Ruthenium complex immobilized on supported ionic-liquid-phase (SILP) for alkoxycarbonylation of olefins with CO2

2021 ◽  
Vol 23 (8) ◽  
pp. 3073-3080
Author(s):  
Shi-Ping Xia ◽  
Guang-Rong Ding ◽  
Rui Zhang ◽  
Li-Jun Han ◽  
Bao-Hua Xu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Phase ◽  
Silica Gel ◽  
Ruthenium Complex ◽  
Porous Silica ◽  
Catalytic Performance ◽  
Imidazolium Chloride ◽  
Supported Ionic Liquid ◽  
Porous Silica Gel

Novel [Ru]@SILP hybrids were synthesized by directly reacting Ru3(CO)12 with specific imidazolium chloride decorated porous silica gel. Impressively, the optimized [Ru]@SILP exhibited enhanced catalytic performance in the alkoxycarbonylation of olefins with CO2.

scholarly journals Influence of the Ionic Liquid on the Activity of a Supported Ionic Liquid Phase FeII Pincer Catalyst for the Hydrogenation of Aldehydes

2019 ◽  
Vol 2019 (30) ◽  
pp. 3503-3510 ◽  
Author(s):  
Zita Csendes ◽  
Julian Brünig ◽  
Nevzat Yigit ◽  
Günther Rupprechter ◽  
Katharina Bica-Schröder ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Phase ◽  
Supported Ionic Liquid

ChemInform Abstract: Supported Ionic Liquid Phase Catalysts

ChemInform ◽  
2010 ◽  
Vol 41 (19) ◽  
Author(s):  
Anders Riisager ◽  
Rasmus Fehrmann
Keyword(s):  
Ionic Liquid ◽  
Liquid Phase ◽  
Supported Ionic Liquid

Efficient and Reusable Silica Gel Supported Metal Ionic Liquid Catalysts for Palmitic Acid Esterification to Biodiesel

2021 ◽  
Vol 43 (1) ◽  
pp. 1-1
Author(s):  
Guo Yingwei Guo Yingwei ◽  
Chen Xuedan Chen Xuedan ◽  
Yan Shiting Yan Shiting ◽  
Zhang Zhengliang Zhang Zhengliang ◽  
Chen Yuqin Chen Yuqin ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Palmitic Acid ◽  
Silica Gel ◽  
High Surface ◽  
High Surface Area ◽  
Kinetic Studies ◽  
Catalytic Performance ◽  
Reaction Conditions ◽  
Acid Esterification ◽  
Supported Metal

A series of silica gel (SG) supported metal ionic liquid catalysts (x[Bmim]Cl-CrCl3/SG) were synthesized and exploited for the esterification of palmitic acid (PA) with methanol (ML) to produce biodiesel efficiently. The 10%[Bmim]Cl-CrCl3/SG catalyst with high surface area and desirable acidity exhibited the best catalytic performance and reusability after six consecutive running cycles. Based on the response surface analysis, the optimal reaction conditions were obtained as follows: methanol/acid mole ratio = 11:1 mol/mol, catalyst amount = 5.3 wt%, reaction time = 65 min, as well as reaction temperature = 373 K, reaching to a biodiesel yield of 96.1%. Further kinetic studies demonstrated that the esterification of PA with ML obeyed 1.41 order kinetics for acid concentration with the activation energy of 16.88 kJ/mol

The influence of supports on Rh‐TPPTS supported ionic liquid‐phase catalysts for the hydroformylation of ethylene**

2021 ◽  
Vol 6 (37) ◽  
pp. 9888-9893
Author(s):  
Van Chuc Nguyen ◽  
Van Hung Do ◽  
Duc Duc Truong ◽  
Anders Riisager ◽  
Rasmus Fehrmann ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Phase ◽  
Supported Ionic Liquid

Efficient and Reusable Silica Gel Supported Metal Ionic Liquid Catalysts for Palmitic Acid Esterification to Biodiesel

2021 ◽  
Vol 43 (1) ◽  
pp. 1-1
Author(s):  
Guo Yingwei Guo Yingwei ◽  
Chen Xuedan Chen Xuedan ◽  
Yan Shiting Yan Shiting ◽  
Zhang Zhengliang Zhang Zhengliang ◽  
Chen Yuqin Chen Yuqin ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Palmitic Acid ◽  
Silica Gel ◽  
High Surface ◽  
High Surface Area ◽  
Kinetic Studies ◽  
Catalytic Performance ◽  
Reaction Conditions ◽  
Acid Esterification ◽  
Supported Metal

A series of silica gel (SG) supported metal ionic liquid catalysts (x[Bmim]Cl-CrCl3/SG) were synthesized and exploited for the esterification of palmitic acid (PA) with methanol (ML) to produce biodiesel efficiently. The 10%[Bmim]Cl-CrCl3/SG catalyst with high surface area and desirable acidity exhibited the best catalytic performance and reusability after six consecutive running cycles. Based on the response surface analysis, the optimal reaction conditions were obtained as follows: methanol/acid mole ratio = 11:1 mol/mol, catalyst amount = 5.3 wt%, reaction time = 65 min, as well as reaction temperature = 373 K, reaching to a biodiesel yield of 96.1%. Further kinetic studies demonstrated that the esterification of PA with ML obeyed 1.41 order kinetics for acid concentration with the activation energy of 16.88 kJ/mol

CO2 Capture by Supported Ionic Liquid Phase: Highlighting the Role of the Particle Size

2019 ◽  
Vol 7 (15) ◽  
pp. 13089-13097 ◽  
Author(s):  
Ruben Santiago ◽  
Jesus Lemus ◽  
Daniel Hospital-Benito ◽  
Cristian Moya ◽  
Jorge Bedia ◽  
...  
Keyword(s):  
Particle Size ◽  
Ionic Liquid ◽  
Liquid Phase ◽  
Co2 Capture ◽  
Supported Ionic Liquid
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