scholarly journals High elasticity, chemically recyclable, thermoplastics from bio-based monomers: carbon dioxide, limonene oxide and ε-decalactone

2020 ◽  
Vol 22 (23) ◽  
pp. 8298-8307
Author(s):  
Leticia Peña Carrodeguas ◽  
Thomas T. D. Chen ◽  
Georgina L. Gregory ◽  
Gregory S. Sulley ◽  
Charlotte K. Williams
Keyword(s):  
Carbon Dioxide ◽  
Chemical Recycling ◽  
High Elasticity ◽  
Limonene Oxide

Efficient polymerization catalyses transform bio-sourced monomers into thermoplastics with high elasticity and strength, which can be degraded to allow for chemical recycling. The plastics utilize carbon dioxide, limonene oxide and ε-decalactone.

Two Diastereomers of d-Limonene-Derived Cyclic Carbonates from d-Limonene Oxide and Carbon Dioxide with a Tetrabutylammonium Chloride Catalyst

2018 ◽  
Vol 91 (1) ◽  
pp. 92-94 ◽  
Author(s):  
Hiroshi Morikawa ◽  
Masato Minamoto ◽  
Yuuta Gorou ◽  
Jun-ichi Yamaguchi ◽  
Hisatoyo Morinaga ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates ◽  
Chloride Catalyst ◽  
Limonene Oxide ◽  
Tetrabutylammonium Chloride

scholarly journals Tunable and Recyclable Polyesters from CO2 and Butadiene

2021 ◽  
Author(s):  
Rachel Rapagnani ◽  
Rachel Dunscomb ◽  
Alexandra Fresh ◽  
Ian Tonks
Keyword(s):  
Carbon Dioxide ◽  
Ring Opening ◽  
High Energy ◽  
Ring Opening Polymerization ◽  
Chemical Recycling ◽  
Alternate Route ◽  
Ceiling Temperature ◽  
Chemical Feedstock

Carbon dioxide is inexpensive and abundant, and its prevalence as waste makes it attractive as a sustainable chemical feedstock. Although there are examples of copolymerizations of CO2 with high-energy monomers, the direct copolymerization of CO2 with olefins has not been reported. Herein, an alternate route to tunable, recyclable polyesters derived from CO2 and butadiene via an intermediary lactone, 3-ethyl-6-vinyltetrahydro-2H-pyran-2-one, is described. Catalytic ring-opening polymerization of the lactone by 1,5,7-triazabicyclo[4.4.0]dec-5-ene yields polyesters with molar masses up to 13.6 kg/mol and pendent vinyl sidechains that can undergo post-polymerization functionalization. The polymer has a low ceiling temperature of 138 ºC, allowing for facile chemical recycling. These results mark the first example of a well-defined polyester derived solely from CO2 and olefins, expanding access to new feedstocks that were once considered unfeasible.

scholarly journals Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy

2018 ◽  
Author(s):  
Mario Pagliaro ◽  
Alexandra Fidalgo ◽  
Leonardo Palmisano ◽  
Laura M. Ilharco ◽  
Francesco Parrino ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Physical Properties ◽  
Ring Opening ◽  
Low Cost ◽  
Economic Feasibility ◽  
Homogeneous Catalysts ◽  
Limonene Oxide ◽  
Copolymerization Reaction

Limonene epoxide (1,2 limonene oxide) readily reacts with carbon dioxide in a ring opening copolymerization reaction with insertion of CO2 and formation of polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized using low cost Zn or Al homogeneous catalysts. This study addresses selected relevant questions concerning the technical and economic feasibility of limonene and carbon dioxide polymers en route to the bioeconomy.

A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2

2011 ◽  
Vol 51 (1) ◽  
pp. 187-190 ◽  
Author(s):  
Christophe Das Neves Gomes ◽  
Olivier Jacquet ◽  
Claude Villiers ◽  
Pierre Thuéry ◽  
Michel Ephritikhine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Recycling ◽  
Diagonal Approach

Titelbild: A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2 (Angew. Chem. 1/2012)

2011 ◽  
Vol 124 (1) ◽  
pp. 1-1 ◽  
Author(s):  
Christophe Das Neves Gomes ◽  
Olivier Jacquet ◽  
Claude Villiers ◽  
Pierre Thuéry ◽  
Michel Ephritikhine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Recycling ◽  
Diagonal Approach

Cover Picture: A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2 (Angew. Chem. Int. Ed. 1/2012)

2011 ◽  
Vol 51 (1) ◽  
pp. 1-1 ◽  
Author(s):  
Christophe Das Neves Gomes ◽  
Olivier Jacquet ◽  
Claude Villiers ◽  
Pierre Thuéry ◽  
Michel Ephritikhine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Recycling ◽  
Diagonal Approach

Alternating Copolymerization of Limonene Oxide and Carbon Dioxide

2004 ◽  
Vol 126 (37) ◽  
pp. 11404-11405 ◽  
Author(s):  
Christopher M. Byrne ◽  
Scott D. Allen ◽  
Emil B. Lobkovsky ◽  
Geoffrey W. Coates
Keyword(s):  
Carbon Dioxide ◽  
Limonene Oxide ◽  
Alternating Copolymerization

A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2

2011 ◽  
Vol 124 (1) ◽  
pp. 191-194 ◽  
Author(s):  
Christophe Das Neves Gomes ◽  
Olivier Jacquet ◽  
Claude Villiers ◽  
Pierre Thuéry ◽  
Michel Ephritikhine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Recycling ◽  
Diagonal Approach
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