-phase tube reactor

1991 ◽  
Vol 56 (6) ◽  
pp. 1249-1252
Author(s):  
Marie Fialová ◽  
Ctirad Verner ◽  
Lothar Ebner
Keyword(s):  
Liquid Phase ◽  
Flow Regimes ◽  
Basic Flow ◽  
Axial Dispersion ◽  
Two Phase ◽  
Tube Reactor

The characteristics of axial dispersion in the liquid phase were measured for two basic flow regimes in a horizontal two-phase tube reactor. The data obtained indicate that in some flow regions, axial dispersion can be quite significant.

scholarly journals Thermodynamics and Machine Learning Based Approaches for Vapor–Liquid–Liquid Phase Equilibria in n-Octane/Water, as a Naphtha–Water Surrogate in Water Blends

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 413
Author(s):  
Sandra Lopez-Zamora ◽  
Jeonghoon Kong ◽  
Salvador Escobedo ◽  
Hugo de Lasa
Keyword(s):  
Machine Learning ◽  
Liquid Phase ◽  
Phase Equilibria ◽  
Aspen Plus ◽  
Phase Region ◽  
Two Phase ◽  
Technical Literature ◽  
Phase Liquid ◽  
Liquid Vapor ◽  
Vapor Liquid

The prediction of phase equilibria for hydrocarbon/water blends in separators, is a subject of considerable importance for chemical processes. Despite its relevance, there are still pending questions. Among them, is the prediction of the correct number of phases. While a stability analysis using the Gibbs Free Energy of mixing and the NRTL model, provide a good understanding with calculation issues, when using HYSYS V9 and Aspen Plus V9 software, this shows that significant phase equilibrium uncertainties still exist. To clarify these matters, n-octane and water blends, are good surrogates of naphtha/water mixtures. Runs were developed in a CREC vapor–liquid (VL_ Cell operated with octane–water mixtures under dynamic conditions and used to establish the two-phase (liquid–vapor) and three phase (liquid–liquid–vapor) domains. Results obtained demonstrate that the two phase region (full solubility in the liquid phase) of n-octane in water at 100 °C is in the 10-4 mol fraction range, and it is larger than the 10-5 mol fraction predicted by Aspen Plus and the 10-7 mol fraction reported in the technical literature. Furthermore, and to provide an effective and accurate method for predicting the number of phases, a machine learning (ML) technique was implemented and successfully demonstrated, in the present study.

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