scholarly journals Correction: Synthesis of dibenzocycloketones by acyl radical cyclization from aromatic carboxylic acids using methylene blue as a photocatalyst

2020 ◽  
Vol 22 (4) ◽  
pp. 1443-1443
Author(s):  
Hongshuo Jiang ◽  
Guijie Mao ◽  
Hongfeng Wu ◽  
Qi An ◽  
Minghui Zuo ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Carboxylic Acids ◽  
Radical Cyclization ◽  
Acyl Radical ◽  
Aromatic Carboxylic Acids

Correction for ‘Synthesis of dibenzocycloketones by acyl radical cyclization from aromatic carboxylic acids using methylene blue as a photocatalyst’ by Hongshuo Jiang et al., Green Chem., 2019, 21, 5368–5373.

Synthesis of dibenzocycloketones by acyl radical cyclization from aromatic carboxylic acids using methylene blue as a photocatalyst

2019 ◽  
Vol 21 (19) ◽  
pp. 5368-5373 ◽  
Author(s):  
Hongshuo Jiang ◽  
Guijie Mao ◽  
Hongfeng Wu ◽  
Qi An ◽  
Minghui Zuo ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Carboxylic Acids ◽  
Radical Cyclization ◽  
Cyclization Reaction ◽  
Photoredox Catalysis ◽  
Acyl Radical ◽  
Aromatic Carboxylic Acids

An efficient intramolecular radical cyclization reaction via photoredox catalysis was developed for the synthesis of dibenzocycloketone derivatives using methylene blue as a photosensitizer.

Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage–Independent Activation of Strong C–O Bonds

2018 ◽  
Author(s):  
Erin Stache ◽  
Alyssa B. Ertel ◽  
Tomislav Rovis ◽  
Abigail G. Doyle
Keyword(s):  
Carboxylic Acids ◽  
Functional Groups ◽  
Single Step ◽  
Direct Access ◽  
Photoredox Catalysis ◽  
Acyl Radical ◽  
Synthetic Strategy ◽  
Acyl Radicals ◽  
Benzyl Radicals ◽  
Aliphatic Carboxylic Acids

Alcohols and carboxylic acids are ubiquitous functional groups found in organic molecules that could serve as radical precursors, but C–O bonds remain difficult to activate. We report a synthetic strategy for direct access to both alkyl and acyl radicals from these ubiquitous functional groups via photoredox catalysis. This method exploits the unique reactivity of phosphoranyl radicals, generated from a polar/SET crossover between a phosphine radical cation and an oxygen centered nucleophile. We first show the desired reactivity in the reduction of benzylic alcohols to the corresponding benzyl radicals with terminal H-atom trapping to afford the deoxygenated product. Using the same method, we demonstrate access to synthetically versatile acyl radicals which enables the reduction of aromatic and aliphatic carboxylic acids to the corresponding aldehydes with exceptional chemoselectivity. This protocol also transforms carboxylic acids to heterocycles and cyclic ketones via intramolecular acyl radical cyclizations to forge new C–O, C–N and C–C bonds in a single step.

Intercalated Organo-Bentonite as Efficient Biosorbent for Aromatic Carboxylic Acids from Wastewater

2021 ◽  
pp. 116443
Author(s):  
N. Bensid ◽  
R. Zerdoum ◽  
Z. Hattab ◽  
Y. Boutaleb ◽  
M. Bououdina
Keyword(s):  
Carboxylic Acids ◽  
Aromatic Carboxylic Acids

ChemInform Abstract: “Ligand-Free” Palladium-Catalyzed Direct C-H Bond Oxidative Acyloxylation of 2-Arylpyridines with Aromatic Carboxylic Acids.

ChemInform ◽  
2012 ◽  
Vol 43 (35) ◽  
pp. no-no
Author(s):  
Chao-Jun Hu ◽  
Xiao-Hong Zhang ◽  
Qiu-Ping Ding ◽  
Ting Lv ◽  
Shao-Peng Ge ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Aromatic Carboxylic Acids ◽  
Ligand Free ◽  
Palladium Catalyzed

scholarly journals Fluorescent Derivatization of Aromatic Carboxylic Acids with Horseradish Peroxidase in the Presence of Excess Hydrogen Peroxide

2015 ◽  
Vol 31 (1) ◽  
pp. 37-44
Author(s):  
Junichi ODO ◽  
Masahiko INOGUCHI ◽  
Hiroyuki AOKI ◽  
Yuto SOGAWA ◽  
Masahiro NISHIMURA
Keyword(s):  
Hydrogen Peroxide ◽  
Horseradish Peroxidase ◽  
Carboxylic Acids ◽  
Aromatic Carboxylic Acids ◽  
Excess Hydrogen

scholarly journals Exploring the pathways of aromatic carboxylic acids in ozone solutions

RSC Advances ◽  
2017 ◽  
Vol 7 (55) ◽  
pp. 34339-34347 ◽  
Author(s):  
Xin Zhong ◽  
Chongwei Cui ◽  
Shuili Yu
Keyword(s):  
Organic Matter ◽  
Carboxylic Acids ◽  
Natural Organic Matter ◽  
Aromatic Carboxylic Acids

The reaction between ozone and natural organic matter (NOM) generates a certain amount of aromatic carboxylic acids (ACAs).

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