scholarly journals Photochemical Reduction of Carbon Dioxide to Formic Acid

2021 ◽  
Author(s):  
Shoubhik Das ◽  
Robin Cauwenbergh
Keyword(s):  
Carbon Dioxide ◽  
Green Chemistry ◽  
Formic Acid ◽  
Carbon Capture ◽  
Carbon Capture And Storage ◽  
Photochemical Reduction ◽  
The Past ◽  
Carbon Capture And Utilization ◽  
And Storage

With the growing awareness of green chemistry, carbon capture and utilization (CCU) has got tremendous attention compared to the carbon capture and storage (CCS). Over the past decades, the development...

scholarly journals Harnessing Escherichia coli for bio-based production of formate under pressurized H 2 and CO 2 gases.

2021 ◽  
Author(s):  
Magali Roger ◽  
Thomas C. P. Reed ◽  
Frank Sargent
Keyword(s):  
Escherichia Coli ◽  
Carbon Dioxide ◽  
Formic Acid ◽  
Carbon Capture ◽  
Continuous Production ◽  
Carbon Capture And Storage ◽  
Physiological Role ◽  
Anaerobic Growth ◽  
Formate Hydrogenlyase ◽  
And Storage

Escherichia coli is gram-negative bacterium that is a workhorse for biotechnology. The organism naturally performs a mixed-acid fermentation under anaerobic conditions where it synthesises formate hydrogenlyase (FHL-1). The physiological role of the enzyme is the disproportionation of formate in to H 2 and CO 2 . However, the enzyme has been observed to catalyse hydrogenation of CO 2 given the correct conditions, and so has possibilities in bio-based carbon capture and storage if it can be harnessed as a hydrogen-dependent CO 2 -reductase (HDCR). In this study, an E. coli host strain was engineered for the continuous production of formic acid from H 2 and CO 2 during bacterial growth in a pressurised batch bioreactor. Incorporation of tungsten, in place of molybdenum, in FHL-1 helped to impose a degree of catalytic bias on the enzyme. This work demonstrates that it is possible to couple cell growth to simultaneous, unidirectional formate production from carbon dioxide and develops a process for growth under pressurised gases. IMPORTANCE Greenhouse gas emissions, including waste carbon dioxide, are contributing to global climate change. A basket of solutions is needed to steadily reduce emissions, and one approach is bio-based carbon capture and storage. Here we present out latest work on harnessing a novel biological solution for carbon capture. The Escherichia coli formate hydrogenlyase (FHL-1) was engineered to be constitutively expressed. Anaerobic growth under pressurised H 2 and CO 2 gases was established and aqueous formic acid was produced as a result. Incorporation of tungsten in to the enzyme in place of molybdenum proved useful in poising FHL-1 as a hydrogen-dependent CO 2 reductase (HDCR).

Study on Dispersion of Carbon Dioxide over the Shrubbery Region

2021 ◽  
Vol 9 ◽  
Author(s):  
Wang Huiru ◽  
You Zhanping ◽  
Mo Fan ◽  
Liu Bin ◽  
Han Peng
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Carbon Capture And Storage ◽  
Dispersion Pattern ◽  
Buried Pipeline ◽  
Dynamic Impact ◽  
Coverage Area ◽  
Computational Fluid Dynamics Cfd ◽  
And Storage ◽  
Terrain Features

In the carbon capture and storage (CCS) infrastructure, the risk of a high-pressure buried pipeline rupture possibly leads to catastrophic accidents due to the release of tremendous amounts of carbon dioxide (CO2). Therefore, a comprehensive understanding of the effects of CO2 dispersion pattern after release from CCS facilities is essential to allow the appropriate safety precautions to be taken. Due to variations in topography above the pipeline, the pattern of CO2 dispersion tends to be affected by the real terrain features, such as trees and hills. However, in most previous studies, the dynamic impact of trees on the wind field was often approximated to linear treatment or even ignored. In this article, a computational fluid dynamics (CFD) model was proposed to predict CO2 dispersion over shrubbery areas. The shrubs were regarded as a kind of porous media, and the model was validated against the results from experiment. It was found that shrubbery affected the flow field near the ground, enhancing the lateral dispersion of CO2. Compared with that of the shrub-free terrain, the coverage area of the three shrub terrains at 60 s increased by 8.1 times, 6.7 times, and 9.1 times, respectively. The influence of shrub height and porosity on CO2 dispersion is nonlinear. This research provides reliable data for the risk assessment of CCS.

Densities of the carbon dioxide+hydrogen, a system of relevance to carbon capture and storage

2013 ◽  
Vol 13 ◽  
pp. 78-86 ◽  
Author(s):  
Yolanda Sanchez-Vicente ◽  
Trevor C. Drage ◽  
Martyn Poliakoff ◽  
Jie Ke ◽  
Michael W. George
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Carbon Capture And Storage ◽  
And Storage

scholarly journals Field-Based Stable Isotope Analysis of Carbon Dioxide by Mid-Infrared Laser Spectroscopy for Carbon Capture and Storage Monitoring

2014 ◽  
Vol 86 (24) ◽  
pp. 12191-12198 ◽  
Author(s):  
Robert van Geldern ◽  
Martin E. Nowak ◽  
Martin Zimmer ◽  
Alexandra Szizybalski ◽  
Anssi Myrttinen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Stable Isotope ◽  
Laser Spectroscopy ◽  
Stable Isotope Analysis ◽  
Carbon Capture ◽  
Isotope Analysis ◽  
Carbon Capture And Storage ◽  
Mid Infrared ◽  
Infrared Laser Spectroscopy ◽  
And Storage

scholarly journals Holistic Assessment of Carbon Capture and Utilization Value Chains

Environments ◽  
2018 ◽  
Vol 5 (10) ◽  
pp. 108 ◽  
Author(s):  
Tryfonas Pieri ◽  
Alexandros Nikitas ◽  
Arturo Castillo-Castillo ◽  
Athanasios Angelis-Dimakis
Keyword(s):  
Value Chain ◽  
Carbon Capture ◽  
Carbon Capture And Storage ◽  
Holistic Approach ◽  
Value Chains ◽  
The European Union ◽  
Carbon Capture And Utilization ◽  
Holistic Assessment ◽  
The Individual ◽  
And Storage

Carbon capture and utilization (CCU) is recognized by the European Union, along with carbon, capture and storage (CCS), as one of the main tools towards global warming mitigation. It has, thus, been extensively studied by various researchers around the world. The majority of the papers published so far focus on the individual stages of a CCU value chain (carbon capture, separation, purification, transportation, and transformation/utilization). However, a holistic approach, taking into account the matching and the interaction between these stages, is also necessary in order to optimize and develop technically and economically feasible CCU value chains. The objective of this contribution is to present the most important studies that are related to the individual stages of CCU and to perform a critical review of the major existing methods, algorithms and tools that focus on the simulation or optimization of CCU value chains. The key research gaps will be identified and examined in order to lay the foundation for the development of a methodology towards the holistic assessment of CCU value chains.

The Evaluation and Comparison of Carbon Dioxide Capture Technologies Applied to FCC Flue Gas

2011 ◽  
Vol 347-353 ◽  
pp. 1479-1482 ◽  
Author(s):  
Pu Peng ◽  
Yi Zhuang
Keyword(s):  
Carbon Dioxide ◽  
Flue Gas ◽  
Co2 Emission ◽  
Carbon Capture ◽  
Carbon Dioxide Capture ◽  
Carbon Capture And Storage ◽  
Commercial Success ◽  
Green House ◽  
Co2 Capturing ◽  
And Storage

The CO2 capturing technologies as applied to FCC flue gas in order to reduce GHG (green house gases) were evaluated and compared in this review. Although the CCS (carbon capture and storage) idea has been proposed for more than 30 years, there has been little commercial success of CCS projects. The largest issue is where to store the massive amount of captured pure CO2 every year. Therefore, the review will focus on the efficient use of power or heat to reduce CO2 emission and how to recycle the use of produced CO2 before it is emitted to the atmosphere rather than being captured and stored. The scenarios with oxyfiring, microalgae-cofiring or biogas burning to treat FCC flue gas are introduced and discussed.

Greener Solvent Selection and Solvent Recycling for Carbon Dioxide Capture

2012 ◽  
Vol 5 (1) ◽  
Author(s):  
G. Hachem ◽  
J. Salazar ◽  
U. Dixekar
Keyword(s):  
Carbon Dioxide ◽  
Simulated Annealing ◽  
Carbon Capture ◽  
Power Plants ◽  
Carbon Dioxide Capture ◽  
Carbon Capture And Storage ◽  
Aspen Plus ◽  
Solvent Selection ◽  
Carbon Dioxide Co2 ◽  
And Storage

Carbon capture and storage (CCS) constitutes an extremely important technology that is constantly being improved to minimize the amounts of carbon dioxide (CO2) entering the atmosphere. According to the Global CCS Institute, there are more than 320 worldwide CCS projects at different phases of progress. However, current CCS processes are accompanied with a large energy and efficiency penalty. This paper models and simulates a post-combustion carbon capture system, that uses absorption as a method of separation, in Aspen Plus V7.2. Moreover, the CAPE-OPEN Simulated Annealing (SA) Capability is implemented to minimize the energy consumed by this system, and allow coal-fired power plants to use similar carbon capture systems without losing 20 to 40 % of the plant's output.

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