Effective Hydrogenation of CO2 to Formate Catalyzed by Ionic Liquids Modified Acetate-Cu

2021 ◽  
Author(s):  
Jinling Hu ◽  
Jia Liu ◽  
Chenfei Yao ◽  
Lei Zhou ◽  
You-Ting Wu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Precious Metals ◽  
Hydrogenation Of Co2

Hydrogenation of CO2 is full of challenge, especially when non precious metals are used as catalysts. Herein, we reported an effective hydrogenation of CO2 to formate catalyzed by imidazole ionic...

scholarly journals Separation of precious metals by split-anion extraction using water-saturated ionic liquids

2020 ◽  
Vol 22 (23) ◽  
pp. 8375-8388
Author(s):  
Viet Tu Nguyen ◽  
Sofía Riaño ◽  
Koen Binnemans
Keyword(s):  
Ionic Liquids ◽  
Precious Metals ◽  
Water Saturated ◽  
Selective Process

Split-anion extraction with water-saturated ionic liquids is a benign, efficient and selective process for recovery of precious metals from chloride media.

scholarly journals A Combined Deep Eutectic Solvent–Ionic Liquid Process for the Extraction and Separation of Platinum Group Metals (Pt, Pd, Rh)

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7204
Author(s):  
Olga Lanaridi ◽  
Sonja Platzer ◽  
Winfried Nischkauer ◽  
Andreas Limbeck ◽  
Michael Schnürch ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Mixed Model ◽  
Deep Eutectic Solvent ◽  
Precious Metals ◽  
Platinum Group Metals ◽  
Environmentally Benign ◽  
Extraction Capacity ◽  
Acidic Solutions ◽  
Extraction And Separation ◽  
Platinum Group

Recovery of platinum group metals from spent materials is becoming increasingly relevant due to the high value of these metals and their progressive depletion. In recent years, there is an increased interest in developing alternative and more environmentally benign processes for the recovery of platinum group metals, in line with the increased focus on a sustainable future. To this end, ionic liquids are increasingly investigated as promising candidates that can replace state-of-the-art approaches. Specifically, phosphonium-based ionic liquids have been extensively investigated for the extraction and separation of platinum group metals. In this paper, we present the extraction capacity of several phosphonium-based ionic liquids for platinum group metals from model deep eutectic solvent-based acidic solutions. The most promising candidates, P66614Cl and P66614B2EHP, which exhibited the ability to extract Pt, Pd, and Rh quantitively from a mixed model solution, were additionally evaluated for their capacity to recover these metals from a spent car catalyst previously leached into a choline-based deep eutectic solvent. Specifically, P66614Cl afforded extraction of the three target precious metals from the leachate, while their partial separation from the interfering Al was also achieved since a significant amount (approx. 80%) remained in the leachate.

scholarly journals Dissolution behavior of precious metals and selective palladium leaching from spent automotive catalysts by trihalide ionic liquids

RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 10110-10120
Author(s):  
Arne Van den Bossche ◽  
Nerea Rodriguez Rodriguez ◽  
Sofía Riaño ◽  
Wim Dehaen ◽  
Koen Binnemans
Keyword(s):  
Ionic Liquids ◽  
Precious Metals ◽  
Dissolution Behavior ◽  
Automotive Catalysts ◽  
Automotive Catalyst ◽  
Ceramic Support

Trichloride ionic liquids were used to increase the leaching selectivity of palladium from spent automotive catalyst with a ceramic support.

scholarly journals The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals

2016 ◽  
Vol 87 ◽  
pp. 18-24 ◽  
Author(s):  
Gawen R.T. Jenkin ◽  
Ahmed Z.M. Al-Bassam ◽  
Robert C. Harris ◽  
Andrew P. Abbott ◽  
Daniel J. Smith ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Deep Eutectic Solvent ◽  
Precious Metals ◽  
Environmentally Friendly

scholarly journals Separation of Precious Metals by Using Undiluted Ionic Liquids

2014 ◽  
Vol 21 (1) ◽  
pp. 89-94 ◽  
Author(s):  
Jian YANG ◽  
Fukiko KUBOTA ◽  
Yuzo BABA ◽  
Noriho KAMIYA ◽  
Masahiro GOTO
Keyword(s):  
Ionic Liquids ◽  
Precious Metals

Homogeneous Hydrogenation of CO2 to Methyl Formate Utilizing Switchable Ionic Liquids

2014 ◽  
Vol 53 (18) ◽  
pp. 9849-9854 ◽  
Author(s):  
Mahendra Yadav ◽  
John C. Linehan ◽  
Abhijeet J. Karkamkar ◽  
Edwin van der Eide ◽  
David. J. Heldebrant
Keyword(s):  
Ionic Liquids ◽  
Methyl Formate ◽  
Homogeneous Hydrogenation ◽  
Hydrogenation Of Co2
Sign in / Sign up

Export Citation Format

Share Document